A masterbatch for foam molding which contains a base resin and heat-expandable microspheres. The base resin contains EPDM and the masterbatch contains the heat-expandable microspheres in an amount ranging from higher than 300 parts by weight to 750 parts by weight to 100 parts by weight of the base resin and has a Moony viscosity ML 1+4 (100° C.) ranging from 15 to 90. Also disclosed is a method for producing a masterbatch for foam molding, a resin composition containing the masterbatch for foam molding, and a foam-molded product manufactured by molding the resin composition.
C08J 3/22 - Compounding polymers with additives, e.g. colouring using masterbatch techniques
C08J 9/32 - Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof from compositions containing microballoons, e.g. syntactic foams
2.
HEAT-EXPANDABLE MICROSPHERES, PROCESS FOR PRODUCING THE SAME, AND APPLICATION THEREOF
Heat-expandable microspheres which have a blowing agent encapsulated efficiently therein so as to prevent the blowing agent from escaping out of the microspheres during storage at high temperature, a process for producing the same, and applications thereof. The process for producing heat-expandable microspheres containing a thermoplastic resin shell and a thermally vaporizable blowing agent encapsulated therein includes preparing an aqueous suspension in which oil droplets of an oily mixture containing the blowing agent and a polymerizable component are dispersed in an aqueous dispersion medium and fine particles of an inorganic compound and a monomer (A) and/or a monomer (B) described below are contained in the aqueous dispersion medium; and polymerizing the polymerizable component, wherein Monomer (A): Polymerizable unsaturated monomer having a total sulfuric acid value ranging from more than 0% to 35%; and Monomer (B): Polymerizable unsaturated monomer with a total phosphoric acid ranging from more than 0% to 50%.
C08J 9/20 - Making expandable particles by suspension polymerisation in the presence of the blowing agent
C08J 9/32 - Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof from compositions containing microballoons, e.g. syntactic foams
3.
HOLLOW RESIN PARTICLES FOR THERMOSENSITIVE RECORDING MEDIA
Hollow resin particles for thermosensitive recording media containing a thermoplastic resin shell and a hollow part surrounded by the shell. The hollow resin particles contain a thermally-vaporizable hydrocarbon in an encapsulation ratio of at least 0.2 wt %. The hollow resin particles preferably have a mean volume particle size ranging from 0.1 to 10 μm.
C09D 11/107 - Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
C08J 9/14 - Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
C08J 9/20 - Making expandable particles by suspension polymerisation in the presence of the blowing agent
C08J 9/232 - Forming foamed products by sintering expandable particles
B41M 5/44 - Intermediate or covering layers characterised by the macromolecular compounds
Heat-expandable microspheres including a thermoplastic resin shell and a thermally-vaporizable blowing agent encapsulated therein. The thermoplastic resin is a polymer of a polymerizable component containing a cross-linkable monomer (A) which has at least two (meth)acryloyl groups per molecule and a reactive carbon-carbon double bond in addition to the (meth)acryloyl groups and has a molecular weight of at least 500. Also disclosed are hollow resin particles manufactured by expanding the heat-expandable microspheres; fine-particle-coated hollow resin particles including the hollow resin particles; a composition including a base component and the heat-expandable microspheres, or hollow resin particles, or fine-particle coated hollow resin particles; and a formed article manufactured by forming the composition.
C08J 9/20 - Making expandable particles by suspension polymerisation in the presence of the blowing agent
C08J 9/232 - Forming foamed products by sintering expandable particles
C08F 236/12 - Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with nitriles
Heat-expandable microspheres containing a thermoplastic resin shell and a thermally-vaporizable blowing agent encapsulated therein. The thermoplastic resin is a polymer of a polymerizable component containing acrylonitrile, methacrylonitrile and acrylate ester and which satisfies specific conditions 1 and 2, where Condition 1: the amount of the acrylonitrile (A)
Also disclosed are hollow particles manufactured by expanding the heat-expandable microspheres; a composition containing a base compound and the heat-expandable microspheres or the hollow particles; and a formed product manufactured by molding or applying the composition.
