This method for determining whether an organism having a cell wall exists comprises: preparing a liquid sample by immersing, into an aqueous solvent, a sample to be measured, or preparing, as a liquid sample, a sample to be measured, which is an aqueous solvent; and detecting whether one kind or a plurality of kinds of sRNAs exist in the liquid sample, wherein whether the organism having a cell wall exists is determined on the basis of whether the one kind or the plurality of kinds of sRNAs exist. This method for identifying an organism having a cell wall comprises: preparing a liquid sample by immersing, into an aqueous solvent, a sample to be measured, or preparing, as a liquid sample, a sample to be measured, which is an aqueous solvent; and detecting whether one kind or a plurality of kinds of sRNAs exist in the liquid sample, wherein the organism having a cell wall is identified on the basis of whether the one kind or the plurality of kinds of sRNAs exist.
C12N 15/11 - DNA or RNA fragments; Modified forms thereof
C12Q 1/6888 - Nucleic acid products used in the analysis of nucleic acids, e.g. primers or probes for detection or identification of organisms
C12Q 1/04 - Determining presence or kind of microorganism; Use of selective media for testing antibiotics or bacteriocides; Compositions containing a chemical indicator therefor
C12Q 1/68 - Measuring or testing processes involving enzymes, nucleic acids or microorganisms; Compositions therefor; Processes of preparing such compositions involving nucleic acids
G01N 33/50 - Chemical analysis of biological material, e.g. blood, urine; Testing involving biospecific ligand binding methods; Immunological testing
2.
COMPOSITION FOR HARD TISSUE REPAIR AND KIT FOR HARD TISSUE REPAIR
Disclosed is a hard tissue repair composition which comprises a monomer (A), a polymer powder (B), and a polymerization initiator (C), wherein the polymer powder (B) comprises a polymer powder (B - x) with an aspect ratio of at least 1.10; and among all of the powder particles in the components included in the hard tissue repair composition, the cumulative percentage of powder particles having an aspect ratio of 1.00 to less than 1.10 is at most 75 cumulative %. Also disclosed is a hard tissue repair kit having a member that divides the monomer (A), the polymer powder (B), and the polymerization initiator (C) included in the hard tissue repair composition into at least three in a given combination and stores the same.
Disclosed are: a production method for an olefin multimer, the method comprising conducting an olefin multimerization reaction in the presence of a catalyst for olefin multimerization which comprises a chromium compound (A), an amine compound (B) of general formula (1), and a compound (C) such as an organometallic compound; and the catalyst for olefin multimerization. (In general formula (1), R1 to R4 each represent a group, e.g., a hydrocarbon group; Y indicates a structure represented by CR5R6- where R5 and R6 each represent a hydrogen atom or a group; and Z is an integer of 1-10.)
B01J 31/34 - Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups of chromium, molybdenum or tungsten
Disclosed is a water-insoluble copolymer having a constitutional unit (X) derived from a hydroxycarboxylic acid and a constitutional unit (Y) derived from an amino group-containing polyvalent carboxylic acid, wherein the molar ratio (X/Y) of constitutional units is 2/1 <= (X/Y) < 8/1, and the amide bond proportion of the constitutional unit (Y) represented by the following formula (1) is defined by the following formulae (2-1) to (2-3); a production method thereof; a resin composition containing the copolymer; and a method of using the copolymer for promoting hydrolysis of a resin. Amide bond proportion (%) = A/Asp x 100 (1) [A = number of moles of an amide bond in (Y), Asp = number of moles of (Y)] when 2/1 5 (X/Y) < 4/1 amide bond proportion (%) ? 25 (2-1) when 4/1 5 (X/Y) 5 6.5/1 amide bond proportion (%) 30 (2-2) when 6.5/1 < (X/Y) < 8/1 amide bond proportion (%) a 50 (2-3)
C08G 63/06 - Polyesters derived from hydroxy carboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from hydroxy carboxylic acids
C08L 67/00 - Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
C08L 67/04 - Polyesters derived from hydroxy carboxylic acids, e.g. lactones
5.
ETHYLENE-ALPHA-OLEFIN COPOLYMERS AS VISCOSITY MODIFIERS
Provided are a viscosity modifier for lubricating oils for obtaining an additive composition for lubricating oils having excellent fluidity in a wide temperature range from low temperature to high temperature; and said additive composition for lubricating oils. Further provided are a viscosity modifier for lubricating oils for obtaining a lubricating oil composition capable of reducing viscosity in good balance in a wide temperature range from low temperature to high temperature; and said lubricating oil composition. The viscosity modifier for lubricating oils includes an ethylene a-olefin copolymer (A) which includes 30 to 50 mole% of structural units derived from at least one a-olefin selected from a-olefins having 4 and 5 carbon atoms and 50 to 70 mole% of structural units derived from ethylene (with the proviso that the total of all structural units of said copolymer is 100 mole%) and which satisfies specific requirements (a), (b), and (c).
C10M 143/06 - Lubricating composition characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation containing butene
A process capable of producing an ethylene/.alpha.-olefin copolymer having a high molecular weight even under the conditions of a high polymerization temperature is provided. The process for producing an ethylene/.alpha.-olefin copolymer includes copolymerizing ethylene and an .alpha.-olefin having 3 or more carbon atoms in the presence of an olefin polymerization catalyst including a crosslinked metallocene compound (A) represented by the following general formula [I] and a cocatalyst component (B). In the general formula [I], Y is selected from a carbon atom, etc., M is a hafnium atom or the like, R1 to R12 are each selected from a hydrogen atom, a hydrocarbon group, etc., R13 and R14 are each a substituted aryl group or the like, at least one of R13 and R14 is a substituted aryl group having one or more electron-donating substituents having a Hammett substituent constant a of not more than -0.2, Q is selected from a halogen atom, etc., and j is an integer of 1 to 4.
C08F 4/6592 - Component covered by group containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
C08F 210/16 - Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
7.
MATERIAL FOR DENTURE BASE, DENTURE BASE, METHOD OF MANUFACTURING THE DENTURE BASE, PLATE DENTURE, AND METHOD OF MANUFACTURING THE PLATE DENTURE
Disclosed is a material for a denture base containing a polymer component having a weight average molecular weight of 1,200,000 or more and containing an acrylic resin.
