The invention relates to aqueous polymer dispersions comprising polymerized units issued from the following monomers with related weight proportions based on 100 parts of weight of a)+b): a) 50 to 90% of a monoethylenically unsaturated non-ionic monomer, b) 10 to 50% of vinyl aromatic monomer or methyl methacrylate, c) 1 to 5% of a hydroxy-containing (meth)acrylate, d) 0.1 to 3% of acid monomer selected from d1) acid monomer selected from monocarboxylic or dicarboxylic acid monomers and d2) acid monomer selected from phosphorous-based or sulfur-based strong acid monomers or/and their salts, or from the mixtures of d1) and d2), e) 0.001 to 0.5% of chain transfer agent, and f) 0 to 1% one of internal crosslinker bearing at least two copolymerisable ethylenic unsaturations, the polymer having a Tg measured by DSC from −30 to 0° C. and a gel content of 0 to 60%, formed during polymerization.
C08F 230/02 - Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium, or a metal containing phosphorus
C08F 236/02 - Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
C08K 3/013 - Fillers, pigments or reinforcing additives
Curable resin compositions having extended open times at ambient temperatures and short cure times at elevated temperatures are prepared using a curable resin, a combination of room-temperature-stable liquid peroxides (including at least one perketal), a promoter salt, a thiol-functionalized organicd accelerator and a free radical trap. The curable resin compositions are useful in pultrusion, cure-in-place pipe and resin transfer molding applications, among others.
Waterborne dispersions including crosslinkable multistage polymeric particles useful in coating compositions are provided. The multistage particles have a last-formed layer that includes a diketone functionality that is capable of crosslinking via a dihydrazide component also included in the dispersion. Another embodiment of the waterborne dispersion further includes crosslinkable latex particles having a diketone functionality that are capable of crosslinking with each other and/or the multistage particles via the dihydrazide component. An emulsion polymerization process for forming the multistage particles also is provided. Also provided are coating compositions that contain either embodiment of the waterborne dispersions.
Disclosed are voided latex particles, useful as opacifying agents for coating compositions containing organic solvents. The particles have a hollow interior, which substantially maintains its integrity after the particles are placed in contact with an organic solvent at 25° C. for 30 days. The particles also have a hydrophilic polymeric interior shell surrounding the hollow interior that is swellable with an aqueous swelling solution. The particles have first and second polymeric intermediate shells, surrounding the interior shell, formed from polymers that are different from each other and different from the interior shell polymer. Finally, the particles have an outer polymeric shell, surrounding the interior shells, which is formed from up to 100% by weight, as polymerized units, of methyl methacrylate. The interior shells and the outer shell each have a Tg greater than 60° C. Also disclosed is a multi-stage emulsion process for making the particles.
A method of reducing dispersion viscosity in a dispersion coating formulation is disclosed. The method comprises substituting a portion of the conventional PVDF in the formulation with a highly crystalline PVDF. The highly crystalline PVDF has a crystallinity 44% or greater (from X-ray diffraction). The highly crystalline PVDF imparts lower viscosity to the coating dispersion formulation.
This process for synthesizing thiopolymers involves feeding elemental sulfur or sulfides and unsaturated hydrocarbons into an extruder. The extruder is comprised of a screw and a barrel. The screw is rotated so as to pressurize, heat and mix the sulfur or sulfides and unsaturated hydrocarbon to induce inverse vulcanization thereby producing thiopolymers such as polymeric polysulfides. The invented process can be accomplished by using sulfur which becomes molten at the conditions in the extruder or is preheated and unsaturated hydrocarbons as the starting material. The materials are fed through one or more extruders so as to induce mixing and reaction of the materials forming polysulfides.
Disclosed is a method and an extruder for making carbon blocks using poly (vinylidene fluoride) (PVDF) as binder and absorbents such as activated carbon.
B29C 48/395 - Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
B29C 48/80 - Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling at the plasticising zone, e.g. by heating cylinders
B29C 48/63 - Screws having sections without mixing elements or threads, i.e. having cylinder shaped sections
8.
METHOD OF MANUFACTURING AN ELECTRODE FOR ALL SOLID STATE BATTERY
The invention relates to a method of preparation of an electrode slurry for all solid-state battery. Another subject matter of the invention is a process for making an electrode for all solid-state battery. The invention also concerns the solid-state lithium-ion batteries manufactured by incorporating said electrode.
H01M 4/62 - Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
H01M 4/525 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
H01M 4/505 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
B01D 67/00 - Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
B01D 69/02 - Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor characterised by their properties
10.
VINYL ACRYLIC EMULSION COPOLYMER AND USE THEREOF IN STAIN RESISTANT COATING COMPOSITIONS
Waterborne vinyl acetate-acrylic, “vinyl acrylic” emulsion copolymers which can be used in architectural coatings and impart stain resistance to such coatings are provided. The vinyl acrylic emulsion copolymer particles in the emulsion may contain one or more particle size modes, each with a respective narrow particle size distribution. The vinyl acrylic emulsion copolymers contain as a comonomer an ethylenically unsaturated monomer and also contain a hydrolyzable silane comonomer. The hydrolyzable silane may be present as a comonomer in the vinyl acrylic copolymer and/or may be added to the vinyl acrylic emulsion copolymer emulsion in the form of a hydrolyzable silane that may have a reactive group that is capable of reacting with the vinyl acrylic copolymer.
Encapsulated peroxide particles inhibit skin inflammation. A method of encapsulating a solid peroxide comprises dispersing solid peroxide particles (e.g., benzoyl peroxide) in an aqueous dispersion of fatty acid salt to form a peroxide/fatty acid salt dispersion, wherein the peroxide particles have a mean particle size (D50) of 10 μm or less; and subsequently encapsulating the solid peroxide particles by reacting the one or more monovalent fatty acid salts with one or more multivalent salts of calcium, magnesium, aluminum, silver, and/or zinc, thereby forming encapsulated peroxide particles.
Multi-stage polymeric particles are prepared as a water-borne emulsion, including a first-formed lower Tg soft stage and a second-formed higher Tg hard stage. The polymeric particles include, in both stages: one or more free radical polymerizable ethylenically unsaturated monomers; 0 to 3 wt % of free radical polymerizable surfactant monomer; 0 to 4 wt % of free radical poly-merizable monomer having a beta dicarbonyl functionality; 0 to 2 wt % of monomer selected from acrylamide, diacetone acrylamide, 2-hydroxyethyl (meth)acrylate, hydroxypropyl (meth)acrylates, and hydroxybutyl (meth)acrylates and mixtures thereof; 0-1.9 wt % of free radical polymerizable polyethylenically unsaturated monomers; 0.1 to 1.9% of free radical polymerizable monomer containing phosphorus acid or a salt thereof in the first stage, and 0.1 to 5 wt % of a free radical polymerizable monomer containing phosphorus acid or salt thereof in the second stage. Multi-stage polymeric-particle-based-resin is formulated into direct to metal coatings, having good block, corrosion and excellent humidity resistance.
C09D 147/00 - Coating compositions based on homolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds; Coating compositions based on derivatives of such polymers
A melt processable fluoropolymer composition comprising TFE, VDF and from 1 to 3 mol % fluorinated ether is disclosed. A method of making the polymer is also disclosed.
Copolymers of one or more halogenated olefins and one or more halogenated co-monomers selected from the group consisting of halogenated alkenyl ethers, halogenated alkenyl esters, and halogenated (meth)acrylates are useful in various end-use applications wherein the presence of halogen (e.g., fluorine) in the copolymer imparts one or more desirable properties, as compared to analogous copolymers not containing halogen.