A sizing agent for matrix-resin-reinforcement fibers that simultaneously attains excellent cohesion and abrasion resistance of sized fibers, uniform size application on fiber surface and good bonding between sized fiber and a matrix resin; a synthetic fiber strand sized therewith; and a fiber-reinforced composite material reinforced by the sized fiber strand. The sizing agent contains a polyamide (A), a carbodiimide group-containing compound (B) and water (C), wherein the polyamide (A) has a melt viscosity ranging from 100 to 15,000 mPa·s at 150° C. and the compound (B) has at least two carbodiimide groups per molecule. The polyamide (A) is preferably a water-soluble polyamide.
A resin composition containing heat-expandable microspheres including a thermoplastic resin shell and a thermally vaporizable blowing agent encapsulated therein and at least one base resin selected from rubbers, olefin resins and thermoplastic elastomers. The thermoplastic resin is a polymer of a polymerizable component containing N-substituted maleimide and a nitrile monomer containing methacrylonitrile. Also disclosed are molded articles manufactured by molding the resin composition.
B29C 44/50 - Feeding the material to be shaped into an open space or onto moving surfaces, i.e. to make articles of indefinite length using pressure difference, e.g. by extrusion or by spraying
B29C 44/02 - Shaping by internal pressure generated in the material, e.g. swelling or foaming for articles of definite length, i.e. discrete articles
C08J 3/22 - Compounding polymers with additives, e.g. colouring using masterbatch techniques
C08J 9/32 - Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof from compositions containing microballoons, e.g. syntactic foams
C08L 23/00 - Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
B29K 21/00 - Use of unspecified rubbers as moulding material
Hollow resin particles, a production process for producing the same and application thereof. The hollow resin particles include a thermoplastic resin shell and a hollow part surrounded by the shell. The thermoplastic resin is a polymer produced from a polymerizable component containing 0.6 to 3.0 wt % of a crosslinkable monomer having at least two polymerizable carbon-carbon double bonds per molecule and 97 to 99.4 wt % of an uncrosslinkable monomer having one polymerizable carbon-carbon double bond per molecule. A blowing agent is encapsulated in the hollow resin particles. The blowing agent contains 50 to 100 wt % of an organic compound having a vapor pressure higher than 100 kPa at 25° C. Further, the encapsulation ratio of the blowing agent ranges from 3 to 13 wt % of the hollow resin particles.
C08J 9/232 - Forming foamed products by sintering expandable particles
C08J 9/32 - Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof from compositions containing microballoons, e.g. syntactic foams
C08F 2/44 - Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
C08L 27/06 - Homopolymers or copolymers of vinyl chloride
B01J 13/18 - In situ polymerisation with all reactants being present in the same phase
C08F 220/48 - Acrylonitrile with nitrogen-containing monomers
C08F 220/46 - Acrylonitrile with carboxylic acids, sulfonic acids or salts thereof
C08L 33/18 - Homopolymers or copolymers of nitriles
C08J 9/14 - Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
10.
Rubber composition for vulcanization molding, process for manufacturing the same and application thereof
A rubber composition for vulcanization molding which can be manufactured into a rubber product with good dimensional stability, good appearance and sufficiently light weight, a process for manufacturing the same, and applications thereof. A rubber composition for vulcanization molding containing hollow particles and a base rubber, wherein the hollow particles are composed of a thermoplastic resin shell and a thermally vaporizable blowing agent encapsulated therein and have a specified further expansion ratio, and the base rubber has a Mooney viscosity ML (1+4) ranging from 5 to 90 at 100° C. Also disclosed is a process for manufacturing the rubber composition, hollow particles used for manufacturing the rubber composition, a masterbatch including the hollow particles and a rubber product manufactured from the rubber composition.