An object of the invention is to provide a solid polyaluminoxane composition suitably used as a cocatalyst and a catalyst carrier in combination with an olefin oligomerization or polymerization catalyst, without the use of solid inorganic carriers such as silica. The solid polyaluminoxane composition of the invention includes a polyalkylaluminoxane and a trialkylaluminum, and has a solubility in n-hexane at 25°C of less than 0.50 mol% as measured by a specific method (i), a solubility in toluene at 25°C of less than 1.0 mol% as measured by a specific method (ii), and a 13 mol% or more molar fraction of alkyl groups derived from the trialkylaluminum moieties relative to the total number of moles of alkyl groups derived from the polyalkylaluminoxane moieties and the alkyl groups derived from the trialkylaluminum moieties as measured with respect to tetrahydrofuran-d8 soluble components by a specific method (iii).
C08F 4/642 - Component covered by group with an organo-aluminium compound
C08F 10/00 - Homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
C08G 79/10 - Macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon a linkage containing aluminium
9.
AQUEOUS DISPERSION AND ADDITIVE FOR FRACTURING WORK
The aqueous dispersion of the present invention is an aqueous dispersion in which a biodegradable resin composition (C) in the form of a fine solid is dispersed in an aqueous medium, and the biodegradable resin composition (C) comprises a copolymer (A) comprising a constituent unit (a-1) derived from a polyvalent carboxylic acid and a constituent unit (a-2) derived from a hydroxycarboxylic acid, and a biodegradable resin (B), and wherein the mass composition ratio [(A)/(B)] of the copolymer (A) to the biodegradable resin (B) is 1/99 to 100/0 provided that the total amount of the copolymer (A) and the biodegradable resin (B) is 100.
C08L 67/04 - Polyesters derived from hydroxy carboxylic acids, e.g. lactones
C08L 67/00 - Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
C08J 3/05 - Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media from solid polymers
C08L 101/16 - Compositions of unspecified macromolecular compounds the macromolecular compounds being biodegradable
10.
CATALYST FOR METHANOL PRODUCTION, METHOD OF PRODUCING THE SAME AND PROCESS OF METHANOL PRODUCTION
[Problem] The present invention addresses the problem of providing a catalyst which is used in a method for obtaining methanol from carbon dioxide and hydrogen and which exhibits not only high activity but also excellent long-term stability of reactivity. [Solution] The present invention relates to: a catalyst for methanol production, which contains copper, zinc, aluminum and silicon, and wherein the molar ratio of zinc to copper is 0.5-0.7, the molar ratio of silicon to copper is 0.015-0.05, the ratio of the maximum intensity of the peak ascribed to zinc to the maximum intensity of the peak ascribed to copper as determined by XRD is 0.25 or less, and the half-value width (2?) of the peak ascribed to copper as determined by XRD is 0.75-2.5; and a method for producing methanol using the catalyst for methanol production.
B01J 23/80 - Catalysts comprising metals or metal oxides or hydroxides, not provided for in group of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups with zinc, cadmium or mercury
C07C 29/154 - Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing copper, silver, gold, or compounds thereof
A binder resin for toner in the present invention includes a carboxy group-containing vinyl resin (C) , a glycidyl group-containing vinyl resin (E) , a reactant thereof, and a specific fatty acid metal salt (M) , in which the carboxy group-containing vinyl resin (C) includes a high molecular weight vinyl resin (H) having a peak in a region in which the molecular weight is equal to or more than 2×10 4 and equal to or less than 2×10 5 in the molecular weight distribution of a THF soluble content measured by GPC and a low molecular weight vinyl resin (L) having a peak in a region in which the molecular weight is equal to or more than 2×10 3 and equal to or less than 2×10 4 in the molecular weight distribution of a THF soluble content measured by GPC, and in which the reactant of the carboxy group-containing vinyl resin (C) and the glycidyl group-containing vinyl resin (E) is formed in the presence of the fatty acid metal salt (M) .
The present invention provides an ethylene polymer composition having a particularly high formability and having an excellent mechanical strength, a shaped article formed of such an ethylene polymer, and a film and multilayer film having a particularly excellent blocking resistance. An ethylene polymer composition (.gamma.) according to the present invention includes a specific ethylene polymer (.alpha.) that is a copolymer of ethylene and an .alpha.-olefin having 4 to 10 carbon atoms and an ethylene polymer (.beta.) that is a copolymer of ethylene and an .alpha.-olefin having 4 to 10 carbon atoms but different from the ethylene polymer (a), and weight fraction [W.alpha.] of the ethylene polymer (a) is in the range of not less than 0.1 and not more than 0.9, and weight fraction [W.beta.] of the ethylene polymer (.beta.) is in the range of not less than 0.1 and not more than 0.9 (the sum of the W.alpha. and the W.beta. is 1.0).
What is aimed at is provision of an inexpensive and efficient saccharification method for lignocellulose using a thermostable xylanase and provision of a mutant xylanase that has a substitute amino acid residue, and that exhibits stable activity even under severe conditions in which enzymes easily inactivate, and that provides an initial rate of reaction not significantly reduced as compared to a wild-type xylanase corresponding to the mutant xylanase. Provided is a method of producing a saccharified product of lignocellulose, including contacting a lignocellulosic raw material with a thermostable xylanase, and a mutant xylanase that provides an initial rate of reaction that is at least 70% of that provided by a wild-type xylanase corresponding thereto, that has a xylanase activity after heat treatment at 50 °C for 24 hours that is at least 50% of its xylanase activity before the heat treatment, and that has a substitute amino acid residue.
What is aimed at is provision of an inexpensive and efficient saccharification method for lignocellulose using a thermostable xylanase and provision of a mutant xylanase that has a substitute amino acid residue, and that exhibits stable activity even under severe conditions in which enzymes easily inactivate, and that provides an initial rate of reaction not significantly reduced as compared to a wild-type xylanase corresponding to the mutant xylanase. Provided is a method of producing a saccharified product of lignocellulose, including contacting a lignocellulosic raw material with a thermostable xylanase, and a mutant xylanase that provides an initial rate of reaction that is at least 70% of that provided by a wild-type xylanase corresponding thereto, that has a xylanase activity after heat treatment at 50 °C for 24 hours that is at least 50% of its xylanase activity before the heat treatment, and that has a substitute amino acid residue.