Disclosed is a method for producing a battery electrode using a low solution viscosity polymeric binder composition where the binder composition comprises a fluoropolymer.
The present invention relates generally to the field of electrical energy storage in the lithium storage batteries of Li-ion type. More specifically, the invention relates to a binder for Li-ion battery positive electrode, to a method of preparation of said electrode and to its use in a Li-ion battery. Another subject matter of the invention is the Li-ion batteries manufactured by incorporating this electrode material.
H01M 4/62 - Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
H01M 4/58 - Selection of substances as active materials, active masses, active liquids of polyanionic structures, e.g. phosphates, silicates or borates
H01M 4/131 - Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
A beeswax and/or beehive or bee keeping equipment surface is treated with a composition containing at least one solvent, at least one surfactant and at least one oxidizing agent (e.g., peroxide), optionally also containing other components such as an oxidizing agent activator, a viscosifying agent, an enzyme and/or a pH control agent, to reduce the amount of pesticide residues on the beeswax surface and/or disinfect against any bacterial, viruses, and fungi infestation.
A01K 51/00 - Appliances for treating beehives or parts thereof, e.g. for cleaning or disinfecting
A01N 25/02 - Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
A01N 37/16 - Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group ; Thio-analogues thereof
A01N 59/00 - Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
18.
AZEOTROPE AND AZEOTROPE-LIKE COMPOSITIONS OF 1-CHLORO-1,2 DIFLUOROETHYLENE AND 2,3,3,3-TETRAFLUOROPROP-1-ENE
Provided are azeotrope or azeotrope-like compositions comprised of 1-chloro-1,2 difluoroethylene (R-1122a) and 2,3,3,3-tetrafluoropropene (HFO-1234yf) and uses thereof.
The present invention relates to heat transfer compositions comprising 1-chloro-1,2 difluoroethylene for use in refrigeration, air conditioning, heat pump systems, chillers, and other heat transfer applications. The inventive heat transfer compositions can possess reduced global warming potential while providing good capacity and performance while providing preferable flammability characteristics
C09K 5/04 - Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice-versa
C10M 171/00 - Lubricating compositions characterised by purely physical criteria, e.g. containing as base-material, thickener or additive, ingredients which are characterised exclusively by their numerically specified physical properties, i.e. containing ingredien
C09K 3/30 - Materials not provided for elsewhere for aerosols
C08J 9/14 - Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
20.
DEVICE TO RELEASE WATER AND ANTIMICROBIAL VAPOR INTO AN ENCLOSED OR PARTIALLY ENCLOSED SPACE
Devices and methods for provided both an antimicrobial vapor such as hydrogen peroxide and/or peracetic acid and water vapor in an enclosed or partially enclosed space are described. The device and method provided is for the reduction or elimination of microbes from air and surfaces in contact with air within an enclosed or partially enclosed space using hydrogen peroxide or peracetic acid in the vapor phase and also provide for humidity from water vapor. The device and method are directed towards a release of an antimicrobial vapor and water vapor through a permeable container/barrier containing a matrix into which water and an antimicrobial vapor producing material are absorbed.
B65D 81/24 - Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants
B65B 55/19 - Sterilising contents prior to, or during, packaging by adding materials intended to remove free oxygen or to develop inhibitor gases, e.g. vapour-phase inhibitors
A23B 7/144 - Preserving or ripening with chemicals not covered by group or in the form of gases, e.g. fumigation; Compositions or apparatus therefor
A23L 3/3427 - Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of gases, e.g. fumigation; Compositions or apparatus therefor in a controlled atmosphere, e.g. partial vacuum, comprising only CO2, N2, O2 or H2O in which an absorbent is placed or used
B01J 20/10 - Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
B01J 20/28 - Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
21.
REMOVAL OF RESIDUAL MERCAPTANS FROM POLYMER COMPOSITIONS
The removal of mercaptans from polymer compositions is described, where removal occurs by at least one of: contacting the polymer composition with a radical initiator that reacts with the mercaptain compound to form a non-odorous compound; and contacting the polymer composition with a transition metal that immobilizes the mercaptan compound.
C08G 81/02 - Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers at least one of the polymers being obtained by reactions involving only carbon-to-carbon unsaturated bonds
The present invention pertains to a non-linear, copolymer comprising recurring units derived from vinylidene fluoride (VDF) monomer, at least one functional comonomer and optionally at least one fluorinated ethylenic comonomer. The non-linear fluorinated copolymer comprises from 0.01 to 3.0% by moles of recurring units derived from functional comonomer. The non-linear fluorinated copolymer can be used as electrode binder in batteries.
An anionically-stabilized aqueous emulsion composition includes a) a first emulsion polymer having a Tg from −60° C. to 40° C.; b) a volatile base; and c) polymeric particles, different from the first emulsion polymer and present in emulsified form. The c) polymeric particles are polyamine graft copolymers, in which vinyl monomers form a polymer grafted to a water-soluble amino-group containing polymer. The anionically-stabilized aqueous emulsion composition may have a pH of from 8 to 11.
C09D 151/08 - Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
A polyol pre-mix containing at least one halogenated hydroolefin blowing agent and having improved shelf life stability is provided, wherein each polyol combined with the halogenated hydroolefin blowing agent has an apparent pH of between 3 and 11.4. Controlling the apparent pH of the polyol(s) enables the polyol pre-mix to be stored for extended periods of time and then used in combination with organic polyisocyanate to produce foam formulations having gel times and tack free times not significantly different from those exhibited when freshly prepared polyol pre-mix is used.
C08J 9/14 - Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
C08G 18/18 - Catalysts containing secondary or tertiary amines or salts thereof
C08G 18/42 - Polycondensates having carboxylic or carbonic ester groups in the main chain
C08G 18/76 - Polyisocyanates or polyisothiocyanates cyclic aromatic
C08G 18/09 - Processes comprising oligomerisation of isocyanates or isothiocyanates involving reaction of a part of the isocyanate or isothiocyanate groups with each other in the reaction mixture
Formulations for producing modified bio-based polymers, especially bio-based polyesters like PLA and/or biodegradable polymers like PBAT, include at least one organic peroxide and at least one bio-based reactive additive. The at least one organic peroxide and/or the at least one bio-based reacted additive are capable of reacting with a bio-based polymer and/or biodegradable polymer to produce the modified bio-based and/or modified biodegradable polymer. The modified bio-based and/or modified biodegradable polymers have improved properties compared to non-modified bio-based and/or biodegradable polymers. The improved properties may related to processability, especially improved melt strength which results in easier processing while producing foamed polymers, thin films, such as blown film, cast film, tentered film and the like. The improved properties may be related to physical properties such as improved stiffness, toughness or tensile strength.
Non-polymeric coupling agent formulation for producing wood-polymer composites include at least one organic peroxide and a non-polymeric bio-based additive that includes at least one of a bio-based oil or a bio-based acid or derivatives of bio-based oils or acid is provided. The coupling agent formulations are capable of producing polymer matrix composites having improved strength and aging characteristics. The improved strength may be related to physical properties such as improved stiffness, toughness or tensile strength. A masterbatch utilizing the non-polymeric coupling agent formulation is provided, as well as a method making the masterbatch.
Embodiments of organic peroxide formulations provide longer scorch time protection and require fewer additives. The peroxide formulations may include, for example, at least one organic peroxide, and at least one scorch retardant additive selected from the group consisting of vitamin K1 (phlloquinone), K2 (menaquinone), K3 (menadione), olive leaf oil (oleuropein), and mixtures thereof.
