01 - Chemical and biological materials for industrial, scientific and agricultural use
Goods & Services
Chemical products for industry; adhesives (adhesive
materials) for industry; unprocessed artificial resins in
the form of powders or pastes; unprocessed synthetic resins;
vulcanizing agents; hot-melt adhesives.
The present invention belongs to the field of three-dimensional printing methods. It relates to a method for printing a three-dimensional article made of polycyanoacrylate. It also relates to a method for recycling a three-dimensional article made of polycyanoacrylate.
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
B29B 17/02 - Separating plastics from other materials
It is provided a photocurable adhesive composition, an article comprising at least one surface coated with the adhesive composition and the use thereof. The photocurable adhesive composition exhibits a good storage stability and a good adhesiveness, and which ensures at the same time a satisfactory curing time. It makes it possible to obtain good quality articles presenting a high flexibility.
01 - Chemical and biological materials for industrial, scientific and agricultural use
16 - Paper, cardboard and goods made from these materials
Goods & Services
Glues for industrial use and for the construction industry. Adhesives (glues) for stationery or household purposes;
adhesives for do-it-yourself; wood glues for household use;
fabric glues for household use; glues for office use; glues
for glass for household use; glues for leather for household
use.
5.
TWO-COMPONENT POLYURETHANE STRUCTURAL ADHESIVE WITH IMPROVED PROPERTIES
A PU2K structural adhesive composition comprising an —NCO component and a hardener component. The —NCO component and hardener component each comprise from 0.1% to 40% by weight of a thixotropic composition (A) comprising a bis-urea obtained by reaction of a primary aliphatic amine with a diisocyanate, in suspension in a continuous phase consisting of a plasticizer chosen from an alkyl phthalate and pentaerythritol tetravalerate; and at least one component, among the —NCO component and hardener component, comprises from 5% to 40% by weight of alumina. The structural adhesive is used in the field of construction, the manufacture of transportation means, preferably of the motor vehicle, rail and aerospace industries, and shipbuilding.
01 - Chemical and biological materials for industrial, scientific and agricultural use
Goods & Services
Industrial chemicals; industrial adhesives; artificial resins in the form of powders or pastes; raw synthetic resins; vulcanizing agents; hot-melt adhesives
7.
HOT-MELT PRESSURE-SENSITIVE ADHESIVES FOR RESEALABLE PACKAGING
The present invention relates to a hot-melt pressure-sensitive adhesive composition comprising: - i) from 40% to 80% by weight of at least one but-1-ene-ethylene copolymer A, said copolymer comprising more than 80% by weight of units derived from but-1-ene; - ii) from 1.5% to 4.5% by weight of at least one propylene-ethylene-butene copolymer T, said copolymer T comprising more than 50% by weight of units derived from propylene; - iii) at least one non-hydrogenated tackifying resin obtained by polymerization, or copolymerization with an aromatic hydrocarbon, of mixtures of unsaturated aliphatic hydrocarbons having from 4 to 6 carbon atoms derived from petroleum cuts.
The present invention relates to the use of a multilayer system F1 comprising: - a layer C1 comprising at least one polyolefin, - an adhesive layer A comprising the product of reaction between an -NCO component and an -OH component, and - a layer C2 comprising at least one polyolefin, for preparing a recycled item, said multilayer system F1 comprising at least 90% by weight of a polyolefin or of a mixture of polyolefins relative to the total weight of said system.
C09J 175/14 - Polyurethanes having carbon-to-carbon unsaturated bonds
B32B 27/08 - Layered products essentially comprising synthetic resin as the main or only constituent of a layer next to another layer of a specific substance of synthetic resin of a different kind
The present invention relates to a recycled article comprising a polyolefin or a mixture of polyolefins, and a reaction product between an –NCO component and an –OH component, said article having a maximum haze value of 20%.
B32B 27/08 - Layered products essentially comprising synthetic resin as the main or only constituent of a layer next to another layer of a specific substance of synthetic resin of a different kind
1) Moisture curable silylated adhesive composition comprising:
from 20% to 50% weight of a silane modified APAO;
from 2% to 15% weight of a filler consisting of expanded hollow thermoplastic polymer microspheres; and
from 10% to 60% weight of a tackifying agent.
1) Moisture curable silylated adhesive composition comprising:
from 20% to 50% weight of a silane modified APAO;
from 2% to 15% weight of a filler consisting of expanded hollow thermoplastic polymer microspheres; and
from 10% to 60% weight of a tackifying agent.
2) Method for manufacturing an assembly product comprising:
heating at from 130° C. to 180° C. said composition to make it liquid enough to be applied on a substrate, then
coating said composition on the surface of a primary substrate, then
putting into contact the coated surface of the primary substrate with the surface of a secondary substrate, then
chemically curing the coated composition with water, preferably with atmospheric moisture.
C09J 151/06 - Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
B32B 37/12 - Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
B32B 7/12 - Interconnection of layers using interposed adhesives or interposed materials with bonding properties
B32B 15/04 - Layered products essentially comprising metal comprising metal as the main or only constituent of a layer, next to another layer of a specific substance
B32B 15/20 - Layered products essentially comprising metal comprising aluminium or copper
The present invention relates to an adhesive composition, characterized in that same makes it possible to recycle a multilayer system F1 comprising said adhesive composition, in order to prepare an article comprising at least 25% by weight of said recycled system F1.
The present invention relates to an aqueous adhesive composition comprising: —a) an amylomaltase-treated starch or an amylomaltase-treated maltodextrin; and —b) ammonium zirconium carbonate.
The present invention relates to a hot melt adhesive composition comprising: at least one styrene block copolymer; at least one bio-based tackifier resin; and optionally at least one plasticizer chosen from: an esterified fatty acid; and a stand oil; wherein the hot melt adhesive composition has a glass transition temperature higher than 0° C. The present invention further relates to the use of said hot-melt adhesive composition for bonding two substrates and to an article comprising said hot-melt adhesive composition.
C09J 145/00 - Adhesives based on homopolymers or copolymers of compounds having no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic or in a heterocyclic ring system; Adhesives based on derivatives of such polymers
B32B 37/12 - Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
B32B 5/02 - Layered products characterised by the non-homogeneity or physical structure of a layer characterised by structural features of a layer comprising fibres or filaments
The invention relates to a two-component composition comprising: − a component A comprising a reaction product obtained by reacting at least: − an aliphatic polyisocyanate, and − a crystalline polyester polyol having a number average molecular weight of less than 3000 g/mol; and − a component B comprising: − at least one polyester polyol, − a chain extender, and − a silane coupling agent. Furthermore, the invention relates to the use of the composition according to the invention, as an adhesive to manufacture an article having a bonding strength value after sterilization greater than or equal to 3.5 N/15mm. The invention also relates to a multilayer film comprising at least two layers of substrates bonded together by a continuous layer, wherein said continuous layer consists of the two-component composition according to the invention. The invention also relates to the use of the multilayer film according to the invention for the manufacture of flexible packaging intended for sterilization treatments.
B32B 7/12 - Interconnection of layers using interposed adhesives or interposed materials with bonding properties
C08G 18/12 - Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
15.
ADHESIVE TWO-COMPONENT COMPOSITION BASED ON ITACONATE MONOMER
The present invention relates to a two-component adhesive composition comprising:
a component A comprising:
at least one polyurethane P comprising at least two (meth)acrylate end functions;
at least one reducing agent; and
at least one itaconate monomer of following formula (1):
The present invention relates to a two-component adhesive composition comprising:
a component A comprising:
at least one polyurethane P comprising at least two (meth)acrylate end functions;
at least one reducing agent; and
at least one itaconate monomer of following formula (1):
wherein each of R1 and R2 represents, independently of one another, organic radicals;
at least one core-shell impact modifier;
a component B comprising:
at least one oxidizing agent; and
optionally at least one (meth)acrylate monomer M1.
The present invention relates to a hot melt adhesive composition comprising: − at least one block copolymer (P1) comprising : o a polymer block (A) containing a structural unit derived from an isoprenoid conjugated diene, o a non-elastomeric polymer block (B) containing a structural unit derived from an aromatic vinyl compound; wherein said block copolymer (P1) has a biocarbon content equal to or higher than 45%, and said block copolymer (P1) is at least partially hydrogenated; − at least one bio-based tackifier resin, and wherein the hot melt adhesive composition has a glass transition temperature higher than 0°C.
C09J 153/02 - Vinyl aromatic monomers and conjugated dienes
C08L 53/02 - Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl aromatic monomers and conjugated dienes
The present invention relates to a hot melt pressure-sensitive adhesive composition comprising: − at least 20% by weight of one or more block copolymer(s) (P1) comprising : - a polymer block (A) containing a structural unit derived from an isoprenoid conjugated diene, - a non-elastomeric polymer block (B) containing a structural unit derived from an aromatic vinyl compound; wherein said block copolymer (P1) has a biocarbon content equal to or higher than 45%, and said block copolymer (P1) is at least partially hydrogenated; − at least one bio-based tackifier resin selected from the group consisting of: - natural or modified rosins such as, for example, gum rosins, wood rosins, tall-oil rosins, distilled rosins, (partially or fully) hydrogenated rosins, dimerized rosins and polymerized rosins; - polyterpene derivatives; - and mixtures thereof; wherein the hot melt adhesive composition has a glass transition temperature lower than 0°C.