A method of producing isopropyl alcohol includes: culturing an isopropyl alcohol-producing Escherichia coli under a bacterial cell growth condition in which the Escherichia coli stably proliferates in an isopropyl alcohol production period while continuously supplying a substrate solution to a culture tank and continuously removing a product- containing culture solution from the culture tank, the substrate solution containing a plant- derived raw material, the number of cells of the isopropyl alcohol-producing Escherichia coli in the culture tank being maintained during the culturing, and the isopropyl alcohol-producing Escherichia coli having isopropyl alcohol production ability introduced or modified by genetic recombination; bringing the isopropyl-alcohol-producing Escherichia coli into contact with the plant-derived raw material in the culture tank to produce isopropyl alcohol; and recovering the isopropyl alcohol produced by the isopropyl alcohol-producing Escherichia coli from the culture solution that contains the product and that has been removed from the culture tank.
The disclosed invention relates to lubricant compositions containing viscosity index improvers in the form of polymers comprising structural units derived from ethylene, propylene and butylenes.
C10M 161/00 - Lubricating compositions characterised by the additive being a mixture of a macromolecular compound and a non-macromolecular compound, each of these compounds being essential
An object of the invention is to provide a methanol production process which can efficiently produce methanol from carbon dioxide and hydrogen while suppressing loads to the global environment. The process for producing methanol of the invention includes a step (a) of reacting hydrogen and carbon dioxide with each other in a reactor in the presence of a copper-containing catalyst to produce a reaction mixture containing methanol; a step (b) of circulating part or all of the reaction mixture to the step (a); a step (c1) of combusting part of the reaction mixture to produce a combustion product and energy, and a step (c2) of circulating part or all of the combustion product to the step (a), the step (c1) and the step (c2) being performed when the reaction mixture contains a compound (p) containing carbon and hydrogen except methanol at not less than 0 . 1 mol% (wherein all components of the reaction mixture excluding methanol and water represent 100 mol%); and a step (d) of separating a component including methanol from the reaction mixture.
C07C 29/154 - Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing copper, silver, gold, or compounds thereof
B01J 23/80 - Catalysts comprising metals or metal oxides or hydroxides, not provided for in group of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups with zinc, cadmium or mercury
Disclosed is a binder resin for a toner containing a vinyl resin (A), a non-crystalline polyester resin (SN) and a saturated crystalline polyester resin (SC), in which the content of the vinyl resin (A) is equal to or more than 65 mass % and equal to or less than 95 mass %, based on the total content of 100 mass % of the vinyl resin (A), the non-crystalline polyester resin (SN) and the saturated crystalline polyester resin (SC), the vinyl resin (A) is composed of a carboxyl group-containing vinyl resin (C), a glycidyl group- containing vinyl resin (E) and a reaction product of the vinyl resins, the ester group concentration of the saturated crystalline polyester resin (SC) is equal to or more than 10.0 mmol/g and equal to or less than 13.5 mmol/g, the non- crystalline polyester resin (SN) is dispersed in an island form in the vinyl resin (A) and the saturated crystalline polyester resin (SC) is contained in the island phase of the non- crystalline polyester resin (SN), and the metal component (M) containing at least one metal selected from the group consisting of Zn, Ca, Mg, Al and Ba is contained at least in the saturated crystalline polyester resin (SC), with the proviso that the metal component (M) excludes a metal oxide.
An isopropyl alcohol-producing Escherichia coli equipped with an isopropyl alcohol production system, having at least one enhanced enzyme activity selected from the group consisting of an enhanced malate dehydrogenase activity, an enhanced NAD(P)+ transhydrogenase (AB-specific) activity, and an enhanced thiolase activity, and an isopropyl alcohol producing method including producing isopropyl alcohol from a plant- derived raw material using the isopropyl alcohol-producing Escherichia coli.
Disclosed is a binder resin for a toner containing at least a carboxyl group-containing vinyl resin (C), a glycidyl group-containing vinyl resin (E), a reaction product of the vinyl resins and a saturated crystalline polyester (S), wherein the saturated crystalline polyester (S) has a predetermined melting point and a predetermined metal component (M), and the binder resin for a toner has a predetermined loss modulus (G") and a predetermined storage modulus (G').
C08L 67/00 - Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
It is an object to provide a lubricating oil composition having low-temperature properties and fuel efficiency at high temperatures which are superior to those of conventional lubricating oil compositions, and to provide a viscosity modifier for lubricating oils and an additive composition for lubricating oils which are used for obtaining said composition. The viscosity modifier for lubricating oils of the present invention comprises a propylene copolymer (A) which has a density of 875kg/m3 or less and which comprises 60mole% or more of structural unit derived from propyl- ene.
C10M 143/04 - Lubricating composition characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation containing propene
C10M 143/06 - Lubricating composition characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation containing butene
C10M 143/08 - Lubricating composition characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation containing aliphatic monomer having more than 4 carbon atoms
22.
ISOPROPYL ALCOHOL-PRODUCING BACTERIUM AND METHOD FOR PRODUCING ISOPROPYL ALCOHOL
The present invention provides an isopropyl alcohol-producing Escherichia coli that includes at least a sucrose hydrolase gene that belongs to a sucrose non-PTS gene group, and an imparted or enhanced isopropyl alcohol production system, and an isopropyl alcohol production method of producing isopropyl alcohol from a sucrose-containing plant-derived raw material using the isopropyl alcohol-producing Escherichia coil.
Provided is a method for producing lactic acid, which includes: obtaining D- lactic acid or L-lactic acid by carrying out lactic acid fermentation using a lactic acid- producing microorganism under a pressurized condition that exceeds normal pressure and is capable of maintaining lactic acid production activity of the lactic acid-producing microorganism.
A novel olefin production process is provided which can be established as an industrial and practical process capable of producing olefins by directly reacting a ketone and hydrogen in a single reaction step. In particular, a novel olefin production process is provided in which propylene is obtained with high selectivity by directly reacting acetone and hydrogen. The olefin production process according to the present invention includes reacting a ketone and hydrogen in the presence of at least one dehydration catalyst and an indium-silver-containing catalyst, and the at least one dehydration catalyst is selected from metal oxide catalysts containing a Group 6 element, zeolites, aluminas and heteropoly acid salts in which part or all the protons in heteropoly acids are exchanged with metal cations.
