The invention relates to aqueous polymer dispersions comprising polymerized units issued from the following monomers with related weight proportions based on 100 parts of weight of a)+b): a) 50 to 90% of a monoethylenically unsaturated non-ionic monomer, b) 10 to 50% of vinyl aromatic monomer or methyl methacrylate, c) 1 to 5% of a hydroxy-containing (meth)acrylate, d) 0.1 to 3% of acid monomer selected from d1) acid monomer selected from monocarboxylic or dicarboxylic acid monomers and d2) acid monomer selected from phosphorous-based or sulfur-based strong acid monomers or/and their salts, or from the mixtures of d1) and d2), e) 0.001 to 0.5% of chain transfer agent, and f) 0 to 1% one of internal crosslinker bearing at least two copolymerisable ethylenic unsaturations, the polymer having a Tg measured by DSC from −30 to 0° C. and a gel content of 0 to 60%, formed during polymerization.
C08F 230/02 - Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium, or a metal containing phosphorus
C08F 236/02 - Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
C08K 3/013 - Fillers, pigments or reinforcing additives
Curable resin compositions having extended open times at ambient temperatures and short cure times at elevated temperatures are prepared using a curable resin, a combination of room-temperature-stable liquid peroxides (including at least one perketal), a promoter salt, a thiol-functionalized organicd accelerator and a free radical trap. The curable resin compositions are useful in pultrusion, cure-in-place pipe and resin transfer molding applications, among others.
Disclosed is a shear stable latex comprising fluoropolymer, a particle size modifier and a surfactant; said latex having solids content of at least 15 wt%, where the ratio of particle size modifier to surfactant is equal to or greater than 2 on a molar to molar basis.
4.
LARGE PARTICLE SIZE FUNCTIONALIZED FLUOROPOLYMER LATEX PREPARATION
Disclosed is a shear stable latex comprising functionalized fluoropolymer, a particle size modifier and a surfactant; said latex having solids content of at least 15 wt%, where the ratio of particle size modifier to surfactant is equal to or greater than 2 on a molar to molar basis.
Waterborne dispersions including crosslinkable multistage polymeric particles useful in coating compositions are provided. The multistage particles have a last-formed layer that includes a diketone functionality that is capable of crosslinking via a dihydrazide component also included in the dispersion. Another embodiment of the waterborne dispersion further includes crosslinkable latex particles having a diketone functionality that are capable of crosslinking with each other and/or the multistage particles via the dihydrazide component. An emulsion polymerization process for forming the multistage particles also is provided. Also provided are coating compositions that contain either embodiment of the waterborne dispersions.
Disclosed are voided latex particles, useful as opacifying agents for coating compositions containing organic solvents. The particles have a hollow interior, which substantially maintains its integrity after the particles are placed in contact with an organic solvent at 25° C. for 30 days. The particles also have a hydrophilic polymeric interior shell surrounding the hollow interior that is swellable with an aqueous swelling solution. The particles have first and second polymeric intermediate shells, surrounding the interior shell, formed from polymers that are different from each other and different from the interior shell polymer. Finally, the particles have an outer polymeric shell, surrounding the interior shells, which is formed from up to 100% by weight, as polymerized units, of methyl methacrylate. The interior shells and the outer shell each have a Tg greater than 60° C. Also disclosed is a multi-stage emulsion process for making the particles.
A method of reducing dispersion viscosity in a dispersion coating formulation is disclosed. The method comprises substituting a portion of the conventional PVDF in the formulation with a highly crystalline PVDF. The highly crystalline PVDF has a crystallinity 44% or greater (from X-ray diffraction). The highly crystalline PVDF imparts lower viscosity to the coating dispersion formulation.
This process for synthesizing thiopolymers involves feeding elemental sulfur or sulfides and unsaturated hydrocarbons into an extruder. The extruder is comprised of a screw and a barrel. The screw is rotated so as to pressurize, heat and mix the sulfur or sulfides and unsaturated hydrocarbon to induce inverse vulcanization thereby producing thiopolymers such as polymeric polysulfides. The invented process can be accomplished by using sulfur which becomes molten at the conditions in the extruder or is preheated and unsaturated hydrocarbons as the starting material. The materials are fed through one or more extruders so as to induce mixing and reaction of the materials forming polysulfides.
The invention relates to a coating composition and a coating comprised of fluoropolymer grafted with maleic anhydride, which is able to undergo crosslinking with polyisocyanate, to provide improved chemical resistance.
C09D 127/12 - Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
C08F 259/08 - Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group on to polymers containing fluorine
C07C 265/14 - Derivatives of isocyanic acid containing at least two isocyanate groups bound to the same carbon skeleton
C09D 5/00 - Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
10.
METHOD AND EXTRUDER FOR PREPARING A HIGH QUALITY BLOCK OF IMMOBILIZED ACTIVE MEDIA
Disclosed is a method and an extruder for making carbon blocks using poly (vinylidene fluoride) (PVDF) as binder and absorbents such as activated carbon.
B29C 48/395 - Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
B29C 48/80 - Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling at the plasticising zone, e.g. by heating cylinders
B29C 48/63 - Screws having sections without mixing elements or threads, i.e. having cylinder shaped sections
An aqueous emulsion composition useful as a binder for a non-aqueous battery electrode is provided. The composition includes a copolymer and an anionic surfactant that includes a sulfonate group or acid or salt form thereof. The anionic surfactant is not polymerizable with the copolymer. The copolymer includes as polymerized monomers: an ethylenically unsaturated ionic monomer including a phosphate or phosphonate group or salt or acid forms thereof; an ethylenically unsaturated ionic monomer including a sulfonate group or salt or acid forms thereof; a non-ionic monoethylenically unsaturated monomer; optionally an ethylenically unsaturated ionic monomer including a carboxylate group or salt or acid or anhydride form thereof; and optionally a monomer having at least two ethylenic unsaturations. A slurry composition including the aqueous emulsion composition and an active material is also provided.
The present invention provides methodes and composition for improving a froth flotation process for the removal of mineral values from aqueous solutions. The method uses mercaptide microemulsions to improve the separation effectiveness of a collector. The present invention provides a method of enhancing the performance of a collector in a froth flotation separation of mineral ore in a medium, the method comprising the steps of: forming a slurry by blending a collector microemulsion, the mineral ore in a medium, and optionally other additives, -and removing concentrate from the ore by sparging the slurry; wherein the collector microemulsion comprises a continuous phase which is an aqueous carrier fluid and a dispersed phase comprises a mercaptide.
A composite polymer process aid is provided. The process aid includes one or more inorganic mineral fillers and one or functionalized polymers. The functionalized polymers include at least one base polymer functionalized with an epoxy, hydroxyl, β-keto ester, β‑keto amide, or carboxylic acid reactive functional group. The composite polymer process aid is in the form of a plurality of individual particles. At least a portion of the individual particles include both inorganic mineral fillers and the functionalized polymers. The composite polymer modifier is formed by a process of: i) blending an aqueous solution, an aqueous dispersion, an aqueous suspension, an aqueous slurry, or a dry powder of the mineral fillers with an aqueous solution, an aqueous dispersion, an aqueous suspension or an aqueous emulsion of the functionalized polymers to form an aqueous blend, and ii) powderizing the aqueous blend to form the composite polymer process aid.