The invention relates to an ionic silylated copolyurethane of formula (I): (I) The invention also relates to a process for preparing the ionic silylated copolyurethane of formula (I) according to the invention, to a composition comprising said ionic silylated copolyurethane and to the use of said composition.
C08G 18/12 - Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
C08G 18/18 - Catalysts containing secondary or tertiary amines or salts thereof
C08G 18/28 - Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
C09J 175/12 - Polyurethanes from compounds containing nitrogen and active hydrogen, the nitrogen atom not being part of an isocyanate group
C09J 201/10 - Adhesives based on unspecified macromolecular compounds characterised by the presence of specified groups containing hydrolysable silane groups
C09K 3/10 - Materials not provided for elsewhere for sealing or packing joints or covers
19.
TWO-COMPONENT THERMALLY CONDUCTIVE COMPOSITION OF SILYL POLYMER
The invention relates to a two-component thermally conductive composition comprising: a composition (A) comprising: a silyl polymer, and a composition (B) comprising: at least 1% by weight of a filler (C) relative to the total weight of the composition (B), the filler (C) providing at least 0.0025% by weight of moisture relative to the total weight of the composition (B), the composition (A) and/or the composition (B) further comprising at least one thermally conductive filler, and the composition (A) and/or the composition (B) further comprising: a rheology agent (r1) chosen from amide waxes and/or a rheology agent (r2) comprising: from 1% to 40% by weight of a bisurea (a) obtained by reaction of an aliphatic primary amine with a diisocyanate having a molar mass of less than 500 g/mol, relative to the total weight of the rheology agent (r2), and from 60% to 99% by weight of a specific plasticizer (b), relative to the total weight of the rheology agent (r2), said rheology agent (r2) being in the form of a suspension of solid particles of bisurea (a) in a continuous phase of plasticizer (b). The invention also relates to the use of a filler (C) having a specific moisture content, for the crosslinking, without addition of free water, of a two-component composition, the two-component composition comprising a composition (A) comprising a silyl polymer, and a composition (B) comprising said filler (C).
C09J 201/10 - Adhesives based on unspecified macromolecular compounds characterised by the presence of specified groups containing hydrolysable silane groups
C08K 3/013 - Fillers, pigments or reinforcing additives
C08L 101/10 - Compositions of unspecified macromolecular compounds characterised by the presence of specified groups containing hydrolysable silane groups
The present invention concerns a compound of formula (I), wherein R1 is H or an organic moiety, said compound of formula (I) having a biocarbon content equal to or higher than 20%.
C07C 255/23 - Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms containing cyano groups and carboxyl groups, other than cyano groups, bound to the same unsaturated acyclic carbon skeleton
C09J 4/00 - Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond
C07D 307/12 - Radicals substituted by oxygen atoms
CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (France)
Inventor
Mazajczyk, Jérôme
Barrat, Alexis
Simon, Frédéric
Lalevee, Jacques
Fouquay, Stéphane
Abstract
The present invention relates to a crosslinkable two-component composition comprising: - a component A comprising: - an organic copper derivative; - at least one (meth)acrylate compound M1; provided that when the organic copper derivative is not halogenated, then component A also comprises a halogenated carboxylic acid; - a component B comprising at least one compound having the following formula (VI): [Ra2pp, Qp+ (VI) and uses thereof.
CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (France)
Inventor
Mazajczyk, Jérôme
Barrat, Alexis
Simon, Frédéric
Lalevee, Jacques
Fouquay, Stéphane
Abstract
The present invention relates to a method for assembling two substrates by adhesive bonding, comprising the following steps: i) mixing the components A and B of a two-component crosslinkable composition; ii) coating, onto at least one of the two substrates to be assembled, the mixture obtained in step i); activating said mixture during or after the coating, by subjecting to electromagnetic radiation; iv) bringing the two substrates into effective contact; v) crosslinking the mixture.
01 - Chemical and biological materials for industrial, scientific and agricultural use
Goods & Services
Adhesives (sticking substances) for the adhesiveness of different substrates, in particular metals, plastics and composite materials for use in industry.
The invention relates to a moisture curable composition, comprising: at least one silyl-modified polymer (A); at least one organofunctional silane compound (B) possessing at least one amino group and a hydrolysable silyl group; and at least one flame retardant component (C) comprising a halogen-free nitrogen-phosphorous flame retardant. The invention further relates to the use of said moisture curable composition as a sealant, as an adhesive or as a coating, as well as an article comprising at least one layer obtained by curing said moisture curable composition.
C09D 171/00 - Coating compositions based on polyethers obtained by reactions forming an ether link in the main chain; Coating compositions based on derivatives of such polymers
C09J 171/00 - Adhesives based on polyethers obtained by reactions forming an ether link in the main chain; Adhesives based on derivatives of such polymers
C08G 18/10 - Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
C08G 18/12 - Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
C08G 18/38 - Low-molecular-weight compounds having hetero atoms other than oxygen
The invention relates to a kit comprising a component (A) comprising an aqueous dispersion comprising at least one polymer; a component (B) comprising at least one curing agent; and a component (C) comprising at least one coloring agent. The invention further relates to the use of the kit as an adhesive or a coating. The invention also relates to a method for bonding two substrates or for coating a surface of a substrate comprising mixing the components A, B, C, as well as to an article obtained by the use or the method.
C08L 31/00 - Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of c; Compositions of derivatives of such polymers
C08L 33/00 - Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters,; Compositions of derivatives of such polymers
C08L 63/00 - Compositions of epoxy resins; Compositions of derivatives of epoxy resins
The present invention relates to a polyamide, to a composition comprising same, and to the use thereof, and also to a molded article deriving therefrom and to a process for producing same. The polyamide is particularly suitable as hot-melt adhesive for the low-pressure and low-temperature overmolding of a heat-sensitive battery, for example a lithium-polymer battery.
C08G 69/26 - Polyamides derived from amino carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
C08L 77/06 - Polyamides derived from polyamines and polycarboxylic acids
B29C 45/14 - Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
B29C 45/00 - Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
C09J 177/06 - Polyamides derived from polyamines and polycarboxylic acids
C09J 5/06 - Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers involving heating of the applied adhesive
The invention relates to a composition comprising: - a silylated polymer, - carbon black having an oil absorption number (OAN) of at least 80 ml/100 g, and - a rheology agent. The invention also relates to the use of the composition according to the invention for adhesive bonding and sealing purposes.
A multilayer film comprises an adhesive layer A comprising an HMPSA composition (a); a complexable thin layer B comprising a PolyPropylene (PP) composition (b); and a heat-sealable and breakable layer C comprising a PolyPropylene (PP) composition (c). Layers B and C are bonded together by layer A and the film is characterized in that the melt flow indices of compositions (a), (b) and (c), denoted MFI(a), MFI(b) and MFI(c), respectively, are such that the ratios MFI(a)/MFI(b) and MFI(a)/MFI(c) are each between 0.3 and 3.5. A process for manufacturing the film comprises flat sheet coextrusion of composition (a) and of compositions (b) and (c) at a temperature of between 150° C. and 250° C. Resealable packaging can comprise the multilayer film.
B32B 27/08 - Layered products essentially comprising synthetic resin as the main or only constituent of a layer next to another layer of a specific substance of synthetic resin of a different kind
B32B 7/12 - Interconnection of layers using interposed adhesives or interposed materials with bonding properties
The present invention relates to a pressure sensitive hot melt adhesive, particularly to a pressure sensitive hot melt positioning adhesive for use on feminine sanitary pads or adult incontinent products having improved peel values on fabrics made from Lyocell fibers, particularly eucalyptus-based Lyocell fibers.
The present invention concerns a two-part curable composition comprising: a) a first part (part A) comprising: ‐ at least one cyanoacrylate monomer; b) a second part (part B) comprising : ‐ a nucleophilic initiator; ‐ a plasticizer; said two-part curable composition further comprising a color changing indicator in part A and/or part B; said nucleophilic initiator being selected from the group consisting of : organic bases, quaternary ammonium salts, metal salts of carboxylic acids, and mixtures thereof. The present invention also concerns its use, in particular for determining cure of said composition.
The present invention relates to a hot melt adhesive composition comprising: i) a copolymer polymerized by metallocene catalysis; ii) 2% to 50% by weight, relative to the total weight of said composition, of a naturally sourced wax having a dropping point of 65°C to 105°C; iii) a tackifying resin; said hot melt adhesive composition having a viscosity of less than 3000 mPa.s at 130°C.