Disclosed is a polymer process aid used to reduce or eliminate surface defects that can arise during extrusion of thermoplastic polymers. The polymer process aid comprises a thermoplastic vinylidene fluoride copolymer (A) having a melt viscosity at or above 25 kP. The VDF copolymer can be a VDF/HFP copolymer. The polymer process aid also contains at least one interfacial agent (B). Also disclosed is 1) a masterbatch (D) and articles containing the polymer process aid (A/B).
The present invention relates to a polyester-urethane composition. In particular, the invention relates to aliphatic alkyl ring-containing compositions that are useful for producing ultraviolet light resistant coatings. The invention further relates to pigmented and clear coating compositions formulated with the polyester-urethane composition of the present invention. The polyester-urethane compositions may be crosslinked.
Disclosed is a method for producing a battery electrode using a granulated polymeric binder composition where the binder composition comprises agglomerated particles wherein greater than 95% by weight of agglomerated particles are 400 um or greater but less than 2.5 mm and a bulk density of greater than 0.4 g/cc.
A method of reducing foamed density that results in a foamed polyvinyl chloride (PVC) component exhibiting reduced density. The foamed PVC component contains at least a PVC resin and a process aid blend. The process aid blend contains from 1 weight % to 60 weight % (based on the weight of the blend) of a functionalized process aid, and from 99 weight % to 40 weight % (based on the weight of the blend) of a non-functionalized process aid. The functionalized process aid includes at least one base polymer functionalized with a reactive epoxy, hydroxyl, β-keto ester, β-keto amide, or carboxylic acid functional group. The foamed PVC component containing the process aid blend has a lower density than a reference foamed PVC component made using the same process conditions and additives, but which contains only non-functionalized process aid and not the functionalized process aid.
C08L 63/00 - Compositions of epoxy resins; Compositions of derivatives of epoxy resins
C08L 33/08 - Homopolymers or copolymers of acrylic acid esters
C08L 33/10 - Homopolymers or copolymers of methacrylic acid esters
C08L 23/28 - Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or halogen-containing compounds
C08J 9/00 - Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
C08J 9/04 - Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
The use of compatible, semi-miscible or miscible polymer compositions as support structures for the 3D printing of objects, including those made from polyether-block-amide copolymers such as PEBAX® block copolymers from Arkema, polyamides such as RILSAN® polyamides from Arkema, polyether ketone ketone such as KEPSTAN® PEKK from Arkema, and fluoropolymers, such a KYNAR® PVDF from Arkema, especially objects of polyvinylidene fluoride and its copolymers. One particularly useful miscible polymer is an acrylic polymer, which is miscible with the fluoropolymer in the melt. The support structure composition provides the needed adhesion to the build plate and to the printed object and support strength during the 3D printing process, yet it is removable after the fluoropolymer object has cooled. The support polymer composition is selected to be stiff and low warping, yet flexible enough to be formed into filaments.
B29C 64/40 - Structures for supporting 3D objects during manufacture and intended to be sacrificed after completion thereof
B29C 64/112 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using individual droplets, e.g. from jetting heads
C08L 33/12 - Homopolymers or copolymers of methyl methacrylate
C08L 27/16 - Homopolymers or copolymers of vinylidene fluoride
C08L 77/00 - Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
C08G 65/00 - Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
A one-pack polymer modifier containing a) at least one process aid functionalized with a reactive epoxy, hydroxyl, β-keto ester, β-keto amide or carboxylic acid functional group, b) at least one impact modifier, c) optionally, at least one mineral filler and d) optionally, at least one further additive is useful for modifying the properties of thermoplastic polymers such as PVC, including reducing the surface gloss of an article prepared from the thermoplastic polymer and improving the impact strength of such an article.
The invention relates to the use of a low Tg compatible resin as an adhesive layer for the welding of a thermoplastic composite structure to a thermoplastic or thermoset structure. The invention is especially good for the welding of large parts, such as wind turbine halves and spar caps. A useful thermoplastic composite is one formed by the infusion and curing of long fibers by a reactive acrylic liquid resin system, such as ELIUM® resin systems from Arkema.
B29C 65/42 - Applying molten plastics, e.g. hot melt between pre-assembled parts
C08L 33/10 - Homopolymers or copolymers of methacrylic acid esters
B32B 27/08 - Layered products essentially comprising synthetic resin as the main or only constituent of a layer next to another layer of a specific substance of synthetic resin of a different kind
An injection molding process to mold a fluorinated thermoplastic elastomeric polymer composition is disclosed. An article made using the process has little shrinkage.
This invention discloses a reticulated film composite and a method of fabricating a reticulated film composite suitable as a 3 dimensional porous and conductive matrix which contains up to 80% porosity and exhibits high recovery after compression. The reticulated film composite is produced by casting and drying of a slurry which exhibits a high yield stress (i.e. greater than 50 dyne/cm2) and comprised of a high MW resin dissolved in a solvent (i.e. having solution viscosity of higher than 100 cp at 5% in NMP at room temperature) and dispersed nanoparticles of carbon of high specific surface areas (i.e. greater than 1 m2/g preferably greater than 10 m2/g), examples include but not limited to conductive carbon, carbon nanotubes, graphene, activated carbon or mixture thereof. This reticulated film composite exhibits high electrical conductivity (i.e. volume resistivity of less than 10,000 Ω·cm) and superior dimensional stability even at elevated temperatures (i.e. at 140° C.). It will exhibit a recovery of height or porosity after being compressed to over 50% of its height. The composite of this invention is suitable as an electrically conductive composite, as a gas diffusion layer in a fuel cell, or as a high efficiency electrode in super capacitors
C08J 9/00 - Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
C08J 9/28 - Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum
37.
COMPOSITE FUNCTIONALIZED ACRYLIC PROCESS AIDS FOR GLOSS AND SURFACE MODIFICATION
A composite polymer process aid is provided. The process aid includes one or more inorganic mineral fillers and one or functionalized polymers. The functionalized polymers include at least one base polymer functionalized with an epoxy, hydroxyl, β-keto ester, β-keto amide, or carboxylic acid reactive functional group. The composite polymer process aid is in the form of a plurality of individual particles. At least a portion of the individual particles include both inorganic mineral fillers and the functionalized polymers. The composite polymer modifier is formed by a process of: i) blending an aqueous solution, an aqueous dispersion, an aqueous suspension, an aqueous slurry, or a dry powder of the mineral fillers with an aqueous solution, an aqueous dispersion, an aqueous suspension or an aqueous emulsion of the functionalized polymers to form an aqueous blend, and ii) powderizing the aqueous blend to form the composite polymer process aid.
Disclosed is a composition comprising a PVDF copolymer where at least one comonomer is selected from Hexafluoropropene, 2,3,3,3-tetrafluoropropylene, 3,3,3-trifluoropropene, from 0.005-5% of one or more inorganic or polymeric nucleating additives and 0.01-20% of one or more dispersing agents having reduced haze. Also disclosed is a method of preparing the composition.
The present invention relates to optical fiber communication cables, and more particularly, relates to foamed polyvinylidene fluoride polymer filler rods used in optical fiber cable constructions. The foamed polyvinylidene fluoride polymer filler rod may or may not contain a central strength member. This invention includes cables containing the foamed PVDF filler rods of this invention. The present disclosure provides filler rods that have higher melting temperature than the conventional filler rods and methods of making the filler rods.