The invention discloses a dope solution for membrane fabrication comprising a blend of TEP with NMP as a solvent system in a process to make PVDF membranes, where PVDF resin comprises a homopolymer resin, or a copolymer of VDF and at least one of hexafluoroprdpylene, trifluoroethylene, chlorotrifluoroethylene, or a tetrafluoropropene.
B01D 67/00 - Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
C07D 207/02 - Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
The present invention pertains to a non-linear, copolymer comprising recurring units derived from vinylidene fluoride (VDF) monomer, at least one functional comonomer and optionally at least one fluorinated ethylenic comonomer. The non-linear fluorinated copolymer comprises from 0.01 to 3.0% by moles of recurring units derived from functional comonomer. The non-linear fluorinated copolymer can be used as electrode binder in batteries.
The invention relates to a method of preparation of an electrode slurry for all solid-state battery. Another subject matter of the invention is a process for making an electrode for all solid-state battery. The invention also concerns the solid-state lithium-ion batteries manufactured by incorporating said electrode.
H01M 4/62 - Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
H01M 4/525 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
H01M 4/505 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
B01D 67/00 - Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
B01D 69/02 - Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor characterised by their properties
19.
VINYL ACRYLIC EMULSION COPOLYMER AND USE THEREOF IN STAIN RESISTANT COATING COMPOSITIONS
Waterborne vinyl acetate-acrylic, “vinyl acrylic” emulsion copolymers which can be used in architectural coatings and impart stain resistance to such coatings are provided. The vinyl acrylic emulsion copolymer particles in the emulsion may contain one or more particle size modes, each with a respective narrow particle size distribution. The vinyl acrylic emulsion copolymers contain as a comonomer an ethylenically unsaturated monomer and also contain a hydrolyzable silane comonomer. The hydrolyzable silane may be present as a comonomer in the vinyl acrylic copolymer and/or may be added to the vinyl acrylic emulsion copolymer emulsion in the form of a hydrolyzable silane that may have a reactive group that is capable of reacting with the vinyl acrylic copolymer.
Encapsulated peroxide particles inhibit skin inflammation. A method of encapsulating a solid peroxide comprises dispersing solid peroxide particles (e.g., benzoyl peroxide) in an aqueous dispersion of fatty acid salt to form a peroxide/fatty acid salt dispersion, wherein the peroxide particles have a mean particle size (D50) of 10 μm or less; and subsequently encapsulating the solid peroxide particles by reacting the one or more monovalent fatty acid salts with one or more multivalent salts of calcium, magnesium, aluminum, silver, and/or zinc, thereby forming encapsulated peroxide particles.
The invention relates to an aqueous slurry composition comprising an aqueous-baed polymeric binder and anionic oxide nanoparticles that can be used, for example, in coating of electrodes and/or separators in electrochemical devices. This coating after drying, is highly porous, electronically isolating, and exhibits high dimensional stability at elevated temperatures.
H01M 50/446 - Composite material consisting of a mixture of organic and inorganic materials
C06B 45/32 - Compositions or products which are defined by structure or arrangement of component or product comprising a coated component the component base containing an inorganic explosive or an inorganic thermic component the coating containing an organic compound
Multi-stage polymeric particles are prepared as a water-borne emulsion, including a first-formed lower Tg soft stage and a second-formed higher Tg hard stage. The polymeric particles include, in both stages: one or more free radical polymerizable ethylenically unsaturated monomers; 0 to 3 wt % of free radical polymerizable surfactant monomer; 0 to 4 wt % of free radical poly-merizable monomer having a beta dicarbonyl functionality; 0 to 2 wt % of monomer selected from acrylamide, diacetone acrylamide, 2-hydroxyethyl (meth)acrylate, hydroxypropyl (meth)acrylates, and hydroxybutyl (meth)acrylates and mixtures thereof; 0-1.9 wt % of free radical polymerizable polyethylenically unsaturated monomers; 0.1 to 1.9% of free radical polymerizable monomer containing phosphorus acid or a salt thereof in the first stage, and 0.1 to 5 wt % of a free radical polymerizable monomer containing phosphorus acid or salt thereof in the second stage. Multi-stage polymeric-particle-based-resin is formulated into direct to metal coatings, having good block, corrosion and excellent humidity resistance.
C09D 147/00 - Coating compositions based on homolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds; Coating compositions based on derivatives of such polymers
There is provided a method for increasing the bulk density of low bulk density materials by gently admixing a low bulk density material and a liquid and thereafter removing substantially all of the liquid, for example, by evaporation.
A melt processable fluoropolymer composition comprising TFE, VDF and from 1 to 3 mol % fluorinated ether is disclosed. A method of making the polymer is also disclosed.
Copolymers of one or more halogenated olefins and one or more halogenated co-monomers selected from the group consisting of halogenated alkenyl ethers, halogenated alkenyl esters, and halogenated (meth)acrylates are useful in various end-use applications wherein the presence of halogen (e.g., fluorine) in the copolymer imparts one or more desirable properties, as compared to analogous copolymers not containing halogen.
Methods of blending liquid peroxide solutions and crystalline or amorphous solid materials to provide a dry-to-the-touch peroxide containing solid materials.
This invention describes the preparation and characterization of cross-linkable fluoropolymers, These cross-linkable fluoropolymers contain keto functional monomer. The keto functional monomer is incorporated on fluoropolymer while crosslinking agent was post-added after polymerization. The cross-linking reaction occurs after water/solvent evaporation or during melt processing.
C08L 27/12 - Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
C08L 51/00 - Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
Disclosed is a method for producing a battery electrode using a low solution viscosity polymeric binder composition where the binder composition comprises a fluoropolymer.
The present invention relates generally to the field of electrical energy storage in the lithium storage batteries of Li-ion type. More specifically, the invention relates to a binder for Li-ion battery positive electrode, to a method of preparation of said electrode and to its use in a Li-ion battery. Another subject matter of the invention is the Li-ion batteries manufactured by incorporating this electrode material.
H01M 4/62 - Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
H01M 4/58 - Selection of substances as active materials, active masses, active liquids of polyanionic structures, e.g. phosphates, silicates or borates
H01M 4/131 - Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
A beeswax and/or beehive or bee keeping equipment surface is treated with a composition containing at least one solvent, at least one surfactant and at least one oxidizing agent (e.g., peroxide), optionally also containing other components such as an oxidizing agent activator, a viscosifying agent, an enzyme and/or a pH control agent, to reduce the amount of pesticide residues on the beeswax surface and/or disinfect against any bacterial, viruses, and fungi infestation.