C08J 9/18 - Making expandable particles by impregnating polymer particles with the blowing agent
C08J 9/22 - After-treatment of expandable particles; Forming foamed products
B29B 7/74 - Mixing; Kneading using other mixers or combinations of dissimilar mixers
C08J 9/32 - Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof from compositions containing microballoons, e.g. syntactic foams
C08J 3/22 - Compounding polymers with additives, e.g. colouring using masterbatch techniques
B29C 35/08 - Heating or curing, e.g. crosslinking or vulcanising by wave energy or particle radiation
B29B 7/18 - Mixing; Kneading non-continuous, with mechanical mixing or kneading devices, i.e. batch type with movable mixing or kneading devices rotary with more than one shaft
A process for producing heat-expandable microspheres which enables constant and high-yield production of heat-expandable microspheres having a mean particle size ranging from 0.01 to 10 μm without deteriorating their expansion performance, and the application thereof. The process produces heat-expandable microspheres containing a thermoplastic resin shell and the blowing agent encapsulated therein. The process includes a step of dispersing a polymerizable component and the blowing agent in an aqueous dispersion medium containing a polyester amide having an acid value (mgKOH/g) ranging from 95 to 140 and a step of polymerizing the polymerizable component.
C08J 9/20 - Making expandable particles by suspension polymerisation in the presence of the blowing agent
B01J 13/18 - In situ polymerisation with all reactants being present in the same phase
C08J 9/32 - Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof from compositions containing microballoons, e.g. syntactic foams
Heat-expandable microspheres and applications thereof, the heat-expandable microspheres including a thermoplastic resin shell and a thermally-vaporizable blowing agent encapsulated therein. The thermoplastic resin is produced by polymerizing a polymerizable component containing (A) a nitrile monomer including methacrylonitrile, (B) a carboxyl-group-containing monomer and (C) a monomer having a functional group reactive with the carboxyl group. The polymerizable component satisfies the following conditions 1 and 2:
B) Inequality (I)
Condition 2: The ratio by weight of the monomer (B) to the monomer (C) ranges from 600:1 to 3:1.
C08J 9/32 - Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof from compositions containing microballoons, e.g. syntactic foams
C08F 2/44 - Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
C08F 220/06 - Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
C08J 9/00 - Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
C08J 9/32 - Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof from compositions containing microballoons, e.g. syntactic foams
A synthetic fiber finish includes a lubricant (A), a polyhydric alcohol fatty acid ester having at least one hydroxyl group per molecule (B), and an organic sulfonic acid compound (C). The lubricant (A) includes a sulfur-containing ester (A3). The amount of the lubricant (A) ranges from 50 to 90 wt %, the amount of the ester (B) ranges from 1 to 20 wt % and the amount of the sulfur-containing ester (A3) ranges from 5 to 20 wt %, to a nonvolatile component of the finish.
Heat-expandable microspheres including a thermoplastic resin shell and a thermally-vaporizable blowing agent encapsulated therein. The thermoplastic resin is produced by polymerizing a polymerizable component containing (A) a nitrile monomer including acrylonitrile and methacrylonitrile, (B) a carboxyl-group-containing monomer, and (C) a monomer copolymerizable with the nitrile monomer (A) and the carboxyl-group-containing monomer (B). Further, the amount of the acrylonitrile in the nitrile monomer (A) ranges from 0.1 to 9 wt % based on the nitrile monomer (A). Also disclosed are hollow particles manufactured by heating and expanding the heat-expandable microspheres; a composition containing a base compound and at least one particulate material selected from the heat-expandable microspheres and the hollow particles; and a formed product manufactured by molding or applying a coat of the composition.
Heat-expandable microspheres having an almost spherical shape and high expansion performance and exhibiting good workability when mixed with a resin, a process for producing the heat-expandable microspheres, and applications thereof. The heat-expandable microspheres include a thermoplastic resin shell and a blowing agent encapsulated therein and vaporizable by heating. The thermoplastic resin is produced by polymerizing a polymerizable component containing a methacrylate monomer and a carboxyl-containing monomer, and optionally containing a nitrile monomer in an amount ranging from 0 to 30 parts by weight to 100 parts by weight of the total amount of the methacrylate monomer and the carboxyl-containing monomer. The blowing agent contains a hydrocarbon having at least 8 carbon atoms per molecule.