B32B 37/15 - Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state
G02B 6/44 - Mechanical structures for providing tensile strength and external protection for fibres, e.g. optical transmission cables
B32B 27/06 - Layered products essentially comprising synthetic resin as the main or only constituent of a layer next to another layer of a specific substance
B32B 27/08 - Layered products essentially comprising synthetic resin as the main or only constituent of a layer next to another layer of a specific substance of synthetic resin of a different kind
B32B 27/20 - Layered products essentially comprising synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
B32B 5/20 - Layered products characterised by the non-homogeneity or physical structure of a layer characterised by features of a layer containing foamed or specifically porous material foamed in situ
Feeding bees a composition containing at least one oxidizing agent (e.g., peroxide), optionally also containing other components such as an oxidizing agent activator or a viscosifying agent, to treat against, reduce and/or limit the spread of bacterial, virus, and fungi infestation in bees and/or beehives.
The invention relates to a fluoropolymer-acrylic coating composition that can be used, for example, in coating electrodes and/or separators in electrochemical devices. A coated separator for a lithium ion battery contains the porous separator substrate, and coatings on at least one side of the separator. The coating consists of an inorganic coating on at least one side of the separator, and an adhesive organic coating on at least one side of the inorganic coating or the separator. The organic coating contains an improved fluoropolymer-acrylic composition or a mixture of fluoropolymer and acrylic. The present invention can improve the adhesion of the coated separator to electrodes.
A coated separator for a lithium ion battery contains the porous separator substrate, and coatings on at least one side of the separator. The organic coating contains a silane functionalized fluoropolymer-acrylic composition or a mixture of silane functionalized fluoropolymer and non-silane functionalized fluoropolymer. The present invention can improve the adhesion of the coated separator to electrodes and offer good swelling properties in electrolyte.
H01M 50/46 - Separators, membranes or diaphragms characterised by their combination with electrodes
H01M 50/446 - Composite material consisting of a mixture of organic and inorganic materials
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
H01M 50/403 - Manufacturing processes of separators, membranes or diaphragms
C09J 127/22 - Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Adhesives based on derivatives of such polymers modified by chemical after-treatment
This invention discloses a method of fabricating a reticulated solid electrolyte/separator (RSES) which is suitable both as electrolyte and separator in a solid state battery. The reticulated composite is produced by casting and drying of a slurry which exhibits a high yield stress (greater than 50 dyne/cm2) and comprised of a high MW resin dissolved in a solvent (having solution viscosity of higher than 100 cp at 5% in NMP at room temperature) and dispersed nanoparticles of solid electrolyte of high specific surface areas (i.e. greater than 1 m2/g, preferable greater than 10 m2/g) including but not limited to LLZO, LSP, or LIPON or derivatives thereof. This reticulated solid electrolyte/separator exhibits superior cycling properties and high ionic conductivity, resists lithium dendrite penetration, and maintains a high dimensional stability (less than 10% shrinking) at elevated temperatures (up to 140° C.). In addition, the present disclosure relates to electrochemical cells comprising such a reticulated film composite to act as both electrolyte and separator.
The invention relates to a solid porous article having a crosslinked thermoplastic binder interconnecting one or more types of interactive powdery materials or fibers. The interconnectivity is such that the binder connects the powdery materials or fibers in discrete spots rather than as a complete coating, allowing the materials or fibers to be in direct contact with, and interact with a fluid. The resulting article is a formed multicomponent, interconnected web, with porosity. The separation article is useful in water purification, as well as in the separation of dissolved or suspended materials in both aqueous and non-aqueous systems in industrial uses, gas storage.
B01J 20/20 - Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising carbon obtained by carbonising processes
B01J 20/28 - Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
C02F 1/28 - Treatment of water, waste water, or sewage by sorption
B01D 15/00 - Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
B01D 53/04 - Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
This invention discloses a reticulated film composite and a method of fabricating the reticulated film composite suitable as a separator in electrochemical cells as sound absorbing films, or as high efficiency filtering media. The reticulated film composite is produced by casting and drying of a slurry which exhibits a high yield stress (i.e. greater than 50 dyne/cm2) and comprised of a high MW resin dissolved in a solvent (i.e. having solution viscosity of higher than 100 cp at 5% in NMP or in water at room temperature) and dispersed nanoparticles with high specific surface areas (i.e. greater than 10 m2/g) such as fumed alumina, or fumed silica, or fumed zirconia or mixture thereof. This reticulated film composite exhibits superior cycling properties and high ionic conductivity with a porosity up to 80% while maintains a high dimensional stability (i.e. less than 10% shrinking) at elevated temperatures (up to 140° C.). The reticulated composite separator coating can be used in combination with an electrode coating either in two separate process steps, or in a one-step process by having a simulations multi-layer casting of electrode and separator to manufacture a lithium ion battery.
C08J 9/28 - Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum
A method of manufacturing a semi-crystalline article from at least one pseudo-amorphous polymer including a poly aryl ether ketone, such as PEKK, including a softening step, wherein the at least one pseudo-amorphous polymer is heated to a temperature above its glass transition temperature to soften the polymer, and a crystallization step, wherein the at least one pseudo-amorphous polymer is heated to a temperature between its glass transition temperature and melting temperature, the pseudo-amorphous polymer being placed on a mold during either the softening step or the crystallization step before at least some crystallization takes place. The method results in articles demonstrating increased opacity, increased crystallinity, increased thermal resistance, improved chemical resistance, and improved mechanical properties over articles formed by traditional thermoforming processes.
A blowing agent for thermosetting foams is disclosed. The blowing agent is predominately the trans isomer of the hydrochlorofluoroolefin (HCFO) HFCO-1233zd alone or in combination with a hydrofluoroolefin (HFO), hydrofluorocarbon (HFC), hydrochlorofluoroolefin (HCFO), a hydrocarbon. The blowing agent is effective as a blowing agent in the manufacture of thermosetting foams.
C08L 79/00 - Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen, or carbon only, not provided for in groups
C08J 9/14 - Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
C08F 259/08 - Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group on to polymers containing fluorine
ABTRACT
ABTRACT
The present invention relates to a liquid, thermoplastic acrylic gel cap composition that can impart UV resistance, higher impact, and aesthetic effects to a composite material. Additionally, the post processing of the material when combined with a thermoplastic composite can allow for thermoformability, weldability and recyclability, unlike seen with traditional thermoset based gel coats.
Disclosed are voided latex particles, useful as opacifying agents for coating compositions containing organic solvents. The particles have a hollow interior, which substantially maintains its integrity after the particles are placed in contact with an organic solvent at 25° C. for 30 days. The particles also have a hydrophilic polymeric interior shell surrounding the hollow interior that is swellable with an aqueous swelling solution. The particles have first and second polymeric intermediate shells, surrounding the interior shell, formed from polymers that are different from each other and different from the interior shell polymer. Finally, the particles have an outer polymeric shell, surrounding the interior shells, which is formed from up to 100% by weight, as polymerized units, of methyl methacrylate. The interior shells and the outer shell each have a Tg greater than 60° C. Also disclosed is a multi-stage emulsion process for making the particles.
A curable composition containing at least one of a haloalkyl ether (meth)acrylate or a haloalkenyl ether (meth)acrylate and, optionally, one or more different types of co-monomers is cured to provide a polymer having advantageous properties as a result of the incorporation of halogenated functionality derived from the haloalkyl/haloalkenyl ether (meth)acrylate monomer.