A01K 51/00 - Appliances for treating beehives or parts thereof, e.g. for cleaning or disinfecting
A01N 25/02 - Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
A01N 37/16 - Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group ; Thio-analogues thereof
A01N 59/00 - Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
31.
AZEOTROPE AND AZEOTROPE-LIKE COMPOSITIONS OF 1-CHLORO-1,2 DIFLUOROETHYLENE AND 2,3,3,3-TETRAFLUOROPROP-1-ENE
Provided are azeotrope or azeotrope-like compositions comprised of 1-chloro-1,2 difluoroethylene (R-1122a) and 2,3,3,3-tetrafluoropropene (HFO-1234yf) and uses thereof.
The present invention relates to heat transfer compositions comprising 1-chloro-1,2 difluoroethylene for use in refrigeration, air conditioning, heat pump systems, chillers, and other heat transfer applications. The inventive heat transfer compositions can possess reduced global warming potential while providing good capacity and performance while providing preferable flammability characteristics
C09K 5/04 - Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice-versa
C10M 171/00 - Lubricating compositions characterised by purely physical criteria, e.g. containing as base-material, thickener or additive, ingredients which are characterised exclusively by their numerically specified physical properties, i.e. containing ingredien
C09K 3/30 - Materials not provided for elsewhere for aerosols
C08J 9/14 - Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
33.
DEVICE TO RELEASE WATER AND ANTIMICROBIAL VAPOR INTO AN ENCLOSED OR PARTIALLY ENCLOSED SPACE
Devices and methods for provided both an antimicrobial vapor such as hydrogen peroxide and/or peracetic acid and water vapor in an enclosed or partially enclosed space are described. The device and method provided is for the reduction or elimination of microbes from air and surfaces in contact with air within an enclosed or partially enclosed space using hydrogen peroxide or peracetic acid in the vapor phase and also provide for humidity from water vapor. The device and method are directed towards a release of an antimicrobial vapor and water vapor through a permeable container/barrier containing a matrix into which water and an antimicrobial vapor producing material are absorbed.
B65D 81/24 - Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants
B65B 55/19 - Sterilising contents prior to, or during, packaging by adding materials intended to remove free oxygen or to develop inhibitor gases, e.g. vapour-phase inhibitors
A23B 7/144 - Preserving or ripening with chemicals not covered by group or in the form of gases, e.g. fumigation; Compositions or apparatus therefor
A23L 3/3427 - Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of gases, e.g. fumigation; Compositions or apparatus therefor in a controlled atmosphere, e.g. partial vacuum, comprising only CO2, N2, O2 or H2O in which an absorbent is placed or used
B01J 20/10 - Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
B01J 20/28 - Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
34.
REMOVAL OF RESIDUAL MERCAPTANS FROM POLYMER COMPOSITIONS
The removal of mercaptans from polymer compositions is described, where removal occurs by at least one of: contacting the polymer composition with a radical initiator that reacts with the mercaptain compound to form a non-odorous compound; and contacting the polymer composition with a transition metal that immobilizes the mercaptan compound.
C08G 81/02 - Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers at least one of the polymers being obtained by reactions involving only carbon-to-carbon unsaturated bonds
The present invention pertains to a non-linear, copolymer comprising recurring units derived from vinylidene fluoride (VDF) monomer, at least one functional comonomer and optionally at least one fluorinated ethylenic comonomer. The non-linear fluorinated copolymer comprises from 0.01 to 3.0% by moles of recurring units derived from functional comonomer. The non-linear fluorinated copolymer can be used as electrode binder in batteries.
An anionically-stabilized aqueous emulsion composition includes a) a first emulsion polymer having a Tg from −60° C. to 40° C.; b) a volatile base; and c) polymeric particles, different from the first emulsion polymer and present in emulsified form. The c) polymeric particles are polyamine graft copolymers, in which vinyl monomers form a polymer grafted to a water-soluble amino-group containing polymer. The anionically-stabilized aqueous emulsion composition may have a pH of from 8 to 11.
C09D 151/08 - Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
The invention relates to a composite block article having a polyamide binder interconnecting one or more types of interactive particles or fibers. The block article is useful in the separation of materials dissolved or suspended in fluids.
B01D 39/16 - Other self-supporting filtering material of organic material, e.g. synthetic fibres
B01J 20/28 - Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
B01D 53/02 - Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by adsorption, e.g. preparative gas chromatography
B01D 53/14 - Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by absorption
B01J 20/20 - Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising carbon obtained by carbonising processes
The polymerization of vinylidene fluoride at low reaction temperature in the presence of reducing agents especially Bruggolite® type Sulfinate, sulfonate, and sulfite reducing agents, combined with an inorganic initiator resulting in a predominately β phase fluoropolymer is disclosed.
Disclosed is a vinylidene fluoride (co)polymer having a beta phase intensity ratio of greater than 5 and the polymerization process for making the vinylidene fluoride based polymer or copolymer.
C08F 259/08 - Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group on to polymers containing fluorine
C08F 220/06 - Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
C08J 3/14 - Powdering or granulating by precipitation from solutions
H01M 4/02 - Electrodes composed of, or comprising, active material
A polyol pre-mix containing at least one halogenated hydroolefin blowing agent and having improved shelf life stability is provided, wherein each polyol combined with the halogenated hydroolefin blowing agent has an apparent pH of between 3 and 11.4. Controlling the apparent pH of the polyol(s) enables the polyol pre-mix to be stored for extended periods of time and then used in combination with organic polyisocyanate to produce foam formulations having gel times and tack free times not significantly different from those exhibited when freshly prepared polyol pre-mix is used.
C08J 9/14 - Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
C08G 18/18 - Catalysts containing secondary or tertiary amines or salts thereof
C08G 18/42 - Polycondensates having carboxylic or carbonic ester groups in the main chain
C08G 18/76 - Polyisocyanates or polyisothiocyanates cyclic aromatic
C08G 18/09 - Processes comprising oligomerisation of isocyanates or isothiocyanates involving reaction of a part of the isocyanate or isothiocyanate groups with each other in the reaction mixture
Formulations for producing modified bio-based polymers, especially bio-based polyesters like PLA and/or biodegradable polymers like PBAT, include at least one organic peroxide and at least one bio-based reactive additive. The at least one organic peroxide and/or the at least one bio-based reacted additive are capable of reacting with a bio-based polymer and/or biodegradable polymer to produce the modified bio-based and/or modified biodegradable polymer. The modified bio-based and/or modified biodegradable polymers have improved properties compared to non-modified bio-based and/or biodegradable polymers. The improved properties may related to processability, especially improved melt strength which results in easier processing while producing foamed polymers, thin films, such as blown film, cast film, tentered film and the like. The improved properties may be related to physical properties such as improved stiffness, toughness or tensile strength.