C07C 1/22 - Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as hetero atoms by reduction
B01J 27/188 - Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
B01J 29/70 - Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups
There is provided by the present invention a process for preparing a copper-based catalyst having good catalytic activity, markedly excellent durability and good reproducibility. The process for preparing a copper-based catalyst of the invention is a process for preparing a catalyst composed of metal oxides containing copper oxide as an essential component and is characterized by comprising the following steps: (1) a step of bringing an acidic metal salt solution containing copper and a precipitant solution into contact with each other to obtain a slurry solution containing a precipitate of a catalyst precursor, and (2) a step of continuously bringing the slurry solution and a wash liquid into contact with each other to wash the precipitate, with substantially keeping the suspended state.
B01J 23/80 - Catalysts comprising metals or metal oxides or hydroxides, not provided for in group of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups with zinc, cadmium or mercury
B01J 37/00 - Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
C07C 29/154 - Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing copper, silver, gold, or compounds thereof
A novel olefin production process of the invention can be established as an industrial and practical process of producing an olefin with high selectivity by directly reacting a ketone and hydrogen in a single reaction step. In particular, a novel olefin production process is provided in which propylene is obtained with high selectivity by directly reacting acetone and hydrogen. An olefin production process of the invention includes reacting a ketone and hydrogen at a reaction temperature in the range of 50 to 300°C in the presence of a Cu-containing hydrogenation catalyst and a solid acid substance.
C07C 1/24 - Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as hetero atoms by elimination of water
B01J 23/80 - Catalysts comprising metals or metal oxides or hydroxides, not provided for in group of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups with zinc, cadmium or mercury
B01J 29/70 - Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups
C07C 29/145 - Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen-containing functional group of C=O containing groups, e.g. —COOH of ketones with hydrogen or hydrogen-containing gases
C07C 31/10 - Monohydroxylic acyclic alcohols containing three carbon atoms
27.
METHOD FOR PRODUCING LACTIC ACID FROM PLANT-DERIVED RAW MATERIAL, AND LACTIC-ACID-PRODUCING BACTERIUM
Disclosed is a lactic-acid-producing Escherichia coli which has at least one gene including at least a sucrose hydrolase gene and selected from sucrose non-PTS genes (provided that a combination of a repressor protein (cscR), a sucrose hydrolase (cscA), a fructokinase (cscK) and a sucrose permease (cscB) and a combination of a sucrose hydrolase (cscA), a fructokinase (cscK) and a sucrose permease (cscB) are excluded) and is genetically so modified as to have a system for enhancing the production of lactic acid. Also disclosed is a method for producing lactic acid from a plant-derived sucrose-containing raw material by using the lactic-acid-producing Escherichia coli.
The present invention provides: a lactic acid-producing Escherichia coli including an enzymatic activity of at least one NAD-dependent lactate dehydrogenase and an enzymatic activity of at least one NAD-independent lactate oxidoreductase, both of which are enhanced so as to decompose one of D-lactic acid or L-lactic acid and to produce the other one of D- lactic acid or L-lactic acid; and a lactic acid production method using the lactic acid- producing Escherichia coli.
The invention provides a preparation process by which an organic alkali metal compound is obtained in a high yield and a process for preparing an organic transition metal compound using the organic alkali metal compound. The process for preparing an organic alkali metal compound is characterized by adding a compound represented by the following formula (2) in the reaction of an active proton-containing compound represented by the following formula (1) with an alkali metal compound. RH p (1) In the formula (1), R is a hydrocarbon group or an amino group and may contain a halogen atom, a silicon atom, an oxygen atom or a nitrogen atom, H is an active proton, and p is the number of hydrogen atoms abstracted in the reaction with the alkali metal compound. (see formula 2) In the formula (2), R a is an aryl group, R b is selected from the group consisting of a hydrogen atom, a straight-chain hydrocarbon group, a branched hydrocarbon group, a cyclic saturated hydrocarbon group, a cyclic unsaturated hydrocarbon group, a saturated hydrocarbon group substituted with a cyclic unsaturated hydrocarbon group, an oxygen-containing group, a nitrogen-containing group, a sulfur- containing group, a hydrocarbon group-substituted silyl group, and a silyl group-substituted hydrocarbon group, and R c is a hydrogen atom.
Metallocene compounds of the invention are useful as olefin polymerization catalysts or catalyst components. Olefin polymerization processes of the invention involve an olefin polymerization catalyst containing the metallocene compound. In detail, the olefin polymerization catalysts can catalyze with high polymerization activity the production of olefin polymers having high melt tension, excellent mechanical strength and good particle properties, and the olefin polymerization processes involve the catalysts. Ethylene polymers according to the invention are obtained by the polymerization processes and have higher processability and easy-opening properties and particularly excellent mechanical strength compared to conventional ethylene polymers. Thermoplastic resin compositions of the invention contain the ethylene polymers. In more detail, shaped articles or films are obtained from the ethylene polymers or the thermoplastic resin compositions containing the ethylene polymers, and laminate films include the films. According to the invention, a single or plural kinds of bridged metallocene compounds having differing cyclopentadienyl-derived groups afford macromonomers that are a source of long-chain branches and simultaneously catalyze the repolymerization of the macromonomers into olefin polymers having a large number of long-chain branches, small neck-in in the T-die extrusion, small take-up surge and superior mechanical strength. The olefin polymerization catalysts and the polymerization processes can efficiently produce the olefin polymers.
C08F 4/6592 - Component covered by group containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
C07F 7/00 - Compounds containing elements of Groups 4 or 14 of the Periodic System
C07F 7/08 - Compounds having one or more C—Si linkages
31.
ISOPROPYL ALCOHOL-PRODUCING BACTERIUM AND METHOD OF PRODUCING ISOPROPYL ALCOHOL USING THE SAME
The invention provides: an isopropyl alcohol-producing bacterium which has an acetoacetate decarboxylase activity, an isopropyl alcohol dehydrogenase activity, a CoA transferase activity and a thiolase activity having been imparted thereto and is capable of producing isopropyl alcohol from a plant-derived material; a method of producing isopropyl alcohol whereby isopropyl alcohol is produced from a plant-derived material by using this isopropyl alcohol-producing bacterium; and an apparatus therefor.