The wet adhesion of a coating composition may be improved through the use of voided latex particles as opacifying agents which contain a hollow interior as well as an outer shell of a polymer containing functional groups such as amino, 1,3-diketo, urea or ureido. Other types of functional groups may be introduced to the outer shell polymer in order to vary other desired characteristics of the coating. The voided latex particles are non-film-forming.
C08F 265/06 - Polymerisation of acrylate or methacrylate esters on to polymers thereof
C08F 265/02 - Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group on to polymers of acids, salts or anhydrides
C08F 265/04 - Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group on to polymers of esters
C09D 151/00 - Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
B01J 13/20 - After-treatment of capsule walls, e.g. hardening
C08F 293/00 - Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
C09D 133/06 - Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
C09D 133/08 - Homopolymers or copolymers of acrylic acid esters
The invention relates to a process to produce a stable fluoropolymer latex using non-fluorinated surfactant with greater thermal stability. The polymerization is run at pressures greater than typically used. The resulting polymer exhibit improved melt color stability as compared to those produced under similar conditions at lower pressures.
The present disclosure is directed to a gas phase adsorption device comprising a large annulus and a small annulus block wherein the small annulus block is concentrically positioned inside the large annulus block. The present disclosure is also directed to a method for the storage of gas.
B01J 20/20 - Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising carbon obtained by carbonising processes
B01J 20/28 - Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
B01D 53/04 - Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
55.
SILICON- AND ZINC-CONTAINING COUPLING AGENT FOR CELLULOSIC MATERIAL-POLYMER COMPOSITES
A coupling agent formulation for cellulosic material-polymer composites is provided. The formulation includes a) at least one organic peroxide; and b) at least one of i) at least one zinc-containing reagent; and/or ii) at least one silicon-containing reagent. The coupling agent formulations produce polymer matrix cellulosic material composites with improved strength and aging characteristics. The improved strength may be related to physical properties such as improved stiffness, toughness or tensile strength. A masterbatch utilizing the coupling agent formulation is provided, as well as a method making the masterbatch.
Disclosed is a thermoplastic elastomer composition comprising a blend of at least two fluoropolymers. The first fluoropolymer has from 0 to 30 weight percent of a monomer J selected from the group consisting of hexafluoropropene (HFP), fluorinated or perfluorinated vinyl ethers, 2,3,3,3-tetrafluoropropene, trifluoropropene, 1-chloro-3,3,3-trifluoro propene or combinations thereof. The second fluoropolymer has at least 30 weight percent, preferably at least 35 weight percent, of monomer T selected from the group consisting of hexafluoropropene (HFP), fluorinated or perfluorinated vinyl ethers, 2,3,3,3-tetrafluoropropene, trifluoropropene, 1-chloro-3,3,3-trifluoro propene or combinations thereof.
Disclosed is a method of purifying a stream of crude hydrochlorofluoroolefin refrigerant produced by the reaction of 1,1,3,3 tetrachloropropene (R1230za) or 1,1,1,3,3-pentachloropropane (R240fa) with HF. The process includes a step of removing the cis-(Z) isomer by distillation of the crude refrigerant stream prior to a step of reacting the crude refrigerant stream with a base. The reaction with the base is a necessary step in production of the refrigerant and is done to remove HF and residual HCl from the crude refrigerant stream. Removal of the cis-(Z) isomer before the reaction with the base reduces the amount of toxic flammable trifluoropropyne (TFP) that is produced as a side-reaction during the reaction with the base. In addition, temperature control during the reaction with the base is less critical to minimizing the TFP production if the cis-(Z) isomer is first removed.
Disclosed is a step in the purification process of hydrochlorofluoroolefin refrigerants that are made from processes wherein 1,1,3,3 tetrachloropropene (R1230za) or 1,1,1,3,3-pentachloropropane (R240fa) is reacted with HF in excess. The purification process employs a cold-temperature reaction with a base to remove the HF and any HCl. The process prevents an increase in unwanted organic side-products, particularly trifluoropropyne (TPS), and simultaneously does not reduce the amount of the desired hydrochlorofluoroolefin refrigerant produced. The process also can have an optional step whereby hydrochlorofluoroolefin refrigerant and other organics are removed from aqueous process stream or streams resulting from the reaction with the base. The organics removed can be recycled. This optional step advantageously can increase the yield of the desired refrigerant, while decreasing the environmental load of the plant, by purifying the resulting aqueous process streams.
C07C 319/04 - Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols by addition of hydrogen sulfide or its salts to unsaturated compounds
B01J 19/12 - Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
A container which is useful for safely storing and transporting compositions, such as liquid organic peroxide-containing compositions, which may be flammable, combustible, susceptible to exothermic decomposition, explosive and/or otherwise hazardous, is provided. The container includes a containment vessel having thermoset polymer-containing walls, as well as a vent mechanism. The containment vessel may be manufactured by a rotational molding process using a thermoplastic polymer, such as a polyethylene, which is crosslinked to provide the thermoset polymer.
B05B 13/04 - Means for supporting work; Arrangement or mounting of spray heads; Adaptation or arrangement of means for feeding work the spray heads being moved during operation
B05B 5/08 - Plant for applying liquids or other fluent materials to objects
B05B 12/18 - Arrangements for controlling delivery; Arrangements for controlling the spray area for controlling the spray area using fluids, e.g. gas streams
B05B 12/36 - Side shields, i.e. shields extending in a direction substantially parallel to the spray jet
B05B 13/02 - Means for supporting work; Arrangement or mounting of spray heads; Adaptation or arrangement of means for feeding work
C23C 16/455 - Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition (CVD) processes characterised by the method of coating characterised by the method used for introducing gases into the reaction chamber or for modifying gas flows in the reaction chamber
B05D 3/04 - Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to gases
63.
Cyclic ether- and hydroxyl-containing compositions useful for producing fast dry alkyd polymers and methods for making such cyclic ether- and hydroxyl-containing compositions
An alkyd polymer composition for fast-drying, low VOC applications is provided. The alkyd polymer incorporates a minimum required level of a cyclic ether- and hydroxyl-containing composition formed from a sugar alcohol during the alcoholysis step while synthesizing the alkyd polymer. The disclosure also relates to the cyclic ether- and hydroxyl-containing composition which must have a minimum required level of cyclic ether structure incorporated therein in order to produce a sufficiently fast-drying alkyd polymer. Methods of making the cyclic ether- and hydroxyl-containing composition and the alkyd polymer comprising, as polymerized units, the cyclic ether- and hydroxyl-containing composition and a poly acid and/or an anhydride compound, as well as an optional polyol, other than the sugar alcohol, are also provided. Also provided is a 13 C NMR method of characterizing the necessary minimum required level of cyclic ether ring structure in the cyclic ether- and hydroxyl-containing composition and the alkyd polymer formed therefrom.
C07C 319/04 - Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols by addition of hydrogen sulfide or its salts to unsaturated compounds
B01J 19/12 - Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
The invention relates to heat treatment of polymorphic semicrystalline or crystallizable polymers to increase the content of the highest melting crystalline form. Such heat treatment results in a polymer powder that has a consistent, uniform melting range, improved flow and improved durability of the powder particle size for applications that require powder flow at elevated temperatures. In addition to improved powder properties, the articles produced from the powders also exhibit better physical properties in both appearance and in mechanical properties. Thus the invention also includes polymer powders and articles produced by the described processes.