Non-polymeric coupling agent formulation for producing wood-polymer composites include at least one organic peroxide and a non-polymeric bio-based additive that includes at least one of a bio-based oil or a bio-based acid or derivatives of bio-based oils or acid is provided. The coupling agent formulations are capable of producing polymer matrix composites having improved strength and aging characteristics. The improved strength may be related to physical properties such as improved stiffness, toughness or tensile strength. A masterbatch utilizing the non-polymeric coupling agent formulation is provided, as well as a method making the masterbatch.
Embodiments of organic peroxide formulations provide longer scorch time protection and require fewer additives. The peroxide formulations may include, for example, at least one organic peroxide, and at least one scorch retardant additive selected from the group consisting of vitamin K1 (phlloquinone), K2 (menaquinone), K3 (menadione), olive leaf oil (oleuropein), and mixtures thereof.
A coupling agent formulation for cellulosic material-polymer composites is provided. The formulation includes a) at least one organic peroxide; and b) at least one of i) at least one zinc-containing reagent; and/or ii) at least one silicon-containing reagent. The coupling agent formulations produce polymer matrix cellulosic material composites with improved strength and aging characteristics. The improved strength may be related to physical properties such as improved stiffness, toughness or tensile strength. A masterbatch utilizing the coupling agent formulation is provided, as well as a method making the masterbatch.
Disclosed is a composition comprising a PVDF polymer, from 0.01-3% of one or more quaternary organic salts and 10 to 1000ppm of one or more dispersing agents, having reduced optical haze, high melt temperature, and high modulus. Also disclosed is a method of preparing the composition.
C08L 27/16 - Homopolymers or copolymers of vinylidene fluoride
C08L 27/12 - Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
Disclosed is a polymer process aid used to reduce or eliminate surface defects that can arise during extrusion of thermoplastic polymers. The polymer process aid comprises a thermoplastic vinylidene fluoride copolymer (A) having a melt viscosity at or above 25 kP. The VDF copolymer can be a VDF/HFP copolymer. The polymer process aid also contains at least one interfacial agent (B). Also disclosed is 1) a masterbatch (D) and articles containing the polymer process aid (A/B).
The present invention relates to a polyester-urethane composition. In particular, the invention relates to aliphatic alkyl ring-containing compositions that are useful for producing ultraviolet light resistant coatings. The invention further relates to pigmented and clear coating compositions formulated with the polyester-urethane composition of the present invention. The polyester-urethane compositions may be crosslinked.
Disclosed is a method for producing a battery electrode using a granulated polymeric binder composition where the binder composition comprises agglomerated particles wherein greater than 95% by weight of agglomerated particles are 400 um or greater but less than 2.5 mm and a bulk density of greater than 0.4 g/cc.
Organodisulfides blends having heterogeneous moieties of carbon chain length from 8 to 18 are useful stabilizers for polymer compositions, wherein the tendency of a polymer to degrade when exposed to environmental conditions such as heat, light and oxygen may be ameliorated by the incorporation of the heterogeneous organodisulfide blend.
Organodisulfides blends having heterogeneous moieties of carbon chain length from 8 to 18 are useful stabilizers for polymer compositions, wherein the tendency of a polymer to degrade when exposed to environmental conditions such as heat, light and oxygen may be ameliorated by the incorporation of the heterogeneous organodisulfide blend.
A method of reducing foamed density that results in a foamed polyvinyl chloride (PVC) component exhibiting reduced density. The foamed PVC component contains at least a PVC resin and a process aid blend. The process aid blend contains from 1 weight % to 60 weight % (based on the weight of the blend) of a functionalized process aid, and from 99 weight % to 40 weight % (based on the weight of the blend) of a non-functionalized process aid. The functionalized process aid includes at least one base polymer functionalized with a reactive epoxy, hydroxyl, β-keto ester, β-keto amide, or carboxylic acid functional group. The foamed PVC component containing the process aid blend has a lower density than a reference foamed PVC component made using the same process conditions and additives, but which contains only non-functionalized process aid and not the functionalized process aid.
C08L 63/00 - Compositions of epoxy resins; Compositions of derivatives of epoxy resins
C08L 33/08 - Homopolymers or copolymers of acrylic acid esters
C08L 33/10 - Homopolymers or copolymers of methacrylic acid esters
C08L 23/28 - Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or halogen-containing compounds
C08J 9/00 - Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
C08J 9/04 - Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
The use of compatible, semi-miscible or miscible polymer compositions as support structures for the 3D printing of objects, including those made from polyether-block-amide copolymers such as PEBAX® block copolymers from Arkema, polyamides such as RILSAN® polyamides from Arkema, polyether ketone ketone such as KEPSTAN® PEKK from Arkema, and fluoropolymers, such a KYNAR® PVDF from Arkema, especially objects of polyvinylidene fluoride and its copolymers. One particularly useful miscible polymer is an acrylic polymer, which is miscible with the fluoropolymer in the melt. The support structure composition provides the needed adhesion to the build plate and to the printed object and support strength during the 3D printing process, yet it is removable after the fluoropolymer object has cooled. The support polymer composition is selected to be stiff and low warping, yet flexible enough to be formed into filaments.
B29C 64/40 - Structures for supporting 3D objects during manufacture and intended to be sacrificed after completion thereof
B29C 64/112 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using individual droplets, e.g. from jetting heads
C08L 33/12 - Homopolymers or copolymers of methyl methacrylate
C08L 27/16 - Homopolymers or copolymers of vinylidene fluoride
C08L 77/00 - Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
C08G 65/00 - Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
A one-pack polymer modifier containing a) at least one process aid functionalized with a reactive epoxy, hydroxyl, β-keto ester, β-keto amide or carboxylic acid functional group, b) at least one impact modifier, c) optionally, at least one mineral filler and d) optionally, at least one further additive is useful for modifying the properties of thermoplastic polymers such as PVC, including reducing the surface gloss of an article prepared from the thermoplastic polymer and improving the impact strength of such an article.
An aqueous composition for coating cementitious or masonry substrates is provided. When dried, the coating composition has high gloss and low dirt pick-up. The composition includes at least one emulsified polymeric binder; at least one water-soluble silicate; at least one alkyl siliconate; at least one pigment, optionally at least one filler; optionally at least one paint additive; and water. The pigment volume concentration (PVC) of the aqueous composition is 40 weight % or less.
The invention relates to the use of a low Tg compatible resin as an adhesive layer for the welding of a thermoplastic composite structure to a thermoplastic or thermoset structure. The invention is especially good for the welding of large parts, such as wind turbine halves and spar caps. A useful thermoplastic composite is one formed by the infusion and curing of long fibers by a reactive acrylic liquid resin system, such as ELIUM® resin systems from Arkema.
B29C 65/42 - Applying molten plastics, e.g. hot melt between pre-assembled parts
C08L 33/10 - Homopolymers or copolymers of methacrylic acid esters
B32B 27/08 - Layered products essentially comprising synthetic resin as the main or only constituent of a layer next to another layer of a specific substance of synthetic resin of a different kind
A one-part composition includes by wt% of total weight of the composition: a) 5 to 70 wt% of at least one emulsified polymeric binder, the binder comprising one or more of (meth)acrylamide or derivatives thereof as a polymerized monomer; b) 1 to 55 wt% of at least one silicate; c) 0.01 to 10 wt% of at least one alkyl siliconate; d) water, and e) optional additives. The binder a) includes (meth)acrylamide or derivative thereof as a polymerized monomer and is in the form of emulsified polymeric particles having a volume average particle size of 50 nm - 500 nm.
