A hydrogen concentration-controllable safe reaction tank for leaching of waste battery powder, includes at bed provided with supporting frames and a driver; a rotary acid pumping barrel articulated with the supporting frames, the driver being configured to drive the rotary acid pumping barrel to rotate, and a delivery pipe mounted on the bed and passing through the rotary acid pumping barrel where a screw for pushing material is disposed in the delivery pipe; the delivery pipe includes a pouring section located in the rotary acid pumping barrel, the pouring section is provided with a pouring opening at an upper portion and acid leakage holes at a bottom, and at least one acid pumping plate is mounted on an inner wall of the rotary acid pumping barrel.
A preparation method of nano-scaled iron phosphate, includes the steps of: adding a surfactant and a polymer microsphere to an iron salt solution to obtain a mixed liquid; adding a phosphate solution to the mixed liquid for reaction to obtain an iron phosphate slurry; performing solid-liquid separation after removing the polymer microsphere from the iron phosphate slurry, drying and calcining the obtained solid to obtain a nano-scaled iron phosphate.
C01B 25/45 - Phosphates containing plural metal, or metal and ammonium
H01M 4/58 - Selection of substances as active materials, active masses, active liquids of polyanionic structures, e.g. phosphates, silicates or borates
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
3.
Method for preparing lithium iron phosphate by recycling waste batteries
A method of preparing lithium iron phosphate by recycling and utilizing waste batteries. The method may include pre-processing a waste lithium iron phosphate battery to obtain lithium iron phosphate powder, adding alkaline liquid to the lithium iron phosphate powder, and filtering to obtain a filter residue; an iron source, a lithium source or a phosphorus source to the filter residue, and performing ball milling to obtain a ball-milled product; preparing a carbon source solution, and adding a surfactant to the carbon source solution to obtain a mixed solution; mixing the ball-milled product and the mixed solution, performing spray pyrolysis to obtain a high-temperature powder, spraying atomized water to the high-temperature powder to remove impurities, and then calcining to obtain a finished product of lithium iron phosphate.
A method for safely oxidising roasting NdFeB powder material. The method may include: S1: magnetizing and drying the NdFeB powder material; S2: heating the magnetized and dried NdFeB powder material to spontaneous combustion, and then preparing the spontaneous combustion product into a powder; and S3: magnetizing and then oxidising roasting the powder to obtain NdFeB oxide.
A fire-extinguishing agent capable of extinguishing the combustion of aluminum slag, and a preparation method therefor and the use thereof. The fire-extinguishing agent comprises the following raw materials: a sulfate, a chlorine salt, a mineral, a silica gel, a surfactant and a stearate. The main materials of sulfate and chlorine salt are solid waste containing sulfate and chlorine salt obtained by separating high-salt wastewater generated during a resynthesis process of a positive electrode material of a waste lithium battery. The solid waste containing sulfate and chlorine salt is used as a material for a fire-extinguishing agent, which can effectively recycle waste resources. The wastewater of a large amount and high salt content produced in the synthesis process of the positive electrode material of the waste lithium battery is separated and evaporated to obtain more solid wastes containing sulfate and chlorine salt, which can be used as the main material for preparing fire-extinguishing agents on a large scale.
A treatment method of scrapped positive electrode slurry, includes the following steps: pretreating the scrapped positive electrode slurry to obtain a slurry solution; performing electrophoresis coagulation and filter pressing on the slurry solution to obtain a liquid phase and a solid phase; and performing gradient roasting on the solid phase to obtain a positive electrode material.
A reaction kettle cleaning apparatus, includes a kettle body and a stirrer, the stirrer being located in the kettle body and including a stirring rod and a stirring portion, where a movable frame is disposed on the stirring rod and is movable along the stirring rod; and a cleaning device is disposed on the movable frame is configured to clean the kettle body; and the reaction kettle cleaning apparatus further includes a movable control apparatus configured to control the movable frame to move.
A method for removing impurities from a waste lithium battery safely through pyrolysis. The method may include: (1) performing primary roasting on electrode fragments of a waste lithium battery, quenching, and then layered screening to obtain a current collector fragment and an electrode material; (2) mixing and grinding the electrode material and a grinding aid, soaking the mixture in an alkali liquor, filtering and taking out filter residues to obtain electrode powder, and (3) performing secondary roasting on the electrode powder to obtain a positive electrode material.
The invention discloses a method for preparing graphene by mechanical exfoliation and application thereof. The method includes the following steps of: (1) dispersing graphite raw material in a foaming agent aqueous solution to obtain a graphite pre-dispersing solution; and (2) subjecting the graphite pre-dispersing solution to milling, washing with water, and centrifugal classification, to obtain the graphene; wherein the foaming agent aqueous solution includes the following components: sodium alpha-olefin sulfonate, sodium alcohol ether sulphate, diethanolamine coconut fatty acid, polyethylene glycol, and water. In the invention, the foaming agent produce a large amount of stable and fine foam in a closed milling cavity, which can produce jostle effect, support the graphite, and increase the contact area between the graphite and the milling medium, so as to achieve good exfoliation effect.