The invention relates to a hot melt adhesive composition comprising from 5 to 35 % by weight of at least one styrene block polymeric component, from 40 to 65 % by weight of at least one tackifying resin, from 15 to 40 % by weight of at least one plasticizer, from 3 to 15 % by weight of at least one polyolefin wax having an enthalpy of crystallization of at least 45 J/g, and from 0 to 5 % by weight of at least one stabilizer, based on the total weight of the hot melt adhesive composition. The invention also relates to a process for preparing such a hot melt adhesive composition, to an article comprising such a hot melt adhesive composition and to the use of such a hot melt adhesive composition for adhering a hygiene disposable article on a fabric.
C09J 153/02 - Vinyl aromatic monomers and conjugated dienes
C08L 51/06 - Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
The present invention relates to an adhesive composition comprising a polymer composition, lightened fillers, carbonate fillers; and a tackifying resin, and also to its use for applying a flexible surface covering to a substrate and to a corresponding bonding process.
01 - Chemical and biological materials for industrial, scientific and agricultural use
Goods & Services
Industrial chemicals; Adhesives for use in industry; Unprocessed artificial resins in the form of powders or Synthetic resins, unprocessed In the form of pastes; Synthetic resins, unprocessed; Vulcanising preparations; Hot melts.
01 - Chemical and biological materials for industrial, scientific and agricultural use
Goods & Services
Industrial chemicals; Adhesives for use in industry; Unprocessed artificial resins in the form of powders or Synthetic resins, unprocessed In the form of pastes; Synthetic resins, unprocessed; Vulcanising preparations; Hot melts.
The present invention relates to a hot melt adhesive composition comprising styrene triblock copolymer components, and related articles comprising at least one interior or exterior surface coated with the hot melt adhesive composition.
The invention relates to an adhesive composition comprising at least one silyl polymer comprising at least one hydrolyzable alkoxysilane group; at least one polyvinyl ether compound; and at least one curing catalyst, and also to the use of said composition as an adhesive and also to self-adhesive articles comprising at least one support layer and at least one layer of said composition.
The present invention refers to a curable two-part adhesive composition comprising a first part comprising one or more cyanoacrylate monomer(s), one or more (metha)acrylate monomer(s), a per-compound and, optionally, additives to control viscosity and rheology; and a second part comprising: a non-reactive diluent and a transition metal catalyst, and optionally an electron rich initiator for cyanoacrylates. It also relates to a syringe or a cartridge comprising said two-part curable composition, to the use of such composition for bonding substrates, to the use of such composition filling depressions, cracks or holes in a substrate or between substrates to a method for bonding substrates using said composition, and to a repair method for filling depressions, cracks or holes in a substrate or between substrates using said composition.
The use, for seamless textile assembly by printing, of a copolyamide including: a) at least one hard segment obtained by polycondensation of at least one of the following: (i) an α,ω-aminocarboxylic acid; (ii) a lactam; and/or (iii) an aliphatic diacid with 6 to 22 carbon atoms and at least one aliphatic diamine with 2 to 14 carbon atoms, and, optionally, b) at least one soft segment obtained by polycondensation of at least one diacid with 4 to 44 carbon atoms with at least one diamine chosen from diamines with 2 to 44 carbon atoms and polyoxyalkylene diamines, the copolyamide having a melting temperature Tm above 80° C. and below 210° C. and a viscosity at 170° C., as measured according to standard ASTM D3236-88 (2009), using a Brookfield rheometer with SC 4-27 spindle, of between 5 Pa·s and 100-200 Pa·s.
The invention relates to a hot melt adhesive composition comprising a polymer component, the polymer component comprising at least one styrene-butadiene-styrene block copolymer P having a styrene content from 35 to 50% by weight; a styrene-butadiene diblock content from 50 to 80% by weight; and a viscosity of a 15% by weight toluene solution at 25° C. of 20 to 40 mPa.s, and at least one styrene block copolymer other than a styrene-butadiene-styrene block copolymer, wherein said styrene-butadiene-styrene block copolymer P is at a content from 10 to 40% by weight relative to the total weight of the polymer component. The invention also relates to the use of said composition as an adhesive for bonding two substrates, and to articles comprising at least one interior or exterior surface coated with said composition.
C09J 153/02 - Vinyl aromatic monomers and conjugated dienes
C09D 153/02 - Vinyl aromatic monomers and conjugated dienes
B32B 5/02 - Layered products characterised by the non-homogeneity or physical structure of a layer characterised by structural features of a layer comprising fibres or filaments
B32B 7/12 - Interconnection of layers using interposed adhesives or interposed materials with bonding properties
42.
MULTILAYER FILM FOR RECLOSABLE PACKAGE WITH A POLYETHYLENE LAYER OBTAINED BY FLAT SHEET COEXTRUSION
A multilayer film comprises an adhesive layer A comprising an HMPSA composition (a); a complexable thin layer B comprising a PolyEthylene (PE) composition (b); and a heat-sealable and breakable layer C comprising a PolyEthylene (PE) composition (c). Layers B and C are bonded together by layer A. The film is characterized in that (i) the melt flow indices of compositions (b) and (c), denoted MFI(b) and MFI(c), respectively, are each between 2.5 and 15 g/10 minutes; and (ii) the melt flow index of composition (a), denoted MFI(a), is such that the ratios MFI(a)/MFI(b) and MFI(a)/MFI(c) are each between 1.5 and 10. A process for manufacturing the film comprises flat sheet coextrusion of composition (a) and of compositions (b) and (c) at a temperature of between 150° C. and 250° C. The multilayer film can be used for the manufacture of resealable packaging.
B32B 27/08 - Layered products essentially comprising synthetic resin as the main or only constituent of a layer next to another layer of a specific substance of synthetic resin of a different kind
B32B 27/18 - Layered products essentially comprising synthetic resin characterised by the use of special additives
01 - Chemical and biological materials for industrial, scientific and agricultural use
17 - Rubber and plastic; packing and insulating materials
19 - Non-metallic building materials
Goods & Services
Chemical products for use in industry; chemical products for
the manufacture of adhesives; adhesives (adhesive materials)
for industry; adhesives for ceiling coverings, for floor
coverings, for wall coverings; glues for repair and assembly
of objects; glues for wallpaper; separating and unsticking
[ungluing] products; primers (glues); solvents (chemical
products for use in industry) for glues; unprocessed epoxy,
acrylic and synthetic resins; unprocessed plastic materials. Epoxy, acrylic and synthetic resins (semi-finished
products); packing, stopping and insulating materials;
sealant compounds for joints; insulating coatings;
insulating varnish; adhesive tapes and strips other than for
medical, stationery or household purposes; waterproof
packings; plastic film, plastic membrane, adhesive tape for
installing floor coverings. Non-metallic construction materials; mortar for building;
cement; coatings (building materials); plaster; pitch;
concrete; lime; patching and leveling plaster coats for
walls, floors and ceilings; products for patching walls,
floors and ceilings.
44.
HOT MELT ADHESIVE COMPOSITIONS BASED ON POLY(ALPHA-METHYL-BETA-PROPIOLACTONE) POLYMERS OR DERIVATIVES AND METHODS FOR USING THEM
A hot melt adhesive composition comprises a polymer comprising poly(α-methyl-β-propiolactone) (PMPL) or a derivative thereof, wherein the PMPL is polymerized from a plurality of (R)-α-methyl-β-propiolactone monomers and a plurality of (S)-α-methyl-β-propiolactone monomers, wherein the ratio of (R):(S) monomers is from about 90:10 to about 10:90. Changing the (R):(S) ratio impacts the isotactic diad fraction and consequently the crystallinity and thermomechanical properties of the resulting PMPL. The PMPL may be hydroxyl-terminated, with the residue thereof serving as the elastomeric B block in an A:B:A triblock copolymer having hard end A blocks, such as a residue of polylactic acid. The PMPL diol may also be used as a reactant to form an alkoxysilane-terminated polymer, a polyurethane, or a (co)polyester. In some embodiments, such triblock polymers may be entirely bio-sourced and compostable.
CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (France)
UNIVERSITE DE BORDEAUX (France)
INSTITUT POLYTECHNIQUE DE BORDEAUX (France)
Inventor
Delgado, Marine
Michaud, Guillaume
Colin, Boris
Simon, Frédéric
Fouquay, Stéphane
Pucheault, Mathieu
Abstract
The present invention relates to a two-component composition comprising a first part (A) comprising a borane BH3-amine complex and an alkene compound, and a second part (B) comprising at least one radically polymerizable compound comprising at least one ethylenic bond, and to an adhesive composition obtained therefrom, and also to uses thereof. The invention also relates to articles made with this composition.
It is provided a foam composition particularly comprising a binding agent, a filler, a dispersing agent, a lubricating agent, and a solvent, said foam composition being packaged with a propellant. The foam, obtained upon dispensing the foam composition, is particularly suitable for use on all indoor applications, for example for closing gaps in partition walls and floors, for sealing pipe penetrations through walls and ceiling, and for sealing linear joints. The foam composition provides improved mechanical properties upon dispensing and applications.