An aqueous composition for coating cementitious or masonry substrates is provided. When dried, the coating composition has high gloss and low dirt pick-up. The composition includes at least one emulsified polymeric binder; at least one water-soluble silicate; at least one alkyl siliconate; at least one pigment, optionally at least one filler; optionally at least one paint additive; and water. The pigment volume concentration (PVC) of the aqueous composition is 40 weight % or less.
A method of coating a cementitious and/or masonry substrate includes applying an aqueous coating composition to the cementitious and/or masonry substrate. The aqueous coating composition includes at least one pigment, optionally at least one filler, at least one emulsified polymeric binder, at least one water-soluble silicate, and optionally at least one additive. The emulsified polymeric binder includes at least one of: a) (meth)acrylamide or derivative thereof as a polymerized monomer; or b) 1 weight % or more of at least one surfactant based on the total dry weight of the total monomer in the emulsified polymeric binder. The aqueous coating composition has a weight ratio of emulsified polymeric binder to the water-soluble silicate from 65:35 to 95:5 on a dry weight basis. The aqueous coating composition also has a pigment volume concentration (PVC) from 5% to 85.
B05D 3/10 - Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by other chemical means
B05D 7/00 - Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
B05D 7/14 - Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
A one-part composition includes by wt% of total weight of the composition: a) 5 to 70 wt% of at least one emulsified polymeric binder, the binder comprising one or more of (meth)acrylamide or derivatives thereof as a polymerized monomer; b) 1 to 55 wt% of at least one silicate; c) 0.01 to 10 wt% of at least one alkyl siliconate; d) water, and e) optional additives. The binder a) includes (meth)acrylamide or derivative thereof as a polymerized monomer and is in the form of emulsified polymeric particles having a volume average particle size of 50 nm - 500 nm.
A method of coating a cementitious and/or masonry substrate includes applying an aqueous coating composition to the cementitious and/or masonry substrate. The aqueous coating composition includes at least one pigment, optionally at least one filler, at least one emulsified polymeric binder, at least one water-soluble silicate, and optionally at least one additive. The emulsified polymeric binder includes at least one of: a) (meth)acrylamide or derivative thereof as a polymerized monomer; or b) 1 weight % or more of at least one surfactant based on the total dry weight of the total monomer in the emulsified polymeric binder. The aqueous coating composition has a weight ratio of emulsified polymeric binder to the water-soluble silicate from 65:35 to 95:5 on a dry weight basis. The aqueous coating composition also has a pigment volume concentration (PVC) from 5% to 85.
B05D 3/10 - Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by other chemical means
B05D 7/00 - Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
B05D 7/14 - Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
61.
METHOD TO PROCESS FLUORINATED THERMOPLASTIC ELASTOMERS
An injection molding process to mold a fluorinated thermoplastic elastomeric polymer composition is disclosed. An article made using the process has little shrinkage.
This invention discloses a reticulated film composite and a method of fabricating a reticulated film composite suitable as a 3 dimensional porous and conductive matrix which contains up to 80% porosity and exhibits high recovery after compression. The reticulated film composite is produced by casting and drying of a slurry which exhibits a high yield stress (i.e. greater than 50 dyne/cm2) and comprised of a high MW resin dissolved in a solvent (i.e. having solution viscosity of higher than 100 cp at 5% in NMP at room temperature) and dispersed nanoparticles of carbon of high specific surface areas (i.e. greater than 1 m2/g preferably greater than 10 m2/g), examples include but not limited to conductive carbon, carbon nanotubes, graphene, activated carbon or mixture thereof. This reticulated film composite exhibits high electrical conductivity (i.e. volume resistivity of less than 10,000 Ω·cm) and superior dimensional stability even at elevated temperatures (i.e. at 140° C.). It will exhibit a recovery of height or porosity after being compressed to over 50% of its height. The composite of this invention is suitable as an electrically conductive composite, as a gas diffusion layer in a fuel cell, or as a high efficiency electrode in super capacitors
C08J 9/00 - Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
C08J 9/28 - Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum
63.
METHOD FOR MONITORING A TUBE SHEET OF A HEAT EXCHANGER
Shell-and-tube devices typically require regular maintenance. Described herein is an automated method for tracking the status of individual tubes during maintenance activities and recording status data for review and analysis. Status data may optionally be reported in real-time summary format and/or used to predict time-to-completion. The method helps to reduce the expense of performing maintenance activities in shell-and-tube devices, including shell-and-tube reactors and heat exchangers.
F28D 7/00 - Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
F28F 11/00 - Arrangements for sealing leaky tubes or conduits
64.
METHOD FOR MONITORING A TUBE SHEET OF A HEAT EXCHANGER
Shell-and-tube devices typically require regular maintenance. Described herein is an automated method for tracking the status of individual tubes during maintenance activities and recording status data for review and analysis. Status data may optionally be reported in real-time summary format and/or used to predict time-to-completion. The method minimizes omission errors and helps to reduce the expense of performing maintenance activities in shell-and-tube devices, including shell-and-tube reactors and heat exchangers.
Shell-and-tube devices typically require regular maintenance. Described herein is an automated method for tracking the status of individual tubes during maintenance activities and recording status data for review and analysis. Status data may optionally be reported in real-time summary format and/or used to predict time-to-completion. The method minimizes omission errors and helps to reduce the expense of performing maintenance activities in shell-and-tube devices, including shell-and-tube reactors and heat exchangers.
Shell-and-tube devices typically require regular maintenance. Described herein is an automated method for tracking the status of individual tubes during maintenance activities and recording status data for review and analysis. Status data may optionally be reported in real-time summary format and/or used to predict time-to-completion. The method helps to reduce the expense of performing maintenance activities in shell-and-tube devices, including shell-and-tube reactors and heat exchangers.
F28D 7/00 - Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
F28F 11/00 - Arrangements for sealing leaky tubes or conduits
67.
WATER BASED BINDER COMPOSITION AND APPLICATION THEREOF
An electrode forming slurry composition is provided. The electrode-forming slurry compositions include a) from 10 to 300 parts of one or more particulate electrode-forming materials; b) from 0.1 to 60 parts of polymeric latex particles; and c)100 parts water. The electrode forming slurry compositions can form an electrode, an anode for a non-aqueous secondary battery, in particular a lithium ion battery. The polymeric latex particles b) include i) at least one ethylenically unsaturated monomer comprising at least one acid functional group; and include ii) no fluorinated monomer or butadiene monomer polymerized therein. Also provided is an anode including the electrode forming slurry composition in dried form.