The invention provides a plant disease control composition including active ingredients of (RS)-N-[2-(1,3-dimethylbutyl)thiophene-3-yl]-1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamide (common name: penthiopyrad) and at least one fungicidal compound other than penthiopyrad, and a plant disease prevention method wherein such a compound is applied to plant seeds or soil. According to the invention, a composition and a prevention method are provided which demonstrate a prevention effect against plural types of disease pathogenic microbes, and also demonstrate a preventing effect to currently emerging resistant pathogenic microbes, when applied to plant seed or soil.
A01N 43/80 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms, as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
A01N 25/00 - Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
It is intended to provide a composition comprising at least one neonicotinoid compound selected from dinotefuran, clotianidin, nitenpyram, thiamethoxam, imidacloprid, thiacloprid and acetamiprid, and penthiopyrad, and a method for preventing plant disease and insect damage, characterized by applying the composition to plant seeds and the like. According to the invention, a composition which exhibits, by being applied to plant seeds and the like, a preventive effect on plural disease and insect damages, has a high residual efficacy, and further exhibits a preventive effect also on resistant bacteria or resistant insect pests notably existing at present, and a method for preventing plant disease and insect damage are provided.
A01N 51/00 - Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequenc
The invention provides a plant disease control composition including active ingredients of (RS)-N-[2-(1,3-dimethylbutyl)thiophene-3-yl]-1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamide (common name: penthiopyrad) and at least one fungicidal compound other than penthiopyrad, and a plant disease prevention method wherein such a compound is applied to plant seeds or soil. According to the invention, a composition and a prevention method are provided which demonstrate a prevention effect against plural types of disease pathogenic microbes, and also demonstrate a preventing effect to currently emerging resistant pathogenic microbes, when applied to plant seed or soil.
A01N 25/00 - Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
Disclosed is a method for commercially producing 2-alkenyl-3-aminothiophene derivatives, which are useful as intermediates for agricultural chemicals, at low cost. Specifically disclosed is a method for introducing alkenyl groups into the 2-position of 3-aminothiophene derivatives by reacting 3-aminothiophene derivatives represented by the general formula (2) below or salts thereof with a ketone represented by the general formula (1) below without using a protecting group. Also specifically disclosed are 2-alkenyl-3-aminothiophene derivatives (3a) to (3d) which are useful as intermediates for agricultural chemicals, (see formula 1) (see formula 2) (see formula 3a)(see formula 3b) (see formula 3c) (see formula 3d)
A process for producing nitroguanidine derivatives represented by the following general formula (3) or a salt thereof, which has an insecticidal activity, in which nitroisourea derivatives (1) or a salt thereof and compounds (2) or a salt thereof are reacted in the presence of a base in an aqueous solution (see formula 1) wherein: R1 represents an alkyl group or a benzyl group; R2 represents an alkyl group; and R3 represents a hydrogen atom or an alkyl group, (see formula 2) wherein: R4, R5 and R6 each represent a hydrogen atom or an alkyl group; and Q represents a heterocyclic group, (see formula 3).
There is a harmful organism that cannot be controlled or is difficult to be controlled with the use of a single agent of a compound represented by the general formula (1) according to the invention, an insecticide, a miticide or a fungicides. Accordingly, an object of the invention is to provide a composition for preventing harmful organisms for efficiently controlling such a harmful organism. That is, the invention is directed to a composition for preventing harmful organisms, characterized by comprising the compound represented by the general formula (1) and other insecticides, miticides or fungicides as active ingredients, (see formula 1) wherein, in the formula, A1, A2, A3 and A4 independently represent a carbon atom, a nitrogen atom or an oxidized nitrogen atom; G1 and G2 independently represent an oxygen atom or a sulfur atom; R1 and R2 independently represent a hydrogen atom or a C1 to C4 alkyl group; Xs may be the same or different and represent a hydrogen atom, a halogen atom or a trifluoromethyl group; Q1 represents a substituent such as a phenyl group or a heterocyclic group; and Q2 represents a substituent such as a phenyl group or a heterocyclic group.)
A01N 37/22 - Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N, e.g. carboxylic acid amides or imides; Thio-analogues thereof the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides
A01N 43/40 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
38.
COMPOSITION FOR PREVENTING PLANT DISEASES AND METHOD FOR PREVENTING THE DISEASES
The present invention is to provide a composition for preventing plant diseases which comprises at least Component I and Component II, is capable of obtaining a synergic effect that cannot be expected with each single component, is capable of markedly increasing a control effect in a much smaller amount of chemicals against various plant pathogens, and causes no phytotoxicity suffering. A composition for preventing plant diseases comprises Components I and II as active ingredients. The Component I is (RS)-N-[2-(1,3-dimethylbutyl)thiophen-3-yl]-1-methyl-3-tri fluoromethyl-1H-pyrazole-4-carboxamide. As the Component II, there can be exemplified, for example, tetraconazole, flutriafol, imibenconazole, triadimefon, simeconazole, oxpoconazole fumarate, prothioconazole, bupirimate, spiroxamine, metiram, dodine, anilazine, chlozolinate, oxycarboxin, ethaboxam, iprovalicarb, pyrazophos, fluoroimide, diflumetorim, fenhexamid, famoxadone, fenamidone, cyazofamid, zoxamide, cyflufenamid, boscalid, benthiavalicarb-isopropyl, picoxystrobin, pyraclostrobin, fluoxastrobin or dimoxystrobin.
A01N 37/24 - Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N, e.g. carboxylic acid amides or imides; Thio-analogues thereof the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides containing at least one oxygen or sulfur atom being directly attached to the same aromatic ring system
A01N 37/44 - Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio-analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio-analogue of
A01N 37/52 - Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing groups, e.g. carboxylic acid amidines
A01N 43/28 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atom with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3
A01N 43/32 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atom with two or more hetero atoms six-membered rings
A01N 43/40 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
A01N 43/64 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
A01N 43/88 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms, as ring hetero atoms six-membered rings with three ring hetero atoms
A01N 43/90 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
A01N 47/12 - Carbamic acid derivatives, i.e. containing the group —O—CO—N; Thio-analogues thereof containing a —O—CO—N group, or a thio-analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
A01N 55/00 - Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
A01N 55/02 - Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur containing metal atoms
39.