C08L 61/16 - Condensation polymers of aldehydes or ketones with phenols only of ketones with phenols
B33Y 70/00 - Materials specially adapted for additive manufacturing
C08L 71/00 - Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
B29C 64/153 - Processes of additive manufacturing using only solid materials using layers of powder being selectively joined, e.g. by selective laser sintering or melting
B29C 39/08 - Introducing the material into the mould by centrifugal force
C08G 8/02 - Condensation polymers of aldehydes or ketones with phenols only of ketones
B29B 15/00 - Pretreatment of the material to be shaped, not covered by groups
66.
Process and apparatus for heat treatment of a polymer powder
A method and apparatus for heat treating powders of semi-crystalline or crystallizable polymers. The apparatus includes a heating device for heating the powder to a temperature that is less than the melting temperature of a highest melting crystalline form of the powder, a vessel containing the powder that is exposed to heat produced by the heating device, and a mechanism for moving the vessel to cause the powder within the vessel to move with respect to the vessel.
The invention relates to polyvinylidene fluoride (PVDF) copolymer compositions that have improved crosslinking efficiency and performance. The PVDF copolymer contains a high level (>14 and preferably greater than 16 wt %) of a fluorinated comonomer, and has a high molecular weight as measured by the melt viscosity at 230° C. and 100 sec−1 of 18 to 40 kpoise. The composition can be effectively cross-linked with a low level radiation (high cross-linking efficiency). The cross-linked composition is useful in high-temperature applications, such as automotive wire and cable, and heat shrink tubing.
C08L 27/16 - Homopolymers or copolymers of vinylidene fluoride
B32B 5/18 - Layered products characterised by the non-homogeneity or physical structure of a layer characterised by features of a layer containing foamed or specifically porous material
B32B 27/06 - Layered products essentially comprising synthetic resin as the main or only constituent of a layer next to another layer of a specific substance
B32B 27/20 - Layered products essentially comprising synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
H01B 3/44 - Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances waxes acrylic resins
68.
3-D PRINTED SEMI-CRYSTALLINE AND AMORPHOUS POLYMER ARTICLES
The invention relates to 3D printed parts made with thermoplastic polymers having a low stiffening temperature. 3D printed parts of the invention have very good Z layer adhesion, have a high elongation at break in the Z direction, preferably of more than 50 percent, and have at least an 80 percent ratio of Z to XY stress at yield or at break. The resulting part may be nearly isotropic—having similar mechanical properties in the XY and Z print directions. The excellent layer adhesion makes the resultant printed part more robust—able to withstand many cycles of use. Certain polymers of the invention produce printed parts that have a very low haze, and are nearly transparent.
A stable polyol pre-mix composition comprises a blowing agent, a polyol, a surfactant, and a catalyst composition comprising an oxygen-containing amine catalyst and a metallic salt. The oxygen-containing amine catalyst may be, for example, one or more of an alkanol amine, an ether amine, or a morpholine group-containing compound such as, for example, 2-(2-dimethylaminoethoxy)ethanol or N,N,N′-trimethylaminoethyl-ethanolamine. The metallic salt may be, for example, alkali earth carboxylates, alkali carboxylates, and carboxylates of metals selected form the group consisting of zinc (Zn), cobalt (Co), tin (Sn), cerium (Ce), lanthanum (La), aluminum (Al), vanadium (V), manganese (Mn), copper (Cu), nickel (Ni), iron (Fe), titanium (Ti), zirconium (Zr), chromium (Cr), scandium (Sc), calcium (Ca), magnesium (Mg), strontium (Sr), and barium (Ba)
c) at least one lower alkyl acrylate monomer in an amount ranging between about 1 wt. % to 20 wt. % based on the overall weight of the polymer composition.
The invention concerns polymer microfiltration or ultrafiltration porous membranes, intended for the treatment of effluents. More specifically, the invention concerns filtration membranes having at least one surface coated with a fluoropolymer-based latex.
B01D 69/02 - Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor characterised by their properties
The invention relates to a separator for non-aqueous-type electrochemical devices that has been coated with a polymer binder composition having polymer particles of two different sizes, one fraction of the polymer particles with a weight average particle size of less than 1.5 micron, and the other fraction of the polymer particles with a weight average particle size of greater than 1.5 microns. The bi-modal polymer particles provide an uneven coating surface that creates voids between the separator and adjoining electrodes, allowing for expansion of the battery components during the charging and discharging cycle, with little or no increase in the size of the battery itself. The bi-modal polymer coating can be used in non-aqueous-type electrochemical devices, such as batteries and electric double layer capacitors.
H01M 50/451 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising layers of only organic material and layers containing inorganic material
H01M 50/414 - Synthetic resins, e.g. .thermoplastics or thermosetting resins
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
H01M 50/454 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising a non-fibrous layer and a fibrous layer superimposed on one another
The invention relates to novel linear, semi-crystalline, functional fluoropolymers that have been obtained by copolymerizing a fluorinated vinylic monomer and a hydrophilic (meth)acrylic comonomer bearing a halogen functionality.
C08F 283/02 - Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass on to polycarbonates or saturated polyesters
C09D 151/08 - Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
C09D 133/16 - Homopolymers or copolymers of esters containing halogen atoms
C09D 127/16 - Homopolymers or copolymers of vinylidene fluoride
The invention relates to novel linear, semi-crystalline, functional fluoropolymers that have been obtained by copolymerizing a fluorinated vinylic monomer and a hydrophilic monomer chosen from vinyl alkyl acids, vinyl phosphonates, functional acrylamides, carbonates, vinyl ethers, alkoxy compounds, and double hydrophilic group monomers.
The invention relates to low density fluoropolymer foam, and preferably polyvinylidene fluoride (PVDF) foam, such as that made with KYNAR PVDF resins, and articles made of the foam. The foam is produced by adding microspheres containing blowing agents to the polymer and processing it through an extruder. The microspheres consist of a hard shell containing a physical blowing agent. The shell softens at elevated temperatures and allows the expansion of the blowing agent, and microsphere to create larger voids within the polymer matrix. By proper control of the polymer composition, viscosity, processing temperature, blowing agent selection, loading ratio, and finishing conditions, useful articles such as foamed PVDF pipe, tube, profiles, film, wire jacketing and other articles can be produced. The microspheres may be added to the fluoropolymer matrix by several means, including as part of a masterbatch with a compatible polymer carrier.
C08J 9/32 - Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof from compositions containing microballoons, e.g. syntactic foams
B29C 48/40 - Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws, e.g. twin screw extruders
A hose coupling guard including a fixture configured to connect to a hose coupling having a release mechanism, and a cover movably connected to the fixture to be movable between a first position and a second position. The cover includes a shield configured to enclose the release mechanism when the cover is in the first position, and to expose the release mechanism when the cover is in the second position. A display surface may be located on the shield and configured to be oriented to face a location from which an operator can operate the release mechanism.
The present disclosure is directed to an immobilized media device and methods for making an immobilized media device. The present disclosure is also directed to methods for the separation of components of a media comprising filtering the media through an immobilized media device.
B01J 20/20 - Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising carbon obtained by carbonising processes
B01J 20/28 - Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
B01J 20/30 - Processes for preparing, regenerating or reactivating
B01D 39/20 - Other self-supporting filtering material of inorganic material, e.g. asbestos paper or metallic filtering material of non-woven wires
C02F 1/00 - Treatment of water, waste water, or sewage
C02F 1/28 - Treatment of water, waste water, or sewage by sorption
78.