A composition including a polymeric binder for the negative electrode of a secondary energy storage device is provided. The polymeric binder provides a matrix for particulate electrode-forming materials, which may include an active material and a conductive material. The polymeric binder contains acid functional groups. The polymeric binder also contains other functional monomers, which also may contribute to the performance of the polymeric binder in the negative electrode.
H01M 4/131 - Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M 4/62 - Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
H01G 11/28 - Electrodes characterised by their structure, e.g. multi-layered, porosity or surface features arranged or disposed on a current collector; Layers or phases between electrodes and current collectors, e.g. adhesives
H01G 11/38 - Carbon pastes or blends; Binders or additives therein
An electrode forming composition for use as the active material layer on a current collector of an electrode within a non-aqueous electrical energy storage device is provided. The electrode forming composition includes a) at least one particulate electrode-forming material, b) a polymeric binder. The polymeric binger includes at least one non-ionic monoethylenically unsaturated monomer and at least one particular oxyalkylated monomer with ethylenic unsaturation and terminated by hydrogen or an aryl or alkyl chain.
H01G 11/28 - Electrodes characterised by their structure, e.g. multi-layered, porosity or surface features arranged or disposed on a current collector; Layers or phases between electrodes and current collectors, e.g. adhesives
C07C 329/00 - Thiocarbonic acids; Halides, esters or anhydrides thereof
C07C 323/18 - Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton
C07C 323/20 - Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton with singly-bound oxygen atoms bound to carbon atoms of the same non-condensed six-membered aromatic ring
71.
COMPOSITE FUNCTIONALIZED ACRYLIC PROCESS AIDS FOR GLOSS AND SURFACE MODIFICATION
A composite polymer process aid is provided. The process aid includes one or more inorganic mineral fillers and one or functionalized polymers. The functionalized polymers include at least one base polymer functionalized with an epoxy, hydroxyl, β-keto ester, β-keto amide, or carboxylic acid reactive functional group. The composite polymer process aid is in the form of a plurality of individual particles. At least a portion of the individual particles include both inorganic mineral fillers and the functionalized polymers. The composite polymer modifier is formed by a process of: i) blending an aqueous solution, an aqueous dispersion, an aqueous suspension, an aqueous slurry, or a dry powder of the mineral fillers with an aqueous solution, an aqueous dispersion, an aqueous suspension or an aqueous emulsion of the functionalized polymers to form an aqueous blend, and ii) powderizing the aqueous blend to form the composite polymer process aid.
The invention relates to polymer blends comprised of a fluoropolymer and functional acrylic copolymer. The fluoropolymer is majority in the blend, accounting for 80 wt% or higher. The fluoropolymer can be polyvinylidene fluoride (PVDF) and its copolymers. VDF copolymer can contain fluorinated comonomers such as hexafluoropropylene (HFP), tetrafluoroethylene (TFE) etc, or functionalized monomers such as vinyl carboxylic acid, phosphoric, sulfonic acid and their salts. The functional acrylic copolymers are poly(methyl) methacrylate copolymers with functional containing monomers.
Disclosed is a composition comprising a PVDF copolymer where at least one comonomer is selected from Hexafluoropropene, 2,3,3,3-tetrafluoropropylene, 3,3,3-trifluoropropene, from 0.005-5% of one or more inorganic or polymeric nucleating additives and 0.01-20% of one or more dispersing agents having reduced haze. Also disclosed is a method of preparing the composition.
The present invention relates to optical fiber communication cables, and more particularly, relates to foamed polyvinylidene fluoride polymer filler rods used in optical fiber cable constructions. The foamed polyvinylidene fluoride polymer filler rod may or may not contain a central strength member. This invention includes cables containing the foamed PVDF filler rods of this invention. The present disclosure provides filler rods that have higher melting temperature than the conventional filler rods and methods of making the filler rods.
B32B 37/15 - Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state
G02B 6/44 - Mechanical structures for providing tensile strength and external protection for fibres, e.g. optical transmission cables
B32B 27/06 - Layered products essentially comprising synthetic resin as the main or only constituent of a layer next to another layer of a specific substance
B32B 27/08 - Layered products essentially comprising synthetic resin as the main or only constituent of a layer next to another layer of a specific substance of synthetic resin of a different kind
B32B 27/20 - Layered products essentially comprising synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
B32B 5/20 - Layered products characterised by the non-homogeneity or physical structure of a layer characterised by features of a layer containing foamed or specifically porous material foamed in situ
A connecting composition and a sealing coating for wire or cable insulation is disclosed. The connecting composition comprising a PVDF copolymer and a solvent. The solvent comprises cyclic ketone, wherein the weight percent of PVDF copolymer is from 20 to 40 wt.%, preferably 20 to 35 wt.% based on the total weight of PVDF copolymer and solvent. The PVDF copolymer comprises one or more comonomers and at least 75 wt.% vinylidene fluoride units, preferable at least 80% vinylidene fluoride units and has a melt viscosity of 2 to 12, preferably 4 and 10 kPoise at 230°C and 100s- 1.
C08L 27/16 - Homopolymers or copolymers of vinylidene fluoride
C09D 1/00 - Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
C09D 127/16 - Homopolymers or copolymers of vinylidene fluoride
F16L 9/147 - Compound tubes, i.e. made of materials not wholly covered by any one of the preceding groups comprising only layers of metal and plastics with or without reinforcement
F16L 11/118 - Hoses, i.e. flexible pipes made of rubber or flexible plastics with corrugated wall having arrangements for particular purposes, e.g. electrically conducting
F16L 11/15 - Hoses, i.e. flexible pipes made of rigid material, e.g. metal or hard plastics corrugated
H01G 11/06 - Hybrid capacitors with one of the electrodes allowing ions to be reversibly doped thereinto, e.g. lithium ion capacitors [LIC]
H01G 11/28 - Electrodes characterised by their structure, e.g. multi-layered, porosity or surface features arranged or disposed on a current collector; Layers or phases between electrodes and current collectors, e.g. adhesives
Feeding bees a composition containing at least one oxidizing agent (e.g., peroxide), optionally also containing other components such as an oxidizing agent activator or a viscosifying agent, to treat against, reduce and/or limit the spread of bacterial, virus, and fungi infestation in bees and/or beehives.
The invention relates to a fluoropolymer-acrylic coating composition that can be used, for example, in coating electrodes and/or separators in electrochemical devices. A coated separator for a lithium ion battery contains the porous separator substrate, and coatings on at least one side of the separator. The coating consists of an inorganic coating on at least one side of the separator, and an adhesive organic coating on at least one side of the inorganic coating or the separator. The organic coating contains an improved fluoropolymer-acrylic composition or a mixture of fluoropolymer and acrylic. The present invention can improve the adhesion of the coated separator to electrodes.
A coated separator for a lithium ion battery contains the porous separator substrate, and coatings on at least one side of the separator. The organic coating contains a silane functionalized fluoropolymer-acrylic composition or a mixture of silane functionalized fluoropolymer and non-silane functionalized fluoropolymer. The present invention can improve the adhesion of the coated separator to electrodes and offer good swelling properties in electrolyte.