ETHYLENE-BASED RESIN AND MOLDED OBJECT OBTAINED THEREFROM
Ethylene-based resin, which exhibits a satisfactorily high melt tension and can provide a molded object excellent in mechanical strength, the ethylene-based resin characterized in simultaneously satisfying the requirements [1] to [5] described below: [1] melt flow rate (MFR) under a loading of 2.16 kg at 190°C is in the range of 0.1 to 100 g/10 minutes; [2] density (d) is in the range of 875 to 970 kg/m3; [3] ratio [MT/.eta.* (g/P) ] of melt tension [MT (g) ] at 190°C to shearing viscosity [.eta.* (P) ] at 200°C at an angular velocity of 1.0 rad/sec. is in the range of 1.50x10 -4 to 9.00x10 -4; [4] sum [(A+B)(/1000C)] of the number of methyl branches [A(/1000C)] and the number of ethyl branches [B(/1000C)] per 1000 carbon atoms measured by 13C-NMR is 1.8 or less; and [5] zero shear viscosity [.eta.0(P)] at 200°C and weight-average molecular weight(Mw)measured by GPC-viscosity detector method (GPC-VISCO) satisfy the following relational expression (Eq-1): 0.01 x 10 -13 x Mw3.4 <= .eta.0 <= 4.5 x 10 -13 x Mw3.4 ---- (Eq- 1).
C08F 4/6592 - Component covered by group containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
This invention provides a medical tube comprising a propylene polymer composition (A). The propylene polymer composition (A) contains a polymer comprising propylene units, and at least a part of the propylene unit- containing polymer has an isotactic structure. The content of the propylene unit based on 100% by mole in total of all the structural units of the propylene unit-containing polymer contained in the composition (A) is 65 to 82% by mole. The medical tube satisfies the following (a1), (a2) and (b1): (a1) a tensile modulus of elasticity of 5 to 25 MPa as measured according to JIS K 6301; (a2) a needle penetration temperature of 120~C or above as measured according to JIS K 7196; and (b1) a distance (H) of not more than 60 mm as determined by preparing a tube having a size of 2.1 mm in inner diameter, 3.5 mm in outer diameter, and 20 cm in length from the composition (A), inserting both ends of the tube into a tool having a hollow hole having a size of 10 mm in diameter x 5 mm in height, forming a loop, pulling down both ends of the tube, and measuring the distance (H) from the upper surface of the tool to the upper end of the loop at the time when the loop has kinked.
A viscosity modifier for lubricating oils or an additive composition for lubricating oils, which is excellent in oil-thickening properties and can provide lubricating oil compositions excellent in low-temperature characteristics and handleability at low temperatures; and lubricating oil compositions excellent in low-temperature characteristics and handleability at low temperatures. The viscosity modifier comprises an ethylene/.alpha.-olefin copolymer (B) which comprises (i) a structural unit derived from ethylene, (ii) a structural unit derived from an .alpha.-olefin having 3 to 19 carbon atoms, and (iii) a structural unit derived from a higher .alpha.-olefin having 4 to 20 carbon atoms whose carbon number is by one or more larger than that of the .alpha.-olefin having the unit (ii) which has the following properties of (1) and (2): (1) the contents of units (i), (ii) and (iii) are 25-49 mol%,15-55 mol%, and 9-40 mol% respectively (with the proviso that the total of the units (i), (ii), and (iii) is 100 mol%) and (2) the intrinsic viscosity [ n] is 0.5 to 5.0 dl/g.
C10M 143/06 - Lubricating composition characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation containing butene
C10M 143/08 - Lubricating composition characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation containing aliphatic monomer having more than 4 carbon atoms
C08F 210/16 - Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
42.
AMIDE DERIVATIVES, PROCESS FOR PREPARATION THEREOF AND USE THEREOF AS INSECTICIDE
An object of the present invention is to provide a compound represented by Formula (1): (see formula 1) wherein A1, A2, A3 and A4 each represent a carbon atom, a nitrogen atom or an oxidized nitrogen atom; R1 and R2 each represent a hydrogen atom, an optionally substituted alkyl group or an optionally substituted C1-C4 alkylcarbonyl group; G1 and G2 each represent an oxygen atom or a sulfur atom; X, which may be identical or different each other, represents a hydrogen atom, a halogen atom, a C1-C3 alkyl group or a trifluoromethyl group; n is an integer of 0 to 4; and Q1 represents an optionally substituted phenyl group, an optionally substituted naphthyl group or an optionally substituted heterocyclic group; Q2 represents a phenyl group or heterocyclic group having one or more substituents, at least one of the substituent being any of a C1-C4 haloalkoxy group, a C2-C6 perfluoroalkyl group, a C1-C6 perfluoroalkylthio group, a C1-C6 perfluoroalkylsulfinyl group and a C1-C6 perfluoroalkylsulfonyl group, an insecticide comprising the compound as the active ingredient, and a process for preparation thereof.
C07C 237/42 - Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups having the carbon atom of at least one of the carboxamide groups bound to a carbon atom of a non-condensed six-membered aromatic ring of the carbon skeleton having nitrogen atoms of amino groups bound to the carbon skeleton of the acid part, further acylated
A01N 37/22 - Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N, e.g. carboxylic acid amides or imides; Thio-analogues thereof the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides
A01N 43/08 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atom with one hetero atom five-membered rings with oxygen as the ring hetero atom
A01N 43/10 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atom with one hetero atom five-membered rings with sulfur as the ring hetero atom
A01N 43/36 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
A01N 43/40 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
A01N 43/42 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings condensed with carbocyclic rings
A01N 43/80 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms, as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
C07D 231/12 - Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
C07D 241/24 - Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
C07D 261/18 - Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen
C07D 307/68 - Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen
43.
AGRICULTURAL/HORTICULTURAL INSECTICIDE AND METHOD FOR USING THE SAME
An object of the present invention is to provide insecticides having high effectiveness. The present invention provides compounds represented by formula (1): (see formula 1) wherein A1, A2, A3, and A4 independently represent a carbon atom, a nitrogen atom, or an oxidized nitrogen atom; R1 represents a C1-C6 alkyl group which may be substituted, a phenyl group which may be substituted, or a heterocyclic group which may be substituted; R2 and R3 independently represent a hydrogen atom, a C1-C4 alkyl group which may be substituted, or a C1-C4 alkylcarbonyl group which may be substituted; G1, G2, and G3 independently represent an oxygen atom or a sulfur atom; Xs may be the same or different and each represent a hydrogen atom, a,halogen atom, a C1-C4 alkyl group which may be substituted, or an amino group which may be substituted; n represents an integer of 0 to 4; Q represents a phenyl group which may be substituted, a naphthyl group which may be substituted, a tetrahydronaphthyl group which may be substituted, or a heterocyclic group which may be substituted, insecticides containing the compounds as active ingredients, and a method for producing the compounds. The compounds represented by formula (1) exhibit an excellent preventive effect as insecticides and also exhibit an excellent preventive effect when being combined with another insecticide, an acaricide, a nematocide, a fungicide, a herbicide, a plant growth regulator, or a biological pesticide.