High strength polyvinylidene fluoride based reinforced compounds
The invention relates to the use of chopped fibers in thermoplastic composite compounds, and in particular to thermoplastic fluoropolymer compounds. The fluoropolymer matrix contains thermoplastic fluoropolymers that have been grafted with a carboxylic polar functionality, such as KYNAR ADX® polymer from Arkema. The chopped fiber—grafted fluoropolymer composite has increased tensile and flexural strength compared to fluoropolymer compounds that contain no grafted carboxylic grafted fluoropolymer.
C08F 259/08 - Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group on to polymers containing fluorine
C08L 27/16 - Homopolymers or copolymers of vinylidene fluoride
C08L 27/22 - Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers modified by chemical after-treatment
The present invention is directed to a polymerizable composition comprising (A) a reaction product of: (a) diethyleneglycol bischloroformate, ethyleneglycol bischloroformate, or combinations thereof; (b) allyl alcohol; (c) optionally, a cyclic polyol selected from the group consisting of a cycloaliphatic polyol having at least one secondary hydroxyl group, a heterocyclic polyol having primary and/or secondary hydroxyl groups, and mixtures thereof; and (d) optionally, at least one linear or branched aliphatic polyol having two to six hydroxyl groups; and (B) an organic peroxide comprising at least three peroxide groups. A polymerizate and/or an optical article comprising the polymerizable compositions of the invention are also provided.
The invention relates to a low coagulum fluoropolymer latex containing little or no surfactant, and having a high fluoropolymer solids content. The polymerization is run at temperatures somewhat greater than typically used. The latex can be dried into a solid resin, in which little or no surfactant is present, without using an ion exchange, washing, or other added unit operation. The invention also relates to the process for forming the high solids, latex, using little or no surfactant.
C08J 9/28 - Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum
The invention relates to thermoplastic filament for use in 3-D printers, in which the core of the filament is non-solid or mono-filament. The filament may contain a multitude of small micro-voids, (a micro foam), be a foam-core structure, be hollow, or have a monofilament core. The filament of the invention is especially useful with crystalline and semi-crystalline polymers, and reduces the negative effect of filament voids, formed by shrinkage during the cooling of the filament.
B33Y 70/00 - Materials specially adapted for additive manufacturing
B29C 64/118 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using filamentary material being melted, e.g. fused deposition modelling [FDM]
D01D 5/247 - Discontinuous hollow structure or microporous structure
D01F 1/08 - Addition of substances to the spinning solution or to the melt for forming hollow filaments
Methods and apparatus for measuring a thickness of a coating on an moving object are provided. Light is directed toward the object at a predetermined location on the object such that a portion of the light interacts with the object. A 1D and/or 2D maximum intensities for at least one wavelength channel is captured that is produced by the portion of the light interacting with the object. A measured average intensity of the wavelength channel and/or intensities and their arithmetic derivatives of multi wavelength channel geometries is converted into 1D (averaged) and/or 2D thickness values. Based on these values an acceptability of the coating is evaluated and thickness calculated.
G01B 11/06 - Measuring arrangements characterised by the use of optical techniques for measuring length, width, or thickness for measuring thickness
B05B 12/08 - Arrangements for controlling delivery; Arrangements for controlling the spray area responsive to condition of liquid or other fluent material discharged, of ambient medium or of target
B05D 1/02 - Processes for applying liquids or other fluent materials performed by spraying
83.
Accelerated peroxide-cured resin compositions having extended open times
Curable resin compositions having extended open times at ambient temperatures and short cure times at elevated temperatures are prepared using a curable resin, a combination of room-temperature-stable liquid peroxides (including at least one perketal), a promoter salt, a thiol-functionalized organic accelerator and a free radical trap. The curable resin compositions are useful in pultrusion, cure-in-place pipe and resin transfer molding applications, among others.
Compounds comprising one or more functionalized fatty acid esters, which may be derived from bio-based oils, are used as a low-VOC coalescent agent (i.e., a coalescent agent having a low content of volatile organic compounds) in waterborne coating compositions. The functional group can be epoxide, vicinal diol, hydroxy phosphotriester, hydroxy ester, hydroxyl alkyl ester, hydroxyl benzyl ester, hydroxy ether, hydroxy amino, hydroxy sulfide, hydroxy nitrile, hydroxy amine, terminal alcohol, thiiran, ketone, or cyclic carbonate. The present disclosure also relates to waterborne coating compositions comprising these functionalized fatty acid esters.
Accelerator solutions containing transition metal complexes based on organic ligands having one or more S—C—N, S—C—C—N, or S—C(═S)—S moieties are useful for accelerating the peroxide cure of resins such as unsaturated polyester resins.
A method of incorporating a peroxide source that produces reactive oxygen species and optionally also incorporating steam with the peroxide source (or other source of heat), into soil as a method of soil remediation, i.e., to destroy or remove chemical contaminants that pose a threat to plant or animal life. The invention also relates to the use of the peroxide source along with optional steam (or other heat source) or hot vaporized peroxide solution to treat soils, in particular those intended for agriculture, as a pesticide for controlling nematodes, pathogenic fungi, insect pests and bacteria. The peroxide source may be applied to the soil using soil cultivation equipment to increase contact between the peroxide source and the soil to be treated. The peroxide source and/or steam or other source of heat or hot vaporized peroxide solution can also be applied with injection wells or infiltration galleries, for instance, for the pesticide use and soil remediation.
The invention relates to a fluoropolymer coating composition that can be used, for example, in coating electrodes and/or separators in electrochemical devices. The fluoropolymer coating composition preferably contains multiple fluoropolymer phases. The coated electrodes and/or separators have both excellent wet adhesion, excellent dry adhesion, and low leachables. Each of the fluoropolymer phases contains polymers having at least 10 weight percent, of a common fluoromonomer, making the polymer phases compatible with each other, and allowing for the phases to be distributed fairly homogeneously on a macroscopic level throughout the composition and dried coating formed from the composition.
Film laminates containing a layer of a lower melting polyaryletherketone and a layer of a higher melting polyaryletherketone adhered to each other are resistant to heat, wear, moisture, weathering and chemicals and are useful for producing articles such as laminated electronic circuits, flexible heaters, insulated wire and cable, radio frequency identification tags and labeled articles.
B32B 7/12 - Interconnection of layers using interposed adhesives or interposed materials with bonding properties
B32B 27/28 - Layered products essentially comprising synthetic resin comprising copolymers of synthetic resins not wholly covered by any one of the following subgroups
B32B 27/08 - Layered products essentially comprising synthetic resin as the main or only constituent of a layer next to another layer of a specific substance of synthetic resin of a different kind
B32B 37/18 - Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with all layers existing as coherent layers before laminating involving the assembly of discrete sheets or panels only
89.
Compositions and methods for crosslinking polymers in the presence of atmospheric oxygen
Embodiments of organic peroxide formulations provide significant improvements in surface tackiness (often including tack-free surfaces) when curing elastomers in the presence of oxygen. The peroxide formulations may include, for example, one or more compounds selected from sulfur-containing compounds, organophosphite compounds, HALS (Hindered Amine Light Stabilizer) compounds, aliphatic allyl urethane compounds, and blends comprising nitroxides (e.g., 4-hydroxy-TEMPO) and quinones (e.g., mono-tert-butylhydroquinone).
Copolymers of one or more halogenated olefins and one or more halogenated co-monomers selected from the group consisting of halogenated alkenyl ethers, halogenated alkenyl esters, and halogenated (meth)acrylates are useful in various end-use applications wherein the presence of halogen (e.g., fluorine) in the copolymer imparts one or more desirable properties, as compared to analogous copolymers not containing halogen.