H01M 50/46 - Separators, membranes or diaphragms characterised by their combination with electrodes
H01M 50/446 - Composite material consisting of a mixture of organic and inorganic materials
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
H01M 50/403 - Manufacturing processes of separators, membranes or diaphragms
C09J 127/22 - Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Adhesives based on derivatives of such polymers modified by chemical after-treatment
This invention discloses a method of fabricating a reticulated solid electrolyte/separator (RSES) which is suitable both as electrolyte and separator in a solid state battery. The reticulated composite is produced by casting and drying of a slurry which exhibits a high yield stress (greater than 50 dyne/cm2) and comprised of a high MW resin dissolved in a solvent (having solution viscosity of higher than 100 cp at 5% in NMP at room temperature) and dispersed nanoparticles of solid electrolyte of high specific surface areas (i.e. greater than 1 m2/g, preferable greater than 10 m2/g) including but not limited to LLZO, LSP, or LIPON or derivatives thereof. This reticulated solid electrolyte/separator exhibits superior cycling properties and high ionic conductivity, resists lithium dendrite penetration, and maintains a high dimensional stability (less than 10% shrinking) at elevated temperatures (up to 140° C.). In addition, the present disclosure relates to electrochemical cells comprising such a reticulated film composite to act as both electrolyte and separator.
The invention relates to a solid porous article having a crosslinked thermoplastic binder interconnecting one or more types of interactive powdery materials or fibers. The interconnectivity is such that the binder connects the powdery materials or fibers in discrete spots rather than as a complete coating, allowing the materials or fibers to be in direct contact with, and interact with a fluid. The resulting article is a formed multicomponent, interconnected web, with porosity. The separation article is useful in water purification, as well as in the separation of dissolved or suspended materials in both aqueous and non-aqueous systems in industrial uses, gas storage.
B01J 20/20 - Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising carbon obtained by carbonising processes
B01J 20/28 - Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
C02F 1/28 - Treatment of water, waste water, or sewage by sorption
B01D 15/00 - Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
B01D 53/04 - Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
This invention discloses a reticulated film composite and a method of fabricating the reticulated film composite suitable as a separator in electrochemical cells as sound absorbing films, or as high efficiency filtering media. The reticulated film composite is produced by casting and drying of a slurry which exhibits a high yield stress (i.e. greater than 50 dyne/cm2) and comprised of a high MW resin dissolved in a solvent (i.e. having solution viscosity of higher than 100 cp at 5% in NMP or in water at room temperature) and dispersed nanoparticles with high specific surface areas (i.e. greater than 10 m2/g) such as fumed alumina, or fumed silica, or fumed zirconia or mixture thereof. This reticulated film composite exhibits superior cycling properties and high ionic conductivity with a porosity up to 80% while maintains a high dimensional stability (i.e. less than 10% shrinking) at elevated temperatures (up to 140° C.). The reticulated composite separator coating can be used in combination with an electrode coating either in two separate process steps, or in a one-step process by having a simulations multi-layer casting of electrode and separator to manufacture a lithium ion battery.
C08J 9/28 - Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum
The invention relates a resin composition containing a polymer matting agent, that improves the aesthetic appearance of an article formed by Material Extrusion 3D printing. The composition contains 30 - 99.9wt% thermoplastic resin and 0.1 – 50 wt% of one or more spherical or near-spherical polymeric matting agents (PMAs) such as Altuglas Acryperl® beads from Arkema. Objects 3D printed from the composition have hidden layer lines (a.k.a. "build lines") and is more uniform in appearance, compared to an object printed from the same thermoplastic resin without PMAs.
B29C 64/165 - Processes of additive manufacturing using a combination of solid and fluid materials, e.g. a powder selectively bound by a liquid binder, catalyst, inhibitor or energy absorber
83.
Production of semicrystalline parts from pseudo-amorphous polymers
A method of manufacturing a semi-crystalline article from at least one pseudo-amorphous polymer including a poly aryl ether ketone, such as PEKK, including a softening step, wherein the at least one pseudo-amorphous polymer is heated to a temperature above its glass transition temperature to soften the polymer, and a crystallization step, wherein the at least one pseudo-amorphous polymer is heated to a temperature between its glass transition temperature and melting temperature, the pseudo-amorphous polymer being placed on a mold during either the softening step or the crystallization step before at least some crystallization takes place. The method results in articles demonstrating increased opacity, increased crystallinity, increased thermal resistance, improved chemical resistance, and improved mechanical properties over articles formed by traditional thermoforming processes.
A blowing agent for thermosetting foams is disclosed. The blowing agent is predominately the trans isomer of the hydrochlorofluoroolefin (HCFO) HFCO-1233zd alone or in combination with a hydrofluoroolefin (HFO), hydrofluorocarbon (HFC), hydrochlorofluoroolefin (HCFO), a hydrocarbon. The blowing agent is effective as a blowing agent in the manufacture of thermosetting foams.
C08L 79/00 - Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen, or carbon only, not provided for in groups
C08J 9/14 - Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
C08F 259/08 - Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group on to polymers containing fluorine
Waterborne dispersions including crosslinkable multistage polymeric particles useful in coating compositions are provided. The multistage particles have a last-formed layer that includes a diketone functionality that is capable of crosslinking via a dihydrazide component also included in the dispersion. Another embodiment of the waterborne dispersion further includes crosslinkable latex particles having a diketone functionality that are capable of crosslinking with each other and/or the multistage particles via the dihydrazide component. An emulsion polymerization process for forming the multistage particles also is provided. Also provided are coating compositions that contain either embodiment of the waterborne dispersions.
Waterborne dispersions including crosslinkable multistage polymeric particles useful in coating compositions are provided. The multistage particles have a last-formed layer that includes a diketone functionality that is capable of crosslinking via a dihydrazide component also included in the dispersion. Another embodiment of the waterborne dispersion further includes crosslinkable latex particles having a diketone functionality that are capable of crosslinking with each other and/or the multistage particles via the dihydrazide component. An emulsion polymerization process for forming the multistage particles also is provided. Also provided are coating compositions that contain either embodiment of the waterborne dispersions.
ABTRACT
ABTRACT
The present invention relates to a liquid, thermoplastic acrylic gel cap composition that can impart UV resistance, higher impact, and aesthetic effects to a composite material. Additionally, the post processing of the material when combined with a thermoplastic composite can allow for thermoformability, weldability and recyclability, unlike seen with traditional thermoset based gel coats.
A method of reducing dispersion viscosity in a dispersion coating formulation is disclosed. The method comprises substituting a portion of the conventional PVDF in the formulation with a highly crystalline PVDF. The highly crystalline PVDF has a crystallinity 44% or greater (from X-ray diffraction). The highly crystalline PVDF imparts lower viscosity to the coating dispersion formulation.