C08J 9/32 - Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof from compositions containing microballoons, e.g. syntactic foams
C08J 9/00 - Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
C08J 9/14 - Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
48.
HEAT-CROSSLINKABLE ADHESIVE COMPOSITION FORMING A HEAT-STABLE ADHESIVE SEAL
A heat-crosslinkable adhesive composition comprises a polymer (A) comprising at least one hydrolysable alkoxysilane group, a silylated copolymer tackifying resin (B′), a non-silylated tackifying resin (C), and a crosslinking catalyst (D). The silylated copolymer tackifying resin comprises a repeating unit (B′1) derived from a silylated olefin monomer, in particular from a silylated (meth)acrylate monomer, and one or more repeating units (B′2) derived from olefin or diolefin monomers included in a petroleum fraction obtained by cracking naphtha and chosen from a C5 fraction, a C9 fraction, dicyclopentadiene. A self-adhesive article comprises a support layer coated with a self-adhesive layer consisting of the heat-crosslinkable adhesive composition in the crosslinked state.
CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (France)
UNIVERSITE DE BORDEAUX (France)
INSTITUT POLYTECHNIQUE DE BORDEAUX (France)
Inventor
Delgado, Marine
Michaud, Guillaume
Colin, Boris
Simon, Frédéric
Fouquay, Stéphane
Pucheault, Mathieu
Abstract
The present invention relates to a process for polymerizing at least one radically polymerizable compound comprising at least one ethylenic bond, in the presence of a borane BH3-amine complex and an alkene.
The present invention relates to a composition comprising: an -NCO component comprising: o A) at least one polyurethane having at least two NCO end groups; and o B) optionally a polyisocyanate compound having at least one polyisocyanate P comprising at least three NCO isocyanate functions; an -OH component comprising: o a polybutadiene polyol P1 having at least two hydroxyl functions, said polyol P1 having a number average molecular mass ranging from 1,000 g/mol to 15,000 g/mol; o a polyol P2 selected from among diols, triols, or mixtures thereof, said polyol P2 having a number average molar or molecular mass ranging from 60 to 500 g/mol; o a polyol P3 having a hydroxyl functionality greater than or equal to 2, said polyol P3 being selected from the group consisting of polyether polyols, polyols of natural origin, polyester polyols, and mixtures thereof, said polyol P3 having a number-average molecular mass ranging from 800 to 5,000 g/mol; and o at least one filler, the total content of filler(s) being greater than or equal to 30% by weight relative to the total weight of said -OH component.
The present invention relates to hot melt adhesive composition comprising: a) from 22% to 60% by weight of at least one styrene block copolymer (A) (designated as "SBC (A)") comprising:. at least one linear styrene block copolymer (A1); and. optionally at least one styrene diblock copolymer (A2); said styrene block copolymer (A) having: - a styrene content higher than or equal to 38% by weight based on the total weight of SBC (A); and - a diblock content ranging from 0% to 10% by weight based on the total weight of SBC(A); b) from 0.1% to 5% by weight of at least one wax having a congealing point higher than or equal to 60°C and a needle penetration at 25°C lower than or equal to 2 dmm; wherein the hot melt adhesive composition has a viscosity at 120°C higher than or equal to 30 000 mPa.s, and a viscosity at 177°C lower than or equal to 5 000 mPa.s.
C09J 153/00 - Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
A61F 13/00 - Bandages or dressings; Absorbent pads
52.
AQUEOUS COATING COMPOSITIONS, USES THEREOF AND PROCESSES FOR PREPARING THE SAME
Disclosed herein is an aqueous coating composition comprising a mixture of an aqueous polyurethane dispersion (A) and a thickener (C), wherein the thickener (C) comprises at least one water-in-oil inverted emulsion. Also disclosed is a process for preparing the aqueous coating composition, a coating film formed by the aqueous coating composition, and uses of the aqueous coating composition in preparation of or as coatings, adhesives, sealants, inks, paints and building products.
C09D 11/106 - Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
C09D 11/102 - Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
53.
(METH)ACRYLATE-BASED TWO-COMPONENT ADHESIVE FORMULATION FOR ASSEMBLING WIND TURBINE BLADES
The invention relates to a two-component adhesive formulation comprising: - a composition (A) comprising: ▪ from 70% to 99.98% by weight of a (meth)acrylic liquid syrup comprising: a) a (meth)acrylic polymer, b) a (meth)acrylic monomer, said (meth)acrylic liquid syrup having a dynamic viscosity ranging from 10 mPa*s to 10 000 mPa*s, ▪ from 0.01% to 12% by weight of at least one urethane-methacrylate oligomer having a functionality greater than or equal to 2, ▪ at least one activator, a composition (B) comprising a radical initiator, said initiator forming, on contact with said activator, a system capable of initiating the polymerization of the (meth)acrylic monomer of composition (A).
C08F 265/06 - Polymerisation of acrylate or methacrylate esters on to polymers thereof
C09J 4/06 - Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups
The invention concerns a hot melt adhesive composition comprising: i) a first metallocene-catalyzed propylene-based copolymer; ii) a second metallocene-catalyzed propylene-based copolymer; iii) a polyolefin copolymer selected from the group consisting of: iii-1) acid-grafted polyolefin copolymer; iii-2) a copolymer based on olefins and unsaturated monomers containing acid groups or anhydride groups; and iii-3) mixtures thereof; iv) a tackifier; v) optionally a third metallocene-catalyzed propylene-based copolymer; wherein each of the metallocene-catalyzed propylene-based copolymers i) and ii) comprises, independently of each other, from 1% to 20% by weight of ethylene units.
C08L 51/06 - Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (France)
UNIVERSITE DE HAUTE-ALSACE (France)
Inventor
Mazajczyk, Jerome
Fouquay, Stephane
Simon, Frederic
Barrat, Alexis
Lalevee, Jacques
Abstract
The present invention relates to a cross-linkable two-component composition comprising: a component A comprising: a compound having one of the following formulae (Ia) or (Ib): and at least one (meth)acrylate monomer M1; a component B comprising at least one amine compound selected from the polyamines, dihydropyridine compounds, and mixtures thereof.
16 - Paper, cardboard and goods made from these materials
Goods & Services
Adhesives for stationery or household purposes / adhesive
materials for stationery or household purposes; adhesives
for do-it-yourself; adhesives [glue] for craft; binder or
adhesive in the nature of a permanently stable mouldable
compound for temporary fixing for use in homes, schools,
offices, shops and stores and for leisure activities; glue
for stationery or household purposes; gums [adhesives] for
stationery or household purposes; office requisites except
furniture; plastic materials for packing; school supplies;
sealing compounds for stationery (adhesives for stationery);
starch paste [adhesive] for stationery or household
purposes.
57.
PROCESS FOR PREPARING SILYLATED IONIC COPOLYURETHANES WITH IMPROVED ELASTICITY
A process for preparing ionic silylated copolyurethanes comprising two ureido-alkylene-alkoxysilane end groups, comprises: (i) forming a composition of copolyurethanes having—NCO end groups by carrying out a polyaddition reaction between a polyisocyanate, a carboxylic diol and a polyol composition comprising a polyol having an Mn of greater than or equal to 2500 g/mol and a polyol having an Mn of less than 2500 g/mol; (ii) neutralizing the formed product with a tertiary amine; and (iii) reacting with an aminosilane derived from a secondary amine. A composition of ionic silylated copolyurethanes comprising two ureido-alkylene-alkoxysilane end groups, said composition being able to be obtained by means of the process. A crosslinkable adhesive and/or sealant composition comprising the composition and a filler.
CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (France)
UNIVERSITE DE BORDEAUX (France)
INSTITUT POLYTECHNIQUE DE BORDEAUX (France)
Inventor
Colin, Boris
Simon, Frédéric
Fouquay, Stéphane
Michaud, Guillaume
Pucheault, Mathieu
Chabaud, Laurent
Abstract
The invention relates to an adhesive composition comprising at least one silylated polymer (A) comprising at least one, preferably at least two, groups of formula (I): -Si(R4)P(OR5)3-P where: each R4 independently represents a linear or branched alkyl radical comprising from 1 to 4 carbon atoms; each R5 independently represents a linear or branched alkyl radical comprising from 1 to 10 carbon atoms and optionally comprising one or more heteroatoms selected from oxygen and nitrogen, or two OR5 groups participate in the same ring comprising from 2 to 8 carbon atoms; p is an integer equal to 0, 1 or 2; and at least one catalyst (B) of formula (V): B(OH)R'R" where: R' represents a substituted or unsubstituted aryl group; and R'' is selected from an OH group and a substituted or unsubstituted aryl group. The invention also relates to the use of said composition as an adhesive or as a coating, to an article comprising at least one layer obtained by crosslinking said composition, and to a method for preparing said article. Finally, the invention relates to the use of the compound of formula (V) for catalysing the crosslinking of a silylated polymer (A) of formula (I).