A curable composition containing at least one of a haloalkyl ether (meth)acrylate or a haloalkenyl ether (meth)acrylate and, optionally, one or more different types of co-monomers is cured to provide a polymer having advantageous properties as a result of the incorporation of halogenated functionality derived from the haloalkyl/haloalkenyl ether (meth)acrylate monomer.
A peroxide delivery system is produced. The peroxide delivery system includes a dry powder that releases the peroxide quickly and completely when needed. The peroxide delivery system may be produced by combining a liquid peroxide or peroxide solution with an inorganic solid support that is inert to the peroxide and is capable of adsorbing large amounts of the liquid peroxide or peroxide solution while remaining dry to the touch. Methods of combining the inorganic solid support with the liquid peroxide or peroxide solution are disclosed. The peroxide delivery system can be formulated in preparations of powders, liquids, foams, sprays, gels, ointments, creams, sticks, or pastes that can be utilized in a variety of applications such as cleaning, stain removal and antiseptic products, for example.
A61Q 11/00 - Preparations for care of the teeth, of the oral cavity or of dentures, e.g. dentifrices or toothpastes; Mouth rinses
A61Q 11/02 - Preparations for deodorising, bleaching or disinfecting dentures
A61Q 17/00 - Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
The invention relates to the use of a compatible thermoplastic material (film, sheet, or raft) as the base sheet or layer for 3-D printing an article. The use of the base film provides a means of printing a large article, and of reducing warpage by printing directly on the film. The printed article adheres to the film better than to traditional printer surfaces (glass, metal, glue, or reusable films), because the printed article and film weld together by forming chain entanglements, due to being compatible, miscible, or semi-miscible in the melt.
A method for synthesizing halogenated organic compounds, such as halogenated alkenyl group-containing and halogenated alkyl group-containing compounds having a heteroatom (e.g., O,N.S) coupled to a carbon atom of a halogenated alkenyl or halogenated alkyl group, involves reacting a halogenated olefin such as a chloro-substituted trifluoropropenyl compound with an active hydrogen-containing organic compound such as an alcohol (e.g., an aliphatic monoalcohol, aliphatic polyalcohol, or a phenolic compound), a primary amine, a secondary amine or a thiol.
C07C 41/16 - Preparation of ethers by reaction of esters of mineral or organic acids with hydroxy or O-metal groups
C07C 303/22 - Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof from sulfonic acids by reactions not involving the formation of sulfo or halosulfonyl groups
C07D 233/58 - Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring nitrogen atoms
C07D 231/12 - Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
C07C 213/06 - Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton from hydroxy amines by reactions involving the etherification or esterification of hydroxy groups
C07D 317/22 - Radicals substituted by singly bound oxygen or sulfur atoms etherified
C07C 67/04 - Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
C07C 43/247 - Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring and to a carbon atom of a ring, other than a six-membered aromatic ring containing halogen
The present invention is directed to material extrusion additive manufacturing processes, including fused filament fabrication, used to manufacture improved parts, devices, and prototypes using polyetherketoneketones (“PEKK”) and polyetheretherketones (“PEEK”). Using the improved processes of the invention, PEKK or PEEK polymer readily is 3D printed by FFF such that it crystallizes slowly enough during deposition for the resulting part to remain mostly or substantially amorphous during printing and thus have low percentage and/or more uniform shrinkage per layer and little to no warping from the base during print, and yet fast enough so that the resulting part crystallizes in post-print processing without substantial or any loss of its printed structure.
B29C 64/118 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using filamentary material being melted, e.g. fused deposition modelling [FDM]
The present invention relates to blowing agent compositions comprising at least one hydrofluoroolefin (HFO) selected from cis- and/or trans-1,3,3,3-tetrafluoropropene (HFO-1234ze) and at least one hydrochlorofluoroolefin (HCFO) selected from cis- and/or trans-1-chloro-3,3,3-trifluoropropene (HCFO-1233zd) used in the preparation of foamable thermoplastic compositions. The blowing agent compositions are useful in the production of low density insulating foams with improved k-factor.
C08J 9/14 - Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
C08J 9/12 - Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
The invention relates to fluoropolymer filament for use in 3-D printing, and 3-D printed fluoropolymer articles having low warpage, excellent chemical resistance, excellent water resistance, flame resistance, and good mechanical integrity. Additionally, the articles of the invention have good shelf life without the need for special packaging. In particular, the invention relates to filament, 3-D printed polyvinylidene fluoride (PVDF) articles, and in particular material extrusion 3-D printing. The articles may be formed from PVDF homopolymers, copolymers, such as KYNAR® resins from Arkema, as well as polymer blends with appropriately defined low shear melt viscosity. The PVDF may optionally be a filled PVDF formulation. The physical properties of the 3-D printed articles can be maximized and warpage minimized by optimizing processing parameters.
B29C 64/112 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using individual droplets, e.g. from jetting heads
C08L 27/16 - Homopolymers or copolymers of vinylidene fluoride
B33Y 70/00 - Materials specially adapted for additive manufacturing
B33Y 80/00 - Products made by additive manufacturing
B29C 64/118 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using filamentary material being melted, e.g. fused deposition modelling [FDM]
C08K 3/30 - Sulfur-, selenium-, or tellurium-containing compounds
B29K 27/12 - Use of polyvinylhalogenides as moulding material containing fluorine
C08L 61/00 - Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
C08L 27/14 - Homopolymers or copolymers of vinyl fluoride
C08L 27/18 - Homopolymers or copolymers of tetrafluoroethene
C08L 71/00 - Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
C08L 33/12 - Homopolymers or copolymers of methyl methacrylate
C08L 61/16 - Condensation polymers of aldehydes or ketones with phenols only of ketones with phenols
B29C 64/106 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
C08L 27/12 - Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
C08L 27/20 - Homopolymers or copolymers of hexafluoropropene
B29K 33/00 - Use of polymers of unsaturated acids or derivatives thereof, as moulding material
B32B 27/08 - Layered products essentially comprising synthetic resin as the main or only constituent of a layer next to another layer of a specific substance of synthetic resin of a different kind
A dispersion of an alkyd-containing polymer dispersed in water is used to form a waterborne coating composition; the alkyd-containing polymer being an acrylic-modified alkyd polymer, a silicone-acrylic-modified alkyd polymer, or a mixture thereof. The resulting waterborne coating composition includes about 2 to about 30% by weight of one or more thermal insulating fillers with the remainder being the alkyd-containing dispersion, such that the coating composition contains about 30 to about 80% by weight of the water and about 2 to about 50% by weight of the alkyd-containing polymer. The coating applied therefrom exhibits at least one of the following properties: a thermal conductivity that is less than 100 mW/mK; a weight retention of at least 70% after being heated up to 400 C as measured by thermogravimetric analysis (TGA) with a heating rate of 20 C/min.; or a weight loss of less than 50% up to a temperature of 470 C as measured by the TGA.
C09D 151/08 - Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
C08G 63/672 - Dicarboxylic acids and dihydroxy compounds
C08G 81/02 - Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers at least one of the polymers being obtained by reactions involving only carbon-to-carbon unsaturated bonds
The invention relates to fluoropolymer composites having a fluoropolymer matrix containing a functionalized fluoropolymer composition, and reinforced with fibers. The fibers can be chopped fibers, long fibers, or a mixture thereof, and the fluoropolymer matrix preferably is based on polyvinylidene fluoride. Any type of fibers, sized or unsized may be used with the functionalized fluoropolymer matrix composition to form the fluoropolymer composite.
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