C07C 323/36 - Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton having at least one of the nitrogen atoms bound to a carbon atom of the same non-condensed six-membered aromatic ring the thio group being a sulfide group the sulfur atom of the sulfide group being further bound to an acyclic carbon atom
C07C 317/36 - Sulfones; Sulfoxides having sulfone or sulfoxide groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton with sulfone or sulfoxide groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having sulfone or sulfoxide groups and amino groups bound to carbon atoms of six-membered aromatic rings being part of the same non-condensed ring or of a condensed ring system containing that ring with the nitrogen atoms of the amino groups bound to hydrogen atoms or to carbon atoms
A01N 33/06 - Nitrogen directly attached to an aromatic ring system
A01N 33/10 - Amines; Quaternary ammonium compounds containing oxygen or sulfur having at least one oxygen or sulfur atom directly attached to an aromatic ring system
An object of the present invention is to provide insecticides having high effectiveness. The present invention provides compounds represented by formula (1): (see formula 1) wherein A1, A2, A3, and A4 independently represent a carbon atom, a nitrogen atom, or an oxidized nitrogen atom; R1 represents a C1-C6 alkyl group which may be substituted, a phenyl group which may be substituted, or a heterocyclic group which may be substituted; R2 and R3 independently represent a hydrogen atom, a C1-C4 alkyl group which may be substituted, or a C1-C4 alkylcarbonyl group which may be substituted; G1, G2, and G3 independently represent an oxygen atom or a sulfur atom; Xs may be the same or different and each represent a hydrogen atom, a halogen atom, a C1-C4 alkyl group which may be substituted, or an amino group which may be substituted; n represents an integer of 0 to 4; Q represents a phenyl group which may be substituted, a naphthyl group which may be substituted, a tetrahydronaphthyl group which may be substituted, or a heterocyclic group which may be substituted, insecticides containing the compounds as active ingredients, and a method for producing the compounds. The compounds represented by formula (1) exhibit an excellent preventive effect as insecticides and also exhibit an excellent preventive effect when being combined with another insecticide, an acaricide, a nematocide, a fungicide, a herbicide, a plant growth regulator, or a biological pesticide.
C07C 271/28 - Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atom of at least one of the carbamate groups bound to a carbon atom of a six-membered aromatic ring to a carbon atom of a non-condensed six-membered aromatic ring
A01N 47/10 - Carbamic acid derivatives, i.e. containing the group —O—CO—N; Thio-analogues thereof
A01N 47/40 - Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
An object of the present invention is to provide insecticides having high effectiveness. The present invention provides compounds represented by formula (1): wherein A1, A2, A3, and A4 independently represent a carbon atom, a nitrogen atom, or an oxidized nitrogen atom; R1 represents a C1-C6 alkyl group which may be substituted, a phenyl group which may be substituted, or a heterocyclic group which may be substituted; R2 and R3 independently represent a hydrogen atom, a C1-C4 alkyl group which may be substituted, or a C1-C4 alkylcarbonyl group which may be substituted; G1, G2, and G3 independently represent an oxygen atom or a sulfur atom; Xs may be the same or different and each represent a hydrogen atom, a halogen atom, a C1-C4 alkyl group which may be substituted, or an amino group which may be substituted; n represents an integer of 0 to 4; Q represents a phenyl group which may be substituted, a naphthyl group which may oe substituted, a tetrahydronaphthyl group which may be substituted, or a heterocyclic group which may be substituted, Insecticides containing the compounds as active ingredients, and a method for producing the compounds. The compounds represented by formula (1) exhibit an excellent preventive effect as insecticides and also exhibit an excellent preventive effect when being combined with another insecticide, an acaricide, a nematocide, a fungicide, a herbicide, a plant growth regulator, or a biological pesticide.
C07C 323/36 - Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton having at least one of the nitrogen atoms bound to a carbon atom of the same non-condensed six-membered aromatic ring the thio group being a sulfide group the sulfur atom of the sulfide group being further bound to an acyclic carbon atom
C07C 317/36 - Sulfones; Sulfoxides having sulfone or sulfoxide groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton with sulfone or sulfoxide groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having sulfone or sulfoxide groups and amino groups bound to carbon atoms of six-membered aromatic rings being part of the same non-condensed ring or of a condensed ring system containing that ring with the nitrogen atoms of the amino groups bound to hydrogen atoms or to carbon atoms
A01N 33/06 - Nitrogen directly attached to an aromatic ring system
The present invention provides an aqueous suspension formulation containing (RS)-N-[2-(1,3-dimethylbutyl)thiophene-3- yl]-1-methyl-3-trifluoromethyl-1H-pyrazole-4-carboxamide and having high rain resistance and stable residual effectiveness. A aqueous suspension formulation for foliar application fungicide of the present invention contains a fungicidal active ingredient, (RS)-N-[2-(1,3-dimethylbutyl)thiophene-3-yl]-1- methyl-3-trifluoromethyl-1H-pyrazole-4-carboxamide, and a polyoxyalkylene rosin acid ester or liquid paraffin, and has improved rain resistance on plant leaves and excellent residual effectiveness.
A01N 25/30 - Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
- 1 - SPECIFICATION Title of the Invention PREPARATION PROCESS FOR INDOLES Abstract of the Disclosure Disclosed herein is to react an aniline and an ethylene glycol at a superatmospheric pressure in preparing an indole by subjecting the aniline and ethylene glycol to a gas-phase catalytic reaction in the presence of a catalyst, thereby improving the selectivity of the reaction and the service life of the catalyst.