C08G 65/336 - Polymers modified by chemical after-treatment with organic compounds containing silicon
C09J 171/00 - Adhesives based on polyethers obtained by reactions forming an ether link in the main chain; Adhesives based on derivatives of such polymers
C08G 18/28 - Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
01 - Chemical and biological materials for industrial, scientific and agricultural use
16 - Paper, cardboard and goods made from these materials
17 - Rubber and plastic; packing and insulating materials
Goods & Services
Industrial chemicals; adhesives and glues for use in industry; adhesive preparations, materials and coatings; solvents; artificial or synthetic acrylic resins, unprocessed or in any shape or form. Adhesives and glues for stationery or household purposes. Acrylic resins (semi-finished products); synthetic resins (semi-finished products); packing, stopping and insulating materials; sealant compounds for joints, insulating plaster.
01 - Chemical and biological materials for industrial, scientific and agricultural use
17 - Rubber and plastic; packing and insulating materials
19 - Non-metallic building materials
Goods & Services
Industrial chemicals; chemicals for use in the manufacture of adhesives; Adhesives for use in industry; adhesives for ceiling coverings, for floor coverings, for wall coverings; Industrial adhesives for the repair and assembly of objects; Adhesives for wallpaper; Chemical preparations in the nature of chemical de-bonding agents for separating and unsticking for the hobby, craft and plastic modeling industry, the construction industry, and for the developing and manufacturing of packaging; primers, namely, adhesive primers for use in roofing; Solvents for manufacturing adhesives; unprocessed synthetic, acrylic and epoxy resins; Unprocessed plastics Synthetic resins as semi-finished products in form of pellets, rods, foils, foams, fibers, films and sheets; acrylic resins as semi-finished products in form of pellets, rods, foils, foams, fibers, films and sheets; epoxy resins as semi-finished products in form of pellets, rods, foils, foams, fibers, films and sheets; Packing and insulating materials; Stopping materials, namely, caulking; Sealant compounds for joints; Insulating plaster; Insulating varnish; Adhesive tapes and adhesive tape strips other than for medical, stationery or household use; Waterproof packings for industrial use and for building construction; Building materials in the nature of coatings, namely, silicone sealants for use on roofs, walls and pavements; Building materials in the nature of coatings, namely, rubber-based sealants for use on roofs, walls and pavements; Building materials in the nature of coatings, namely, resin-based sealants for use on roofs, walls and pavements; Building materials in the nature of coatings, namely, grout sealants for use on roofs, walls and pavements; Building materials in the nature of coatings, namely, polymer sealants for use on roofs, walls and pavements; Building materials in the nature of coatings, namely, adhesive sealants for use on roofs, walls and pavements; Building materials in the nature of coatings, namely, acrylic-based sealants for use on roofs, walls and pavements Building materials, not of metal, namely, grout; Mortar for building; Cement; Building materials in the nature of coatings, namely, bitumen-based roofing sealants; Building materials in the nature of coatings, namely, bitumen-based pavement sealants; Building materials in the nature of coatings, namely, bitumen-based wall sealants; Building materials in the nature of coatings, namely, asphalt-based roofing sealants; Building materials in the nature of coatings, namely, asphalt-based pavement sealants; Building materials in the nature of coatings, namely, asphalt based wall sealants; Building materials in the nature of coatings, namely, tar-based roofing sealants; Building materials in the nature of coatings, namely, tar-based pavement sealants; Building materials in the nature of coatings, namely, tar-based wall sealants; Building materials in the nature of coatings, namely, clay-based roofing sealants; Building materials in the nature of coatings, namely, clay-based pavement sealants; Building materials in the nature of coatings, namely, clay-based wall sealants; Plaster; Pitch; Concrete; Lime building materials; filling and smoothing compounds for walls, floors and ceilings, namely, cement, mortar and grout; patching products for walls, floors and ceilings, namely, spackling compound; patching products for walls, floors and ceilings, namely, filling cement
The invention relates to a hot-melt adhesive composition comprising: (i) at least one specific semi-crystalline aliphatic copolyamide; (ii) at least one filler, the carbon atom content of which is between 60 and 100% relative to the number of atoms constituting the filler, the carbonaceous filler having a median particle size D90 ranging from 1 to 400 micrometers; (iii) at least one electrically insulative filler selected from the metal oxides and nitrides, the sum of the contents of the carbonaceous filler and the electrically insulative filler is between 30 and 75% by weight relative to the total weight of the composition, said fillers having a median particle size D90 ranging from 1 to 400 micrometers The invention also relates to the method for preparing same and to the use thereof.
The invention relates to a hot-melt adhesive composition comprising: (i) at least one specific aliphatic semi-crystalline copolyamide containing a Y unit having a Tg lower than 30° C; (ii) from 3 to 35% by weight, relative to the total weight of the composition, of at least one thermally conductive filler, the carbon atom content of which is between 80 and 100% relative to the number of atoms constituting the filler; and wherein less than 20% of the components of the composition have a density greater than 3. The invention also relates to the method for preparing same and to the use thereof.
01 - Chemical and biological materials for industrial, scientific and agricultural use
03 - Cosmetics and toiletries; cleaning, bleaching, polishing and abrasive preparations
16 - Paper, cardboard and goods made from these materials
17 - Rubber and plastic; packing and insulating materials
19 - Non-metallic building materials
35 - Advertising and business services
42 - Scientific, technological and industrial services, research and design
Goods & Services
Industrial chemicals; Chemical products for the manufacture of adhesives; Adhesives for use in industry; Adhesives for ceiling coverings, floor coverings and wall coverings; Glues for repairing and assembling articles For use in the construction industry; Adhesives for paperhanging; Separating and unsticking [ungluing] preparations; Dressing and finishing preparations for textiles; Solvents (chemicals for use in industry) for adhesives; Unprocessed artificial, acrylic and epoxy resins; Unprocessed plastics. Adhesive removers. Adhesives for stationery or household purposes; Adhesives for do-it-yourself purposes; Glue for household purposes; wood glue for household use; Glues for household fabric; Adhesives for glass, for household purposes; Adhesives for leather, for household purposes; office glues; Paintbrushes; Artists' materials. Artificial, acrylic and epoxy resins (semi-finished products); Packing, stopping and insulating materials; Sealant compounds for joints; Insulating plaster; Insulating varnish; adhesive tapes and bands, other than for medicine, stationery or household purposes; Waterproof packings. Building materials, not of metal; Mortar for building; Cement; Coatings [building materials]; Plaster; Pitch; Concrete; Lime; Coatings being construction materials for patching and smoothing walls, floors and ceilings; Resurfacing preparations for walls, floors and ceilings. Promotion services; Arranging and conducting of commercial events; business administration and organisation; Business auditing in relation to the following fields: Ecological transition, and Environmental issues, Social issues and Ethical issues, Market studies in relation to the following fields: Ecological transition, and Environmental issues, Social issues and Ethical issues; Business efficiency expert services, in relation to the following fields: Ecological transition, Environmental issues, Social issues and Ethical issues. Environmental hazard assessment; Quality assessment; Working on and evaluation of chemical analyses; Research in the field of environmental protection; Providing technological information about environmentally-conscious and green innovations; Environmental surveys; Environmental hazard assessment.
64.
ADHESIVE COMPOSITIONS, LAYERED ARTICLES AND PHOTOVOLTAIC SHEETS
An adhesive composition which comprises a resin component (A) comprising a polyester polyol, a hydrogenated epoxy, a silane, and an optional organic solvent; and a hardener component (B) comprising an aliphatic polyisocyanate and/or an alicyclic polyisocyanate; the adhesive composition being substantially free of aromatic rings. The polyester polyol is prepared by reacting a polybasic acid and a polyalcohol, and the polybasic acid comprises an aliphatic polybasic acid and/or an alicyclic polybasic acid. The polyester polyol has a glass transition temperature (Tg) in a range of from 0°C to 10°C. The adhesive composition of the present invention has strong adhesion, excellent weather-resistance and yellowing-resistance.