B32B 15/08 - Layered products essentially comprising metal comprising metal as the main or only constituent of a layer, next to another layer of a specific substance of synthetic resin
Disclosed are voided latex particles, useful as opacifying agents for coating compositions containing organic solvents. The particles have a hollow interior, which substantially maintains its integrity after the particles are placed in contact with an organic solvent at 25° C. for 30 days. The particles also have a hydrophilic polymeric interior shell surrounding the hollow interior that is swellable with an aqueous swelling solution. The particles have first and second polymeric intermediate shells, surrounding the interior shell, formed from polymers that are different from each other and different from the interior shell polymer. Finally, the particles have an outer polymeric shell, surrounding the interior shells, which is formed from up to 100% by weight, as polymerized units, of methyl methacrylate. The interior shells and the outer shell each have a Tg greater than 60° C. Also disclosed is a multi-stage emulsion process for making the particles.
A curable composition containing at least one of a haloalkyl ether (meth)acrylate or a haloalkenyl ether (meth)acrylate and, optionally, one or more different types of co-monomers is cured to provide a polymer having advantageous properties as a result of the incorporation of halogenated functionality derived from the haloalkyl/haloalkenyl ether (meth)acrylate monomer.
The invention relates to a method of preparation of an electrode slurry for all solid-state battery. Another subject matter of the invention is a process for making an electrode for all solid-state battery. The invention also concerns the solid-state lithium-ion batteries manufactured by incorporating said electrode.
The wet adhesion of a coating composition may be improved through the use of voided latex particles as opacifying agents which contain a hollow interior as well as an outer shell of a polymer containing functional groups such as amino, 1,3-diketo, urea or ureido. Other types of functional groups may be introduced to the outer shell polymer in order to vary other desired characteristics of the coating. The voided latex particles are non-film-forming.
C08F 265/06 - Polymerisation of acrylate or methacrylate esters on to polymers thereof
C08F 265/02 - Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group on to polymers of acids, salts or anhydrides
C08F 265/04 - Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group on to polymers of esters
C09D 151/00 - Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
B01J 13/20 - After-treatment of capsule walls, e.g. hardening
C08F 293/00 - Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
C09D 133/06 - Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
C09D 133/08 - Homopolymers or copolymers of acrylic acid esters
Disclosed is a method and an extruder for making carbon blocks using poly (vinylidene fluoride) (PVDF) as binder and absorbents such as activated carbon.
B29C 44/34 - Component parts, details or accessories; Auxiliary operations
B29C 48/25 - Component parts, details or accessories; Auxiliary operations
B29C 48/395 - Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
B29C 48/625 - Screws characterised by the ratio of the threaded length of the screw to its outside diameter [L/D ratio]
B29C 48/63 - Screws having sections without mixing elements or threads, i.e. having cylinder shaped sections
96.
COATING COMPOSITION WITH IMPROVED BLOCK AND HUMIDITY RESISTANCE, DIRECT TO METAL ADHERENCE AND LOW VOC CONTENT
Multi-stage polymeric particles are prepared as a water-borne emulsion, including a first-formed lower Tg soft stage and a second-formed higher Tg hard stage. The polymeric particles include, in both stages: one or more free radical polymerizable ethylenically unsaturated monomers; 0 to 3 wt% of free radical polymerizable surfactant monomer; 0 to 4 wt% of free radical polymerizable monomer having a beta dicarbonyl functionality; 0 to 2 wt% of monomer selected from acrylamide, diacetone acrylamide, 2-hydroxyethyl (meth)acrylate, hydroxypropyl (meth)acrylates, and hydroxybutyl (meth)acrylates and mixtures thereof; 0-1.9 wt% of free radical polymerizable polyethylenically unsaturated monomers; 0.1 to 1.9% of free radical polymerizable monomer containing phosphorus acid or a salt thereof in the first stage, and 0.1 to 5 wt% of a free radical polymerizable monomer containing phosphorus acid or salt thereof in the second stage. Multi-stage polymeric-particle-based-resin is formulated into direct to metal coatings, having good block, corrosion and excellent humidity resistance.
C08F 265/06 - Polymerisation of acrylate or methacrylate esters on to polymers thereof
C08K 5/523 - Esters of phosphoric acids, e.g. of H3PO4 with hydroxyaryl compounds
C09D 151/00 - Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
C09D 151/06 - Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
97.
COATING COMPOSITION WITH IMPROVED BLOCK AND HUMIDITY RESISTANCE, DIRECT TO METAL ADHERENCE AND LOW VOC CONTENT
Multi-stage polymeric particles are prepared as a water-borne emulsion, including a first-formed lower Tg soft stage and a second-formed higher Tg hard stage. The polymeric particles include, in both stages: one or more free radical polymerizable ethylenically unsaturated monomers; 0 to 3 wt% of free radical polymerizable surfactant monomer; 0 to 4 wt% of free radical polymerizable monomer having a beta dicarbonyl functionality; 0 to 2 wt% of monomer selected from acrylamide, diacetone acrylamide, 2-hydroxyethyl (meth)acrylate, hydroxypropyl (meth)acrylates, and hydroxybutyl (meth)acrylates and mixtures thereof; 0-1.9 wt% of free radical polymerizable polyethylenically unsaturated monomers; 0.1 to 1.9% of free radical polymerizable monomer containing phosphorus acid or a salt thereof in the first stage, and 0.1 to 5 wt% of a free radical polymerizable monomer containing phosphorus acid or salt thereof in the second stage. Multi-stage polymeric-particle-based-resin is formulated into direct to metal coatings, having good block, corrosion and excellent humidity resistance.
C08F 265/06 - Polymerisation of acrylate or methacrylate esters on to polymers thereof
C08K 5/523 - Esters of phosphoric acids, e.g. of H3PO4 with hydroxyaryl compounds
C09D 151/06 - Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
The invention relates to a process to produce a stable fluoropolymer latex using non-fluorinated surfactant with greater thermal stability. The polymerization is run at pressures greater than typically used. The resulting polymer exhibit improved melt color stability as compared to those produced under similar conditions at lower pressures.
The present disclosure is directed to a gas phase adsorption device comprising a large annulus and a small annulus block wherein the small annulus block is concentrically positioned inside the large annulus block. The present disclosure is also directed to a method for the storage of gas.
B01J 20/20 - Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising carbon obtained by carbonising processes
B01J 20/28 - Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
B01D 53/04 - Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
100.
SILICON- AND ZINC-CONTAINING COUPLING AGENT FOR CELLULOSIC MATERIAL-POLYMER COMPOSITES
A coupling agent formulation for cellulosic material-polymer composites is provided. The formulation includes a) at least one organic peroxide; and b) at least one of i) at least one zinc-containing reagent; and/or ii) at least one silicon-containing reagent. The coupling agent formulations produce polymer matrix cellulosic material composites with improved strength and aging characteristics. The improved strength may be related to physical properties such as improved stiffness, toughness or tensile strength. A masterbatch utilizing the coupling agent formulation is provided, as well as a method making the masterbatch.