C08F 220/00 - Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide, or nitrile thereof
B01J 13/18 - In situ polymerisation with all reactants being present in the same phase
C08J 9/00 - Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
C08J 9/14 - Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
C08J 9/32 - Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof from compositions containing microballoons, e.g. syntactic foams
17.
Process for producing heat-expandable microspheres and application thereof
A process for producing heat-expandable microspheres including a thermoplastic resin shell and a blowing agent encapsulated therein. The process includes the steps of dispersing a polymerizable component and the blowing agent in an aqueous dispersion medium having a pH of 7 or less and containing a fine-particle metal compound having a mean particle size ranging from 1.0 to 10 nm, and polymerizing the polymerizable component. The amount of the fine-particle metal compound ranges from 0.15 to 20 parts by weight to 100 parts by weight of the total amount of the polymerizable component and the blowing agent. Also disclosed are heat-expandable microspheres produced by dispersing a polymerizable component and a blowing agent in an aqueous dispersion medium containing colloidal silica and polymerizing the polymerizable component. Also disclosed is a composition containing the heat-expandable microspheres and a base component, a formed product, a slurry composition for use in forming a negative electrode of a lithium-ion secondary battery and a negative electrode.
C08J 9/14 - Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
max are as defined herein. Also disclosed in a process for producing the heat-expandable microspheres which includes preparing an aqueous suspension comprising oily globules dispersed in an aqueous dispersion medium containing a hydrophilic cross-linking agent, wherein the oily globules are made of an oily mixture comprising the blowing agent and a monomer component; and polymerizing the monomer component.
C08J 9/20 - Making expandable particles by suspension polymerisation in the presence of the blowing agent
C08J 9/32 - Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof from compositions containing microballoons, e.g. syntactic foams
An acrylic-fiber finish for carbon fiber production is prepared into a stable emulsion and applied to a carbon-fiber precursor to prevent gumming up of finish components in precursor production and carbon fiber fusing in baking process. The acrylic-fiber finish is used for carbon-fiber production and includes a modified silicone having a modifying group containing a nitrogen atom and an acidic phosphate ester represented by the following chemical formula (1).
2-4 alkylene group, and AO represents an oxyalkylene group, n represents a mole number of oxyalkylene group and is an integer ranging from 0 to 20, and each of a and b is an integer of 1 or 2 and meets the equation a+b=3.
D01F 9/24 - Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from polyaddition, polycondensation or polymerisation products from macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
C08K 5/5419 - Silicon-containing compounds containing oxygen containing at least one Si—O bond containing at least one Si—C bond
C08K 5/521 - Esters of phosphoric acids, e.g. of H3PO4
D01F 6/38 - Monocomponent man-made filaments or the like of synthetic polymers; Manufacture thereof from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds comprising unsaturated nitriles as the major constituent
D06M 13/292 - Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
D06M 15/643 - Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
D01F 9/22 - Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from polyaddition, polycondensation or polymerisation products from macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyacrylonitriles
20.
Sizing agent for reinforcement fibers, and application thereof
4-14 monohydric alcohol. When water is added to the sizing agent thereby producing a mixture with a nonvolatile content of 1 weight %, the mixture exhibits a dynamic surface tension ranging from 40 to 55 mN/m determined by the maximum bubble pressure method when bubbles are blown into the mixture at the rate of one bubble per 100 milliseconds.
D06M 15/27 - Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof of alkylpolyalkylene glycol esters of unsaturated carboxylic acids
C08J 5/06 - Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials
D06M 13/224 - Esters of carboxylic acids; Esters of carbonic acid
D06M 15/572 - Reaction products of isocyanates with polyesters or polyesteramides
Heat-expandable microspheres with high encapsulation efficiency of a blowing agent and good heat-expansion performance, a process for reproducibly producing the heat-expandable microspheres and application thereof are provided. The heat-expandable microspheres comprise essentially a thermoplastic resin shell and a blowing agent encapsulated therein, and contain not more than 500 ppm of silicon, not more than 350 ppm of aluminum and not more than 600 ppm of the total of the silicon and aluminum. The heat-expandable microspheres retain at least 70% of the blowing agent encapsulated therein at the temperature which is the average of their expansion-initiation temperature and maximum expansion temperature.
A method that produces heat-expandable microspheres includes the use of a shell of thermoplastic resin and a non-fluorine blowing agent encapsulated therein having a boiling point not higher than the softening point of the thermoplastic resin. The method includes a step of dispersing an oily mixture containing a polymerizable component, the blowing agent, and a polymerization initiator containing a peroxydicarbonate in an aqueous dispersing medium to polymerize the polymerizable component contained in the oily mixture. The resultant heat-expandable microspheres have a shell which is less apt to become thinner than its theoretical value, contain minimum amount of resin particle inside their shell, and have excellent heat-expanding performance.
The present invention provides heat-expanded microspheres having high packing efficiency, and a production method thereof. The heat-expanded microspheres are produced by expanding heat-expandable microspheres, which comprise shell of thermoplastic resin and a blowing agent encapsulated therein having a boiling point not higher than the softening point of the thermoplastic resin and have an average particle size from 1 to 100 micrometer, at a temperature not lower than their expansion initiating temperature, and the heat-expanded microspheres result in a void fraction not higher than 0.70.
B32B 1/00 - Layered products essentially having a general shape other than plane
B32B 5/16 - Layered products characterised by the non-homogeneity or physical structure of a layer characterised by features of a layer formed of particles, e.g. chips, chopped fibres, powder
C08J 9/22 - After-treatment of expandable particles; Forming foamed products
C08J 9/00 - Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
24.
Heat-expandable microspheres and a method of making heat-expandable microspheres and application thereof
Heat-expandable microspheres having high heat resistance and high solvent resistance, a production process thereof include a shell of a thermoplastic resin and a thermally vaporizable blowing agent being encapsulated therein. The thermoplastic resin includes a copolymer produced by polymerizing a polymerizable component containing a carboxyl-group-containing monomer. The surface of the heat-expandable microspheres is treated with an organic compound containing a metal of the Groups from 3 to 12 in the Periodic Table.
An acrylic-fiber finish for use in carbon-fiber production contributes to high tenacity of resultant carbon fiber. The acrylic-fiber finish for carbon-fiber production includes an epoxy-polyether-modified silicone and a surfactant. The weight ratios of the epoxy-polyether-modified silicone and the surfactant in the total of the non-volatile components of the finish respectively range from 1 to 95 wt % and from 5 to 50 wt %. The carbon fiber production method includes a fiber production process for producing an acrylic fiber for carbon-fiber production by applying the finish to an acrylic fiber which is a basic material for the acrylic fiber for carbon-fiber production; an oxidative stabilization process for converting the acrylic fiber produced in the fiber production process into oxidized fiber in an oxidative atmosphere at 200 to 300 deg.C.; and a carbonization process for carbonizing the oxidized fiber in an inert atmosphere at 300 to 2,000 deg.C.
B05D 3/02 - Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
H01L 23/29 - Encapsulation, e.g. encapsulating layers, coatings characterised by the material
Heat-expandable microspheres include a shell of thermoplastic resin and core material encapsulated in the shell. The core material include a blowing agent having a boiling point not higher than the softening point of the thermoplastic resin and a gas migration inhibitor having a boiling point higher than the softening point of the thermoplastic resin. The ratio of the gas migration inhibitor to the core material is at least 1 weight percent and below 30 weight percent. The average particle size of the heat-expandable microspheres ranges from 1 to 100 micrometers.
A production method for heat-expandable microspheres, which have high expanding ratio and are thermally expanded into hollow particulates having excellent repeated-compression durability, and application thereof are provided. The method produces heat-expandable microspheres a shell of thermoplastic resin and a blowing agent being encapsulated therein and having a boiling point not higher than the softening point of the thermoplastic resin.
Heat-expanded microspheres having high packing efficiency are produced by expanding heat-expandable microspheres, which include a shell of thermoplastic resin and a blowing agent encapsulated therein having a boiling point not higher than the softening point of the thermoplastic resin and have an average particle size from 1 to 100 micrometer, at a temperature not lower than their expansion initiating temperature, and the heat-expanded microspheres result in a void fraction not higher than 0.70.
A finish for acrylic fiber to be processed into carbon fiber includes an ester compound having at least three ester groups in its molecule and a silicone compound, wherein the silicone compound constitutes 10 to 50 weight percent of the whole of the nonvolatile matter of the finish. A method of manufacturing carbon fiber includes the processes of applying the finish for acrylic fiber to be processed into carbon fiber to acrylic fiber to be processed into carbon fiber; oxidative-stabilizing the finish-applied acrylic fiber in an oxidizing atmosphere at 200 to 300 deg. C. to convert the fiber into oxidized fiber; and carbonizing the oxidized fiber in an inert atmosphere at 200 to 3000 deg. C.
B05D 3/02 - Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
C09D 1/00 - Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
D06M 13/224 - Esters of carboxylic acids; Esters of carbonic acid
D01F 11/06 - Chemical after-treatment of man-made filaments or the like during manufacture of synthetic polymers of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
D01F 9/22 - Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from polyaddition, polycondensation or polymerisation products from macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyacrylonitriles
D06M 13/00 - Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
D06M 15/643 - Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
A method that heat-expandable microspheres includes the use of a shell of thermoplastic resin and a non-fluorine blowing agent encapsulated therein having a boiling point not higher than the softening point of the thermoplastic resin. The method includes, a step of dispersing an oily mixture containing a polymerizable component, the blowing agent, and a polymerization initiator containing a peroxydicarbonate in an aqueous dispersing medium to polymerize the polymerizable component contained in the oily mixture. The resultant heat-expandable microsphres have a shell which is less apt to become thinner than its theoretical value, contain minimum amount of resin particle inside their shell, and have excellent heat-expanding performance.
Heat-expandable microspheres include a shell of thermoplastic resin and a blowing agent encapsulated therein having a boiling point not higher than the softening point of the thermoplastic resin, have a maximum expanding ratio not lower than 50 times, and are thermally expanded into hollow particulates having a repeated-compression durability not lower than 75 percent. The method of producing the heat-expandable microspheres includes the steps of dispersing an oily mixture containing a polymerizable component and the blowing agent in an aqueous dispersing medium containing a specific water-soluble compound and polymerizing the polymerizable component contained in the oily mixture.
A production process for heat-expanded microspheres includes the step of providing a gaseous fluid containing heat-expandable microspheres, which includes a shell of thermoplastic resin and a blowing agent encapsulated therein having a boiling point not higher than the softening point of the thermoplastic resin and have an average particle size from 1 to 100 μm. The gaseous fluid is fed through a gas-introducing tube having a dispersion nozzle on its outlet that is fixed inside a conduit having a hot gas flow flowing therethrough. A jet of the gaseous fluid is emitted through the dispersion nozzle. Further, the gaseous fluid is collided on a collision plate fixed under the dispersion nozzle so as to disperse the heat-expandable microspheres in the hot gas flow. The dispersed heat-expandable microspheres are heated in the hot gas flow at a temperature not lower than their expansion initiating temperature and thus expanded.
Thermo-expansive microcapsule comprising: a polymeric shell produced by polymerizing 15 to 75 weight % of a nitrile monomer, 10 to 65 weight % of a monomer having a carboxyl group, 0.1 to 20 weight % of a monomer having an amide group and 0.1 to 20 weight % of a monomer having a cyclic structure in its side chain; and a blowing agent encapsulated in the polymeric shell.
B32B 5/16 - Layered products characterised by the non-homogeneity or physical structure of a layer characterised by features of a layer formed of particles, e.g. chips, chopped fibres, powder
patents