C08G 18/28 - Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
16 - Paper, cardboard and goods made from these materials
Goods & Services
Adhesives in the nature of glue for stationery or household purposes, glue for stationery or household purposes; Adhesives for do-it-yourself purposes; Adhesives in the nature of glue for handicrafts; Binding adhesive materials in the form of permanently moldable compound being modeling clay for temporary fixing purposes for use in households, schools, offices, shops and stores and for leisure activities; Glue for stationery or household purposes; Gums in the nature of glues for stationery or household purposes; Office requisites except furniture, namely reusable adhesive modeling clay, glue sticks, PVA white glue, all-purpose glue, glitter glue; Plastic film for use as packaging material for stationery and household use; school supplies, namely reusable adhesive modeling clay, glue sticks, PVA white glue, all-purpose glue, glitter glue; Compounds for sealing purposes, namely, adhesives for stationery; Starch paste adhesives for stationery or household purposes
16 - Paper, cardboard and goods made from these materials
Goods & Services
(1) Adhésifs [matières collantes] pour la papeterie ou le ménage / matières collantes pour la papeterie ou le ménage; adhésifs pour le bricolage; adhésifs [colle] pour l'artisanat; liant ou adhésif sous la forme d'un composé moulable de façon permanente à des fins de fixation temporaire à utiliser dans les maisons, les écoles, les bureaux, les boutiques et les magasins et pour les activités de loisirs; colles pour la papeterie ou le ménage; gommes [colles] pour la papeterie ou le ménage; articles de bureau à l'exception des meubles; matières en plastiques pour l'emballage; fournitures scolaires; composés de scellement pour la papeterie (adhésifs pour la papeterie); colle d'amidon pour la papeterie ou le ménage.
The present invention relates to a moisture-crosslinkable sealant composition comprising:
at least one polyurethane P comprising at least two NCO end functions;
at least one polyimine A obtained via a process comprising a step of reaction between at least:
a) a (poly)urethane-aldehyde comprising at least 2 aldehyde functions;
b) a primary diamine;
c) optionally in the presence of a primary monoamine or a monoaldehyde if the —CHO/NH2 molar ratio is other than 1.
C08G 18/12 - Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
The present invention relates to compounds having one of the following formulae (I) and (II):
The present invention relates to compounds having one of the following formulae (I) and (II):
The present invention relates to compounds having one of the following formulae (I) and (II):
The present invention relates to compounds having one of the following formulae (I) and (II):
and also to the uses thereof.
C08G 18/12 - Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
C08G 18/76 - Polyisocyanates or polyisothiocyanates cyclic aromatic
C08G 18/72 - Polyisocyanates or polyisothiocyanates
C08G 18/75 - Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
C08G 18/24 - Catalysts containing metal compounds of tin
CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (France)
Inventor
Michaud, Guillaume
Simon, Frédéric
Fouquay, Stéphane
Lalevee, Jacques
Abstract
The present invention relates to a two-component composition comprising: —a composition A comprising: —at least one reducing agent; —at least one (meth)acrylate monomer; —a composition B comprising: —at least one oxidising agent; and—optionally at least one (meth)acrylate monomer; the composition being characterised in that: —it comprises at least one radical photoinitiator in composition A and/or B; —it comprises at least one polymerisation inhibitor in an amount less than or equal to 0.3% by weight relative to the total weight of the composition.
C09J 4/06 - Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups
C09J 133/14 - Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
The invention relates to a hot-melt adhesive composition, comprising at least one polyolefin polymer at a content from 5 to 90% by weight; at least one branched polypropylene at a content from 0.1 to 10% by weight; at least one tackifying resin at a content from 0.1 to 60% by weight; optionally, at least one styrene block copolymer from 0 to 30% by weight; optionally, at least one plasticizer at a content from 0 to 30% by weight; optionally, at least one stabilizer at a content from 0 to 5% by weight; and optionally, at least one wax at a content from 0 to 30% by weight. The invention further relates to the use of a branched polypropylene for reducing stringing of a hot-melt adhesive composition.
The present invention relates to a polyamide composition comprising a polyamide which is the polycondensation product of an acid component and an amine component, the acid component comprising, per mole of acid component: - 30 to 50 mol.% of fatty acid dimer(s); - 30 to 50 mol.% of aliphatic dibasic acid(s); - 0 to 10 mol.% of chain limiter(s); the amine component comprising, per mole of amine component: - 10 to 40 mol.% of cycloaliphatic diamine(s); and - 50 to 80 mol.% of aliphatic diamine(s) comprising 3 to 12 carbon atoms; - 0 to 15 mol.% of polyetheramine(s); said polyamide composition having: - a viscosity less than or equal to 4 Pa.s at 185°C; and - a softening temperature ranging from 150°C to 170°C.
C08G 69/26 - Polyamides derived from amino carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
C08G 69/34 - Polyamides derived from amino carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids using polymerised unsaturated fatty acids
C08L 77/08 - Polyamides derived from polyamines and polycarboxylic acids from polyamines and polymerised unsaturated fatty acids
C09J 177/08 - Polyamides derived from polyamines and polycarboxylic acids from polyamines and polymerised unsaturated fatty acids
CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (France)
Inventor
Mazajczyk, Jérôme
Fouquay, Stéphane
Simon, Frédéric
Michaud, Guillaume
Barrat, Alexis
Lalevee, Jacques
Abstract
The present invention relates to a crosslinkable two-component composition comprising: - a component A comprising: - an iodonium salt having one of the formulae (I-A), (I-B) or (I-C); - at least one (meth)acrylate monomer M1 having one of the formulae (II), (III) or (IV), - an organic or mineral acid having a pKa or pka1 ranging from 0.3 to 5 measured in water at 25°C; - a copper salt or a copper complex; - a component B containing at least one dihydropyridine compound having one of the formulae (VI) to (X), wherein said composition does not contain peroxide.
CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (France)
Inventor
Mazajczyk, Jérôme
Fouquay, Stéphane
Simon, Frédéric
Michaud, Guillaume
Barrat, Alexis
Lalevee, Jacques
Abstract
The present invention relates to a crosslinkable two-component composition comprising: - a component A comprising: - an iodonium salt having one of the formulae (I-A), (I-B) or (I-C); - at least one (meth)acrylate monomer M1, - an organic or mineral acid having a pKa or pka1 ranging from 0.3 to 5 measured in water at 25°C; - at least one photoinitiator P1; - a component B containing at least one dihydropyridine compound having one of the formulae (III) to (VI), wherein said composition does not contain peroxide.
The present invention relates to a moisture-crosslinkable composition comprising:
at least one polymer (A) comprising at least one alkoxysilane group;
at least 25% by weight of at least one carbonate filler (B) relative to the total weight of said composition;
at least one compound chosen from bis(alkoxysilane)s or tri(alkoxysilane)s (C) having a molar mass ranging from 250 to 1000 g/mol;
at least one crosslinking catalyst (D);
said composition being characterized in that it comprises a plasticizer content of less than or equal to 1% by weight relative to the total weight of the composition.
The invention relates to 1) a crosslinkable adhesive composition comprising: at least one polymer (A) comprising a hydrolysable alkoxysilane group; at least one tackifying resin (B); at least one fumed silica (C), preferably hydrophic; at least one crosslinking catalyst (D); and a silsesquioxane resin. The invention also relates to 2) a self-adhesive article comprising a support layer coated with a self-adhesive layer consisting of the adhesive composition in the crosslinked state. The invention further relates to 3) a method for producing the article, comprising crosslinking the composition by heating at a temperature ranging from 15°C to 200°C, and a bonding method using the self-adhesive article.
C09J 201/10 - Adhesives based on unspecified macromolecular compounds characterised by the presence of specified groups containing hydrolysable silane groups
The invention relates to: (1) A cross-linkable adhesive composition comprising: - at least one polymer (A) comprising a hydrolysable alkoxysilane group; - at least one tackifying resin (B); - at least one fumed silica (C), preferably hydrophobic; - at least one cross-linking catalyst (D); and - a silsesquioxane resin (E). (2) The use of said composition for semi-structural joining of two substrates. (3) A method for joining two substrates, which comprises: - melting said composition by heating to a temperature of from 30 to 130°C, then - depositing said composition on a surface of a first substrate, and then - cross-linking said composition by heating to a temperature of from 15 to 200°C and placing said surface in contact with a surface of a second substrate.
C09J 201/10 - Adhesives based on unspecified macromolecular compounds characterised by the presence of specified groups containing hydrolysable silane groups
C09J 7/25 - Plastics; Metallised plastics based on macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
C09J 143/04 - Homopolymers or copolymers of monomers containing silicon
C08K 5/549 - Silicon-containing compounds containing silicon in a ring
77.
POLY (3 -HYDROXYACID) POLYMERS FROM LONG-CHAIN EPOXIDES AND THEIR USES RELATED TO HOT MELT ADHESIVES
11 is an alkyl group having at least 8 carbon atoms. The macromolecule may be hydroxy-terminated, and may be copolymerized with other β-lactone monomers having different substituting groups and/or with higher lactone monomers. The macromolecule may be used as a reactant to form an alkoxysilane-terminated polymer, a polyurethane, or a (co)polyester, or may be used as an elastomeric midblock in a triblock copolymer having hard end blocks, such as polylactic acid. Such triblock systems demonstrate two discreet regions having properties similar to styrene block copolymers and are therefore suitable for use as hot melt or pressure-sensitive adhesives. In some embodiments, such triblock polymers may be entirely bio-sourced and compostable.