The invention discloses a method and application for a safe recovery of waste anode pieces of lithium ion batteries. The method comprises the following steps: crushing and sieving the waste anode piece to obtain an anode powder A and a crushed aluminum slag; mixing the crushed aluminum slag with an acid solution, stirring under ultrasound, and then performing wet sieving to obtain an aluminum slag and a battery powder; the obtained aluminum slag is washed with water, then rinsed with an explosion suppressant, centrifuging to obtain an explosion suppressing aluminum slag, and then packed and compressed to obtain an aluminum slag block; connecting the two ends of the aluminum slag block to a positive plate and a negative plate of a DC electrode respectively, applying a current to melt the aluminum slag block, and cooling to obtain a safe aluminum slag block.
4 structure contains the doping elements, which work together to improve the interfacial activity of the material and introduce more electrochemically active sites.
H01M 4/525 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
H01M 4/505 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
H01M 4/02 - Electrodes composed of, or comprising, active material
12.
Ternary single crystal positive electrode material, preparation method therefor and use thereof
Disclosed are a ternary single crystal positive electrode material, a preparation method therefor and use thereof. The preparation method comprises the following steps: mixing a ternary polycrystalline micropowder, raising a temperature, carrying out a primary sintering, and lowering the temperature to obtain an intermediate; subjecting the intermediate to jet pulverization to obtain a single crystal material, washing the single crystal material with water, and centrifugally drying the single crystal material to obtain a material with a residual alkali content of less than 1500 ppm; and adding a coating agent to the material, raising a temperature, carrying out a secondary sintering, and lowering the temperature to obtain the ternary single crystal positive electrode material. In the present disclosure, by using a jet pulverization device to open a polycrystalline material to form small single crystal particles, the electrochemical performance and the energy density of the material is improved.
H01M 4/505 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
H01M 4/525 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
H01M 4/02 - Electrodes composed of, or comprising, active material
13.
METHOD FOR PURIFYING NICKEL-COBALT-MANGANESE LEACHING SOLUTION
Disclosed is a method for purifying a nickel-cobalt-manganese leaching solution. The method may include: heating a nickel-cobalt-manganese leaching solution, adding a manganese powder thereto, adjusting the pH, reacting same, and filtering same to obtain iron-aluminum slag and a liquid with iron and aluminum removed therefrom; heating the liquid with iron and aluminum removed therefrom, adding a manganese powder thereto, adjusting the pH, reacting same, and filtering same to obtain copper slag and a solution with copper removed therefrom; heating the solution with copper removed therefrom, adding an alkaline solution thereto, adjusting the pH, reacting same, and filtering same to obtain a nickel-cobalt-precipitated solution and nickel-cobalt-manganese hydroxide; and adding water into nickel-cobalt-manganese hydroxide for slurrying, heating same, adding an acidic solution for dissolution, adjusting the pH, reacting same, heating same, adding a manganese powder thereto, adjusting the pH, and filtering same to obtain iron-aluminum slag and a nickel-cobalt-manganese sulfate solution.
Disclosed is a method for producing battery-grade nickel sulfate by using laterite nickel ore comprising the following steps: sorting the laterite nickel ore to obtain lump ore and sediment ore; crushing the lump ore, and then performing heap leaching, to obtain a crude nickel sulfate solution A; separating the sediment ore to obtain high chromium ore, low iron, high magnesium ore, and high iron, low magnesium ore, and drying, roasting, reducing, and sulfurating the low iron, high magnesium ore to obtain low nickel matte; blowing and performing water extraction on the low nickel matte, and then performing oxygen pressure leaching, to obtain a crude nickel sulfate solution B; performing pressure leaching on the high iron, low magnesium ore to obtain a crude nickel sulfate solution C; and performing extraction on the crude nickel sulfate solutions A, B, and C, and then evaporating and crystallizing, to obtain battery-grade nickel sulfate.
C22B 3/38 - Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds containing phosphorus
The present invention relates to a method for recycling iron and aluminum in a nickel-cobalt-manganese solution. The method comprises the following steps: leaching a battery powder and removing copper therefrom to obtain a copper-removed solution, and adjusting the pH value in stages to remove iron and aluminum, so as to obtain a goethite slag and an iron-aluminum slag separately; mixing the iron-aluminum slag with an alkali liquor, and heating and stirring same to obtain an aluminum-containing solution and alkaline slag; and heating and stirring the aluminum-containing solution, introducing carbon dioxide thereto and controlling the pH value to obtain aluminum hydroxide and an aluminum-removed solution.
patents