C07D 209/08 - Indoles; Hydrogenated indoles with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to carbon atoms of the hetero ring
- 28 - Abstract of the Disclosure A glass-reinforced polymer composition of the invention contains 80 to 99.99 parts by weight, of a 4-methyl-1-pentene polymer, 0.01 to 20 parts by weight of a graft-modified polymer of 4-methyl-1-pentene having graft units of an unsaturated carboxylic acid or an acid anhydride thereof in an amount of 0.5 to 15% by weight and having a limiting viscosity of 0.3 to 10 d?/g, and 1 to 300 parts by weight of glass fibers based on 100 parts by weight of the sum of the 4-methyl-1-pentene polymer and the graft-modified polymer. The composition has overall standards of mechanical strength, heat resistance and water resistance.
Abstract of the Disclosure A process for producing an olefin polymer or copolymer which comprises polymerizing or copolymerizing olefins or copolymerizing an olefin with up to 5 mole% of a diolefin in the presence of a catalyst comprising a titanium catalyst component containing magnesium, titanium, halogen and an electron donor, an organo- aluminum catalyst component and a third catalyst compo- nent, characterized in that said catalyst is composed of (A) a titanium catalyst component containing magnesium, titanium, halogen and an electron donor as essential ingredients, said electron donor being selected from the group consisting of (a) esters of polyfunctional compounds selected from polycarboxylic acids having 5 to 36 carbon atoms, polyhydroxy compounds having 6 to 28 carbon atoms and hydroxy-sub- stituted carboxylic acids having 10 to 28 carbon atoms, and (b) monocarboxylic acid esters of the formula RCOOR' in which each of R and R' repre- sents a hydrocarbyl group having 1 to 20 carbon atoms, and at least one of them represents a branched-chain group, an alicyclic group, or an aryl ring-contain- ing linear group, (B) an organoaluminum compound, and (C) an ester of phosphorous acid with an alcohol having 2 to 4 carbon atoms; and a catalyst composition used therefor.
Abstract of the Disclosure A process for producing a polymer or copolymer of an olefin which comprises polymerizing or copolyme- rizing at least one olefin with or without a diolefin in the presence of a catalyst composed of (A) a magnesium- containing solid titanium catalyst component containing magnesium, titanium, a halogen and an electron donor as essential ingredients and (B) an organoaluminum com- pound catalyst component; characterized in that (1) said catalyst further comprises (C) an organic silicon compound catalyst component having an Si-O-C or Si-N-C bond, and (2) said electron donor in the catalyst com- ponent (A) is selected from the group consisting of a cyclic mono- or poly-ester (a), (b), (c), (d), (e) and (f) specified in the claims.
- 1 - SPECIFICATION Title of the Invention Process for Producing Crosslinked Urea-Formaldehyde Polymer Particles Abstract Disclosed is a process for producing fine particles of crosslinked urea-formaldehyde polymer which comprises the steps of synthesizing a precondensate of urea and formaldehyde, allowing the precondensate to react by the addition of an aqueous solution of an acid catalyst, and then neutralizing the reaction mixture, characterized in that the filtrate obtained in the filtration step for separating the polymer particles is recycled to the reaction system at the step of synthesizing a precondensate - 2 - of urea and formaldehyde and/or the step of allowing the precondensate to react by the addition of an aqueous solution of an acid catalyst and in that the precondensate is obtained by reacting 1 mole of urea with 1.4 to 1.9 moles of formaldehyde at a pH of 6 to 10 and a temperature of 10 to 95°C. While such fine particles of crosslinked urea- formaldehyde polymer are useful as a filler for improving certain properties (such as opacity and the like) of paper, disposal of the filtrate resulting from the filtration step for separating the polymer particles has been a serious problem. The disclosed process is carried out in a closed system by recycling of the filtrate and, moreover, the resulting polymer is in the form of fine particles having a diameter of 0.1 to 1.0 µ and hence meets the requirements for a filler of paper (i.e., the capability of improving the opacity and other properties of paper).
Abstract of the Disclosure An improved process for producing an olefin polymer or copolymer by using a novel catalyst composition composed of (A) a titanium catalyst component containing magnesium, titanium, halogen and an ester specified in Claim 1, as an electron donor, (B) an organoaluminum compound and (C) a heterocyclic compound or a ketone specified in Claim 1, as a third component. The com- bination parameter of the ester in (A) and the (C) com- ponent is new, and the process can give a highly stereo- specific olefin polymer or copolymer in high yields.
A B S T R A C T A process for producing an olefin polymer or copolymer which comprises polymerizing or copolymerizing olefins or copolymerizing an olefin with up to 5 mole% of a diolefin in the presence of a catalyst comprising a titanium catalyst component containing magnesium, titanium, halogen and an electron donor 9 an organo- aluminum catalyst component and a third catalyst compo- nent, characterized in that said catalyst is composed of (A) a titanium catalyst component containing magnesium, titanium, halogen and an electron donor as essential ingredients, said electron dono being selected from the group consisting of (a) esters Or polyfunctional compounds selected from polycarboxylic acids having 5 to 36 carbon atoms, polyhydroxy compounds having 6 to 28 carbon atoms and hydroxy-sub- stituted carboxylic acids having 10 to 28 carbon atoms, (b) monocarboxylic acid esters of the formula RCOOR' in which each of R and R' repre- sents a hydrocarbyl group having 1 to 20 carbon atoms, and at least one of them represents a branched-chain group, an alicyclic group, or an aryl ring-contain- ing linear group, and (c) carbonic acid esters having 6 to 18 carbon atoms, (B) an organoaluminum compound, and (C) a substituted methylenediamine compound as a third component; and a catalyst composition used therefor.
-1- SPECIFICATION Title of the Invention METHOD FOR THE PURIFICATION OF PROPYLENE POLYMERS Abstract Disclosed is a method fox the purification of propylene polymers which comprises bringing a propylene polymer containing volatile components into contact with a gas consisting mainly of propylene at a temper- ature lower than the melting point of the polymer, whereby the volatile components are removed from the propylene polymer. A process gas obtained by evaporating the reaction medium contained in a slurry resulting from bulk polymerization using propylene itself as the reaction medium or a process gas separated and recovered from a polymerization mixture resulting from vapor phase polymerization is suitable for use in the practice of the present invention, because its dew point is low- enough for drying purposes and it can be recycled in large amounts. The method of the present invention permits the volatile components contained in the polymer to be removed to substantially the same extent as is attainable by the conventional drying method using a large amount of nitrogen gas. Thus, the present method has very great economic advantages over the conventional one.
patents