A composition comprises a (co)polyester resin having a heat of fusion of 0.1 to 8 J/g and a glass transition temperature between about 50°C and 100°C and an antifog agent, wherein the composition has a heat of fusion of greater than the heat of fusion of the (co)polyester resin and a glass transition temperature less than the glass transition temperature of the (co)polyester resin. The composition may be used as a heat seal layer as part of a laminate for a container, such as an amorphous polyester tray and, when used with a pressure sensitive adhesive layer, may have the ability to reseal the container. The composition may also be used as a heat seal layer of a laminate for use used as a bag or pouch. The composition may be compliant for food contact.
B32B 27/08 - Layered products essentially comprising synthetic resin as the main or only constituent of a layer next to another layer of a specific substance of synthetic resin of a different kind
C09D 167/02 - Polyesters derived from dicarboxylic acids and dihydroxy compounds
79.
POLY (3-HYDROXYACID) POLYMERS FROM LONG-CHAIN EPOXIDES AND THEIR USES RELATED TO HOT MELT ADHESIVES
A macromolecule comprises a ring-opened polymerized product of ?-lactone monomers of formula I: and having a structure of formula IA: wherein R1 is an alkyl group having at least 8 carbon atoms. The macromolecule may be hydroxy-terminated, and may be copolymerized with other ?-lactone monomers having different substituting groups and/or with higher lactone monomers. The macromolecule may be used as a reactant to form an alkoxysilane-terminated polymer, a polyurethane, or a (co)polyester, or may be used as an elastomeric midblock in a triblock copolymer having hard end blocks, such as polylactic acid. Such triblock systems demonstrate two discreet regions having properties similar to styrene block copolymers and are therefore suitable for use as hot melt or pressure-sensitive adhesives. In some embodiments, such triblock polymers may be entirely bio-sourced and compostable.
A macromolecule comprises a ring-opened polymerized product of β-lactone monomers of formula I:
A macromolecule comprises a ring-opened polymerized product of β-lactone monomers of formula I:
and having a structure of formula IA:
A macromolecule comprises a ring-opened polymerized product of β-lactone monomers of formula I:
and having a structure of formula IA:
wherein R1 is an alkyl group having at least 8 carbon atoms. The macromolecule may be hydroxy-terminated, and may be copolymerized with other β-lactone monomers having different substituting groups and/or with higher lactone monomers. The macromolecule may be used as a reactant to form an alkoxysilane-terminated polymer, a polyurethane, or a (co)polyester, or may be used as an elastomeric midblock in a triblock copolymer having hard end blocks, such as polylactic acid. Such triblock systems demonstrate two discreet regions having properties similar to styrene block copolymers and are therefore suitable for use as hot melt or pressure-sensitive adhesives. In some embodiments, such triblock polymers may be entirely bio-sourced and compostable.
A composition comprises a (co)polyester resin having a heat of fusion of 0.1 to 8 J/g and a glass transition temperature between about 50°C and 100°C and an antifog agent, wherein the composition has a heat of fusion of greater than the heat of fusion of the (co)polyester resin and a glass transition temperature less than the glass transition temperature of the (co)polyester resin. The composition may be used as a heat seal layer as part of a laminate for a container, such as an amorphous polyester tray and, when used with a pressure sensitive adhesive layer, may have the ability to reseal the container. The composition may also be used as a heat seal layer of a laminate for use used as a bag or pouch. The composition may be compliant for food contact.
B32B 27/08 - Layered products essentially comprising synthetic resin as the main or only constituent of a layer next to another layer of a specific substance of synthetic resin of a different kind
C09D 167/02 - Polyesters derived from dicarboxylic acids and dihydroxy compounds
82.
USE OF A BLANK SHIM PLATE FOR PREVENTING DROOLING IN DIE SLOT COATING
A slot coating die for applying a fluid composition on a substrate, comprising:
an upstream die part having a lower edge;
a downstream die part having a lower edge, the downstream die part facing the upstream die part and spaced apart from the upstream die part, and the lower edge of the upstream die part being vertically aligned with the lower edge of the downstream die part;
a patterned shim plate between the upstream die part and the downstream die part, the patterned shim plate having a lower edge, wherein the lower edge comprises at least one cut-out; and
a blank shim plate having a lower edge being devoid of cut-out, the blank shim plate being located between the downstream die part and the patterned shim plate; wherein at least one of the upstream die part and the downstream die part comprises at least one fluid inlet.
B05C 5/02 - Apparatus in which liquid or other fluent material is projected, poured or allowed to flow on to the surface of the work from an outlet device in contact, or almost in contact, with the work
B05D 1/26 - Processes for applying liquids or other fluent materials performed by applying the liquid or other fluent material from an outlet device in contact with, or almost in contact with, the surface
The present invention relates to a hot-melt self-adhesive composition comprising: - i) from 5% to 60% by weight of a mixture M1 of styrenic block copolymers, said mixture, based on its total weight, consisting of: - from 30% to 70% by weight of Styrene-Isoprene (SI) diblock copolymers and - from 30% to 70% by weight of Styrene-Isoprene-Styrene (SIS) linear triblock copolymers, the total amount of styrenic units in said mixture M1 being less than 25% and strictly more than 0%, based on the total weight of the mixture M1, and - ii) from 20% to 70% by weight of a mixture M2 of styrenic block copolymers, said mixture, based on its total weight, consisting of: - from 1% to 30% by weight of Styrene-Isoprene (SI) diblock copolymers and - from 70% to 99% by weight of Styrene-Isoprene-Styrene (SIS) linear triblock copolymers, the total amount of styrenic units in said mixture M2 being strictly more than 25%, based on the total weight of the mixture M2, and - iii) at least one non-hydrogenated tackifying resin obtained by polymerization or copolymerization (with an aromatic hydrocarbon) of mixtures of unsaturated aliphatic hydrocarbons having around 5 carbon atoms that are obtained from petroleum fractions.
C09J 153/02 - Vinyl aromatic monomers and conjugated dienes
B32B 7/12 - Interconnection of layers using interposed adhesives or interposed materials with bonding properties
B32B 27/08 - Layered products essentially comprising synthetic resin as the main or only constituent of a layer next to another layer of a specific substance of synthetic resin of a different kind
The present invention relates to a hot melt adhesive composition having an enthalpy of crystallization below 5 J/g and comprising: a) at least 60% by weight of a composition a) comprising: —at least one copolymer A having a needle penetration higher than 15 dmm; —at least (co)polymer B having a needle penetration lower than 15 dmm; b) from 0% to 30% by weight of at least one tackifying resin.
C09J 123/22 - Copolymers of isobutene; Butyl rubber
C09J 5/06 - Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers involving heating of the applied adhesive
B32B 7/12 - Interconnection of layers using interposed adhesives or interposed materials with bonding properties
87.
IONIC SILYLATED COPOLYURETHANE AND MASTIC COMPOSITION COMPRISING SAME
1) Ionic silylated copolyurethane of formula:
1) Ionic silylated copolyurethane of formula:
1) Ionic silylated copolyurethane of formula:
in which R1 is a hydrocarbon radical; R2 is a C2-C4 alkylene; n is an integer such that the molecular mass of —[OR2]n is 2500-20 000 g/mol; R∘ is H or C1-C18 alkyl; R, R′ and R″ are a hydrocarbon-based radical; x and y are integers from 1 à 8; z is an integer from 0 to 8; m and q are an integer of greater than or equal to 1, such that q/m ranges from 0.04 to 20; F1 is a radical of formula (IIa) and F2 is a radical of formula (IIb):
1) Ionic silylated copolyurethane of formula:
in which R1 is a hydrocarbon radical; R2 is a C2-C4 alkylene; n is an integer such that the molecular mass of —[OR2]n is 2500-20 000 g/mol; R∘ is H or C1-C18 alkyl; R, R′ and R″ are a hydrocarbon-based radical; x and y are integers from 1 à 8; z is an integer from 0 to 8; m and q are an integer of greater than or equal to 1, such that q/m ranges from 0.04 to 20; F1 is a radical of formula (IIa) and F2 is a radical of formula (IIb):
in which R3 is methylene or n-propylene; R4 and R5 are methyl or ethyl; p is equal to 0 or 1; R6 is a C1-C4 alkyl.
1) Ionic silylated copolyurethane of formula:
in which R1 is a hydrocarbon radical; R2 is a C2-C4 alkylene; n is an integer such that the molecular mass of —[OR2]n is 2500-20 000 g/mol; R∘ is H or C1-C18 alkyl; R, R′ and R″ are a hydrocarbon-based radical; x and y are integers from 1 à 8; z is an integer from 0 to 8; m and q are an integer of greater than or equal to 1, such that q/m ranges from 0.04 to 20; F1 is a radical of formula (IIa) and F2 is a radical of formula (IIb):
in which R3 is methylene or n-propylene; R4 and R5 are methyl or ethyl; p is equal to 0 or 1; R6 is a C1-C4 alkyl.
2) Process for preparing copolyurethane 1), comprising:
(i) polyaddition between a polyisocyanate, a polyether diol and a carboxylic diol;
(ii) neutralization of the product formed with the amine N(R)(R′)(R″); then
(iii) reaction with an aminosilane derived from a secondary amine.
1) Ionic silylated copolyurethane of formula:
in which R1 is a hydrocarbon radical; R2 is a C2-C4 alkylene; n is an integer such that the molecular mass of —[OR2]n is 2500-20 000 g/mol; R∘ is H or C1-C18 alkyl; R, R′ and R″ are a hydrocarbon-based radical; x and y are integers from 1 à 8; z is an integer from 0 to 8; m and q are an integer of greater than or equal to 1, such that q/m ranges from 0.04 to 20; F1 is a radical of formula (IIa) and F2 is a radical of formula (IIb):
in which R3 is methylene or n-propylene; R4 and R5 are methyl or ethyl; p is equal to 0 or 1; R6 is a C1-C4 alkyl.
2) Process for preparing copolyurethane 1), comprising:
(i) polyaddition between a polyisocyanate, a polyether diol and a carboxylic diol;
(ii) neutralization of the product formed with the amine N(R)(R′)(R″); then
(iii) reaction with an aminosilane derived from a secondary amine.
3) Composition, usable as sealant and/or adhesive, comprising copolyurethane 1) and a filler.
C08G 18/28 - Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
C08G 18/34 - Carboxylic acids; Esters thereof with monohydroxyl compounds
Water-based adhesive composition comprising, on the basis of its total weight: - from 10 % to 45 % by weight (expressed as dry content) of an acrylic emulsion (A), the acrylic emulsion (A) being an aqueous dispersion exempt from polychloroprene; and - from 0.009 % to 0.60 % by weight (expressed as dry content) of a water soluble polymer (B) comprising a xanthan gum; said composition being obtainable by a process (P) comprising a first step (i) of dissolving polymer (B) into water, in the form of a powdered solid. Use of said composition for the bonding of two substrates including at least one porous substrate.
The invention relates to a slot coating die for applying a fluid composition on a substrate, comprising: an upstream die part (1) having a first face (5); a downstream die part (2) having a second face (7), the first face (5) of the upstream die part (1) facing and being parallel to the second face (7) of the downstream die part (2); wherein at least one of the upstream die part (1) and the downstream die part (2) comprises at least one fluid inlet (12) configured for making the fluid composition flow between the upstream die part (1) and the downstream die part (2), and wherein at least one of the upstream die part (1) and the downstream die part (2) comprises at least one horizontal channel (13) on the first face (5) or second face (6), wherein the horizontal channel (13) is at least partially blocked so that the fluid composition is prevented from flowing through at least part of the horizontal channel (13). The invention further relates to a method for applying a fluid composition on a substrate by using said slot coating die and the use of said slot coating die to reduce or prevent ghosting during a slot die coating process. The invention further relates to a method of restructuring an initial slot coating die for applying a fluid composition on a substrate.
B05C 5/02 - Apparatus in which liquid or other fluent material is projected, poured or allowed to flow on to the surface of the work from an outlet device in contact, or almost in contact, with the work
The present invention relates to a two-component crosslinkable composition comprising: - a component A comprising: - a reducing agent; - a metal salt selected from the group consisting of (meth)acrylic acid metal salts, itaconic acid metal salts, and mixtures thereof; - at least one (meth)acrylate monomer M1; - a component B comprising an oxidizing agent; said composition being characterized in that it comprises at least one radical photoinitiator in component A and/or B. The invention also relates to the uses of said composition.
The present invention relates to a crosslinkable two-component composition comprising: ‐ a component A comprising: - a (meth)acrylate monomer, - a reducing agent, - a zinc salt selected from among zinc alkane sulfonates, zinc acetate, and mixtures thereof, ‐ a component B comprising an oxidizing agent; and to uses thereof.
C09D 4/00 - Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond
C09J 4/00 - Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond
1) A sealant composition comprising:
from 3% to 80% of a polymer (A) comprising an alkoxysilane group,
at least 25% of a carbonate filler (B), and
from 0.5% to 20% of a polysiloxane resin (C) comprising, as groups directly linked to the silicon atom:
at least one phenyl group; and
at least one group chosen from a hydroxyl and an aminoalkylene group; and
from 0.1% to 1% of a crosslinking catalyst (D);
1) A sealant composition comprising:
from 3% to 80% of a polymer (A) comprising an alkoxysilane group,
at least 25% of a carbonate filler (B), and
from 0.5% to 20% of a polysiloxane resin (C) comprising, as groups directly linked to the silicon atom:
at least one phenyl group; and
at least one group chosen from a hydroxyl and an aminoalkylene group; and
from 0.1% to 1% of a crosslinking catalyst (D);
said percentages being expressed by weight on the basis of the total weight of said composition.
1) A sealant composition comprising:
from 3% to 80% of a polymer (A) comprising an alkoxysilane group,
at least 25% of a carbonate filler (B), and
from 0.5% to 20% of a polysiloxane resin (C) comprising, as groups directly linked to the silicon atom:
at least one phenyl group; and
at least one group chosen from a hydroxyl and an aminoalkylene group; and
from 0.1% to 1% of a crosslinking catalyst (D);
said percentages being expressed by weight on the basis of the total weight of said composition.
2) The use of said composition as adhesive, sealant or coating.
The present invention relates to a two-part curable composition comprising: • a first part (component A) comprising : • at least 50% by weight based on the total weight of the first part, of one or more alkyl cyanoacrylate monomer, said alkyl cyanoacrylate monomer comprising only one cyanoacrylate function; • one poly(2-cyanoacrylate) monomer having the following formula (I) wherein R is an organic moiety and n is an integer higher or equal to 2; • a second part (component B) comprising a (meth)acrylate component having at least two (meth)acrylate functions.
The invention relates to a hot-melt pressure sensitive adhesive composition comprising at least one styrenic block copolymer, at least one tackifying resin, at least one mineral oil and from 4 to 15% by weight of at least one wax selected from the group consisting of paraffin waxes, Fischer-Tropsch waxes, ethylene-vinyl acetate waxes and any mixture thereof, based on the total weight of the hot-melt pressure sensitive adhesive composition. The invention also relates to an article comprising a surface coated with such a hot-melt pressure sensitive adhesive composition, to a use of such a hot-melt pressure sensitive adhesive composition and to a process for preparing such a hot-melt pressure sensitive adhesive composition.
One-component heat-activatable polyurethane water-based adhesive composition, which comprises, with respect to the total weight of the adhesive composition: —from 12% to 50%, by weight of dry matter, of an aqueous dispersion of a polyurethane (A) comprising alkoxysilyl pending and/or terminal groups, and —from 0.5% to 5% by weight of a glycidoxy substituted alkoxysilane compound (B) with a glycidoxy functionality of at least 2.
A UV-crosslinkable HMPSA composition comprises 10-24% by weight of a block copolymer comprising a styrenic block and a polybutadiene block comprising at least 25% by weight of the 1,2-vinyl unit; 43-65% by weight of a tackifying resin obtained by polymerization, then complete or partial hydrogenation of a C9 fraction, having a softening point of 80-150° C.; 10-25% by weight of a petroleum-derived hydrocarbon oil; and an appropriate amount of a photoinitiator (D). A self-adhesive article comprises a carrier layer (b) coated with a self-adhesive layer (a) comprising the HMPSA composition in the crosslinked state.
CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (France)
Inventor
Mazajczyk, Jérôme
Fouquay, Stéphane
Simon, Frédéric
Michaud, Guillaume
Barrat, Alexis
Lalevee, Jacques
Abstract
The present invention relates to a crosslinkable two-component composition comprising: - a component A comprising: - a compound having the following formula (I): - at least one (meth)acrylate monomer M1 having one of formulae (II), (III) or (IV); - a component B comprising at least one compound having the following formula (V): Rc22-, Q+ (V) and the uses thereof.
The present invention concerns a two-component adhesive composition comprising an -OH component and an -NCO component and characterized in that: - the -OH component is a composition comprising at least one polyol A1; 1 - the -NCO component is a composition comprising at least one polyurethane P2 obtained by a process comprising the following steps: S1) preparing a polyurethane prepolymer P1 comprising at least two terminal -NCO functions by a polyaddition reaction: i) of at least one polyester polyol A2 having a number-average molecular mass (Mn) of from 8000 to 12 000 g/mol; ii) of at least one polyol A3 having a molar mass of not more than 200 g/mol, said polyol A3 comprising at least one secondary OH function; iii) of at least one polyisocyanate; iv) of an optional polyol A4; in amounts such that the molar ratio NCO/OH (r1) is from 1.7 to 2.2; and S2) reacting the product formed at the end of step S1) with at least one aminosilane, in amounts such that the molar ratio NCO/NH (r2) is from 10 to 25.
C08G 18/12 - Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
C08G 18/28 - Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen