An aqueous curable adhesive composition comprises an aqueous polymer dispersion and a polyamine compound having at least two amino groups. A laminated article comprises at least two substrates and the aqueous curable adhesive composition.
C09J 133/06 - Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
B32B 7/12 - Interconnection of layers using interposed adhesives or interposed materials with bonding properties
B32B 27/08 - Layered products essentially comprising synthetic resin as the main or only constituent of a layer next to another layer of a specific substance of synthetic resin of a different kind
TT is an average of >2.5 to 14; wherein the weight of ethoxylated phenol divided by the weight of nonionic branched alcohol alkoxylate surfactant contained in the aqueous hard surface cleaning formulation is 0.1 to < 5.
An aqueous antiperspirant composition is provided, comprising: (A) water; (B) a sweat repellent polymer, comprising a multistage polymer comprising: an acrylate rich stage comprising: structural units of a monoethylenically unsaturated nonionic acrylate rich stage monomer; and structural units of a first carbosiloxane monomer of formula (I); and a carbosiloxane rich stage, comprising: structural units of a vinyl monomer; and structural units of a second carbosiloxane monomer of formula (I); wherein the first carbosiloxane monomer of formula (I) and the second carbosiloxane monomer of formula (I) are the same or different; and (C) an antiperspirant aluminum salt; wherein the aqueous antiperspirant composition is an emulsion. Also provided are methods of using the same.
A61K 8/894 - Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
An aqueous composition comprising: (a) an aqueous dispersion of hybrid polymer particles with a fluorine content of 5% or more, wherein the hybrid polymer particles comprise, based on the weight of the hybrid polymer particles, (i) greater than 20% to 75% by weight of a first polymer component comprising a fluoroethylene vinyl ether copolymer, and (ii) from 25% to less than 80% by weight of a second polymer component, wherein the second polymer component is an acrylic copolymer comprising, based on the weight of the acrylic copolymer, from 0.15% to 1.2% by weight of structural units of a phosphorus-containing acid monomer, a salt thereof, or mixtures thereof, and structural units of a monoethylenically unsaturated nonionic monomer; and (b) from 5% to 30% by dry weight of colloidal silica, based on the total weight of the hybrid polymer particles and the dry weight of the colloidal silica. The aqueous composition can provide coatings with balanced dirt pick-up resistance and durability properties.
Articles useful for bedding and other comfort applications include a coated polyurethane foam. The coating includes an elastomeric polymer, a phase change material, a non-encapsulated wax and optionally a hydrophilic polymer. The coating provides desirable haptic properties, including a "cool touch" feature that creates a sensation of coolness when touched, and a highly smooth surface.
01 - Chemical and biological materials for industrial, scientific and agricultural use
Goods & Services
(1) Chemicals, namely vinyl acetate, acrylic emulsions, cellulosics, silicones, and dry acrylics for use in road applications by the transportation and construction industries.
7.
ACRYLIC DAMPING ADDITIVES FOR FILLED THERMOPLASTICS
ggg less than -10C. The weight ratio of the acrylic vibrational damping polymer to the filler is less than 1:1. A thermoplastic resin composition comprises the sound damping composition and a thermoplastic resin, where the sound damping composition is present in an amount of at least 10 wt% relative to the total weight of the thermoplastic resin composition. Articles produced from the resin composition are also disclosed.
C08K 9/08 - Ingredients agglomerated by treatment with a binding agent
E04F 15/10 - Flooring or floor layers composed of a number of similar elements of other materials, e.g. fibrous or chipped materials, organic plastics, magnesite, hardboard
E04F 15/20 - Separately-laid insulating layers; Other additional insulating measures; Floating floors for sound insulation
The present invention provides fiber cement articles, such as roof tiles having improved impact and hail resistance and methods for making them. The fiber cement articles comprise cement, an optional filler, reinforcing fibers, such as poly(vinyl alcohol) fibers or a mixture of cellulosic and synthetic fibers, one or more core-shell aqueous emulsion polymers having a crosslinked rubbery core with a calculated glass transition temperature (calculated Tg) of from −20 to −140° C., and an at least partially grafted acrylic or vinyl shell polymer having a calculated Tg of from 20 to 170° C., and having a Z-average primary particle size of from 55 to 800 nm, or, preferably, from 140 to 650 nm. The solids weight ratio of the crosslinked rubbery core to the shell of the core-shell aqueous emulsion polymer may range from 85:20 to 97:3.
C04B 20/00 - Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
An interpolymer, which comprises at least one siloxane group, and prepared by polymerizing a mixture comprising one or more “addition polymerizable monomers” and at least one siloxane monomer, in the presence of a catalyst system comprising a Group 3-10 metal complex, and the siloxane monomer is selected from the following Formula 1: Aa-Si(Bb)(Cc)(Hh0)—O—(Si(Dd)(Ee) (Hh1)—O)x—Si(Ff)(Gg)(Hh2), described herein. An ethylene/siloxane interpolymer comprising at least one chemical unit of Structure 1, or at least one chemical unit of Structure 2, each described herein. A process to form an interpolymer, which comprises, in polymerized form, at least one siloxane monomer, or at least one silane monomer without a siloxane linkage, said process comprising polymerizing a mixture comprising one or more “addition polymerizable monomers” and at least one monomer of Formula 4, described herein, in the presence of a catalyst system comprising a metal complex from Formula A or Formula B, each described herein.
C08F 230/08 - Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium, or a metal containing a metal containing silicon
A crosslinkable polyolefin formulation comprises (A) a polyethylene polymer and (B) an arylketone of formula (I) as defined herein; products made therefrom; methods of making and using same; and articles containing same.
B32B 27/20 - Layered products essentially comprising synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
H01B 3/44 - Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances waxes acrylic resins
An aqueous liquid laundry formulation is provided, comprising: a liquid carrier; a cellulase; and a protectant polymer, wherein the protectant polymer comprises: 25 to 65 wt%, based on weight of the protectant polymer, of structural units of formula I
An aqueous liquid laundry formulation is provided, comprising: a liquid carrier; a cellulase; and a protectant polymer, wherein the protectant polymer comprises: 25 to 65 wt%, based on weight of the protectant polymer, of structural units of formula I
An aqueous liquid laundry formulation is provided, comprising: a liquid carrier; a cellulase; and a protectant polymer, wherein the protectant polymer comprises: 25 to 65 wt%, based on weight of the protectant polymer, of structural units of formula I
wherein each R1 is independently selected from a hydrogen and a —CH3 group; and 35 to 75 wt%, based on weight of the protectant polymer, of structural units of formula II
An aqueous liquid laundry formulation is provided, comprising: a liquid carrier; a cellulase; and a protectant polymer, wherein the protectant polymer comprises: 25 to 65 wt%, based on weight of the protectant polymer, of structural units of formula I
wherein each R1 is independently selected from a hydrogen and a —CH3 group; and 35 to 75 wt%, based on weight of the protectant polymer, of structural units of formula II
An aqueous liquid laundry formulation is provided, comprising: a liquid carrier; a cellulase; and a protectant polymer, wherein the protectant polymer comprises: 25 to 65 wt%, based on weight of the protectant polymer, of structural units of formula I
wherein each R1 is independently selected from a hydrogen and a —CH3 group; and 35 to 75 wt%, based on weight of the protectant polymer, of structural units of formula II
wherein each R2 is independently selected from a 2-3 alkyl group and wherein each R3 is independently selected from a hydrogen and a methyl group. Also provided is a method of renewing a soiled cotton containing fabric using aqueous liquid laundry formulation.
A clear hair styling formulation is provided, comprising: a dermatologically acceptable vehicle; and a hair fixative polymer; wherein the hair fixative polymer is a hydrolyzed starch; wherein the hydrolyzed starch has a weight average molecular weight of 5,000 to 50,000 Daltons.
A61K 8/81 - Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
The present invention is a method of making 1,4,5,8-tetrakis(R-phenylamino)anthracene-9,10-dione (where R is H or a hydrocarbyl group) comprising the step of contacting 1,4,5,8-tetrachloroanthraquinone with a mixture of R-anilines comprising at least two different R groups, under conditions to produce 1,4,5,8-tetrakis(R-phenylamino)anthracene-9,10-dione. The present disclosure also provides a reaction mixture of 1,4,5,8-tetrakis(R-phenylamino)anthracene-9,10-dione characterized by having the R groups on at least 75% of the 1,4,5,8-tetrakis(R-amino)anthracene-9,10-dione molecules in the mixture be comprised of 2 or more different R groups. The present disclosure also provides a method of improving the solubility of 1,4,5,8-tetrakis(R-phenylamino)anthracene-9,10-dione in aromatic hydrocarbons distilled from crude oil, comprising selecting a mixture of 1,4,5,8-tetrakis(R-phenylamino)anthracene-9,10-diones which are characterized by having at least 75% of the 1,4,5,8-tetrakis(R-phenylamino)anthracene-9,10-dione molecules in the mixture comprise two or more different R groups. The compounds of the present invention exhibit a suitable UV visible absorbance profile making them suitable for use as a fuel marker.
A two-component solventless adhesive composition including: (A) at least one isocyanate component formulated for application to a first substrate comprising either at least one aromatic-based isocyanate, or a blend of: (Ai) at least one aromatic-based isocyanate; and (Aii) at least one aliphatic-based isocyanate; and (B) at least one isocyanate-reactive component formulated for application to a second substrate comprising a blend of: (Bi) at least one amine-initiated polyol comprising two or more primary hydroxyl groups and a backbone incorporating tertiary amines; (Bii) at least one hydroxyl terminated polyurethane polyol; (Biii) at least one phosphate ester polyol; (Biv) at least one polyester polyol; (Bv) at least one polyether polyol and (Bvi) optionally, at least one silane adhesion promoter; and a process for preparing the above two-component solventless adhesive composition; and a laminate structure made using the above two-component solventless adhesive composition.
The present invention is a composition comprising an aqueous dispersion of first and second polymer particles; and polymeric organic crosslinked microspheres; wherein, the weight-to-weight ratio of second polymer particles to first polymer particles is in the range of from 50:50 to 80:20; and wherein the weight-to-weight ratio of the microspheres to the first and second polymer particles is in the range of from 3:97 to 20:80. The composition of the present invention is useful semi-gloss or satin paint formulations with excellent mar resistance.
C08F 220/18 - Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
C08F 230/02 - Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium, or a metal containing phosphorus
16.
SILICONE-(METH)ACRYLATE COPOLYMER AND METHODS FOR ITS PREPARATION AND USE IN PERSONAL CARE COMPOSITIONS
A silicone-(meth) acrylate copolymer and methods for the preparation and use of the copolymer are provided. The copolymer is soluble in ethanol under ambient conditions. The copolymer, or homogeneous ethanol solution thereof, may be used as a film forming agent in a personal care composition, such as a foundation.
A61K 8/893 - Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by an alkoxy or aryloxy group, e.g. behenoxy dimethicone or stearoxy dimethicone
C08F 220/18 - Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
C08F 230/08 - Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium, or a metal containing a metal containing silicon
A61Q 1/12 - Face or body powders, e.g. for grooming, adorning or absorbing
17.
Solvent stable slip additive composition with monoterpene
p—A′ where e/p is 1-9, A and A′ are selected from hydrogen, alkyl, substituted alkyl, aryl, and substituted aryl groups and at least one of A and A′ is H; (c) non-aqueous fluid carrier miscible with (a); and (d) monoterpene; the weight-ratio of (c) to (b) is 0.5-1; weight-ratio of (b) and (c) to (a) is 0.01-0.50; and the composition contains below one ppm aromatic solvent.
C09D 183/06 - Polysiloxanes containing silicon bound to oxygen-containing groups
C09D 4/06 - Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups
C09D 145/00 - Coating compositions based on homopolymers or copolymers of compounds having no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic or in a heterocyclic ring system; Coating compositions based on derivatives of such polymers
A fabric care composition is provided including water; a cleaning surfactant; a fabric softening silicone, wherein the fabric softening silicone is a nitrogen containing silicone; and a deposition aid polymer, wherein the deposition aid polymer is a dextran polymer functionalized with quaternary ammonium moieties; and wherein the deposition aid polymer enhances deposition of the fabric softening silicone from the fabric care composition onto a fabric.
Provided are multilayer structures and articles comprising same. The multilayer structure comprises: a biaxially-oriented polyethylene film comprising a skin layer with a matte surface and a core, the core comprising one or more core layers; a sealant film; and an adhesive adhering the sealant film to the matte surface of the skin layer of the biaxially-oriented polyethylene film. The multilayer structure can exhibit an enhanced adhesive bonding force in comparison to other multilayer structures.
B32B 27/08 - Layered products essentially comprising synthetic resin as the main or only constituent of a layer next to another layer of a specific substance of synthetic resin of a different kind
B32B 7/12 - Interconnection of layers using interposed adhesives or interposed materials with bonding properties
B32B 7/03 - Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical propert; Layered products characterised by the interconnection of layers with respect to the orientation of features
A method of packaging a battery device with a metal shell, comprising: applying a waterborne two-component polyurethane composition to the metal shell of the battery device, and drying the applied polyurethane composition to form a packaging layer; wherein the polyurethane composition comprises, (A) an aqueous dispersion comprising a hydroxyl-functional polymer, wherein the hydroxyl-functional polymer comprises, by weight based on the weight of the hydroxyl-functional polymer, from 20% to 50% of structural units of a hydroxy-functional alkyl (meth)acrylate; from 0.1% to 10% of structural units of an acid monomer, a salt thereof, or mixtures thereof; and structural units of a monoethylenically unsaturated nonionic monomer; and (B) a polyisocyanate.
An aqueous coating composition comprising (a) from 12.5% to 87% by weight based on the weight of the aqueous coating composition, of a film-forming polymer; (b) from 9.5% to 85% by weight based on the weight of the film-forming polymer, of a specific oligomer; and (c) from 2.5% to 50% by weight based on the weight of the film-forming polymer, of beads with a mean particle size of from 5.0 to 10.5 μm; and a process for preparing the aqueous coating composition.
C09D 4/06 - Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups
C09D 133/06 - Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
The present invention relates to a coated paper article with an intermediate basecoat layer comprising high void fraction porous hollow sphere polymer particles (HSPs). HSPs with very small pore area density and high void fraction result in increased optical density at a given print energy in thermal printing applications.
B41M 5/44 - Intermediate or covering layers characterised by the macromolecular compounds
C08F 265/00 - Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group
C09D 151/00 - Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
23.
ONE-STEP PROCESS FOR MAKING SILICONE IMPACT MODIFIERS
A one-step process for preparing a silicone impact modifier comprises polymerizing a reaction mixture, where the reaction mixture comprises a telechelic methacrylate functional silicone and at least one alkyl (meth)acrylate.
C08F 283/12 - Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass on to polysiloxanes
C08F 230/08 - Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium, or a metal containing a metal containing silicon
C08L 51/08 - Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
C08L 69/00 - Compositions of polycarbonates; Compositions of derivatives of polycarbonates
A method for making a skin moisturizing formulation is provided, comprising: providing a dermatologically acceptable vehicle; selecting a skin moisturizing agent based on its ability to absorb and retain moisture, wherein the skin moisturizing agent selected is a cationic dextran polymer, comprising a dextran polymer functionalized with quaternary ammonium groups; providing the selected skin moisturizing agent; combining the dermatologically acceptable vehicle and the skin moisturizing agent to form a skin moisturizing formulation; wherein the skin moisturizing formulation contains 0.05 to 10 wt %, based on weight of the skin moisturizing formulation, of the skin moisturizing agent. Also provided is a method for moisturizing skin.
The present invention relates to a composition comprising cerium(III) carbonate and a photoinitiator. The composition is useful for paints formulations that benefit from dirt pickup resistance and retention of color over time.
A waterborne precursor polymer dispersion composition comprising the reaction product obtained by free-radical emulsion polymerization of a monomer mixture comprising: (A) at least one alkyl (meth)acrylate; and (B) at least one ethylenically unsaturated compound comprising: (Bi) at least one first functional group; wherein the at least one first functional group comprises at least one ethylenically unsaturated group; and (Bii) at least one second functional group; wherein the at least one second functional group comprises at least one functional group different than the ethylenically unsaturated group; wherein the second functional group is capable of reacting with a crosslinker component; and wherein the crosslinker component is not reactive with component (A) in free-radical polymerization; in the presence of: (C) an aqueous medium; and (D) at least one acid surfactant salt with pKaH from 2.6 to 7; a waterborne contact adhesive polymer dispersion composition including a mixture of: (I) the above waterborne precursor polymer dispersion composition and (II) a crosslinker compound for crosslinking with the at least one second functional group, component (Bii); a bonded article including at least two substrates adhered together with the above waterborne contact adhesive polymer dispersion composition; a process for preparing the above waterborne precursor polymer dispersion composition; a process for preparing the above waterborne contact adhesive composition; and a process of bonding two substrates together using the above waterborne contact adhesive composition to form a bonded article.
The present invention relates to a composition comprising an aqueous mixture of a rheology modifier and a surfactant of Formula I:
The present invention relates to a composition comprising an aqueous mixture of a rheology modifier and a surfactant of Formula I:
The present invention relates to a composition comprising an aqueous mixture of a rheology modifier and a surfactant of Formula I:
where R, R1, x, and y are as defined herein. The composition of the present invention provides a rheology modifier that does not promote microbial growth and does not require a biocide.
A gas barrier laminate and a process for preparing the gas barrier laminate, comprising: (i) providing a paper substrate, (ii) applying an aqueous gas barrier composition to the paper substrate, and (iii) drying the aqueous gas barrier composition at a temperature of less than 120 ℃ for less than 10 minutes to form a gas barrier coating; thereby obtaining the gas barrier laminate; where the aqueous gas barrier composition comprises: (a) an ethylene-vinyl alcohol copolymer having a saponification degree of 85 mol%or more, and (b) a partially neutralized (meth) acrylic acid polymer having a degree of neutralization of from 6 mol%to 18 mol%; where the weight ratio of the ethylene-vinyl alcohol copolymer to the partially neutralized (meth) acrylic acid polymer is in a range of from 80: 20 to 50: 50.
D21H 19/20 - Coatings without pigments applied in a form other than the aqueous solution defined in group comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
A barrier coating comprising a polyvinyl alcohol and a polyacrylic acid wherein the barrier film is formed at less than or equal to 100℃ is disclosed. A laminate comprising a barrier coating formed at less than or equal to 100℃ comprising a polyvinyl alcohol and a polyacrylic acid is also disclosed. The polyacrylic acid can comprise a poly (meth) acrylic acid with a number average molecular weight of from 2000 to 400, 000g/mol, have a 2 to 50% degree of neutralization. The polyvinyl alcohol can have a saponification degree of at least 80%, and a molecular weight of from 10,000 to 300, 000 g/mol. The disclosed barrier coating provides good OTR performance without metallization.
Provided are multistage polymer compositions comprising (a) a core comprising a silicone polymer, and (b) a shell comprising a silicone polymer. At least one of the silicone polymer in the core and the acrylic polymer in the shell comprise polymerized units derived from an organo-phosphorus monomer. Also provided are matrix resin compositions comprising such polymer compositions and a matrix resin.
An automatic dishwashing composition is provided including a builder; a nonionic surfactant; and a dispersant polymer comprising: (a) >60 to <90 wt %, based on weight of the dispersant polymer, of structural units of formula I
An automatic dishwashing composition is provided including a builder; a nonionic surfactant; and a dispersant polymer comprising: (a) >60 to <90 wt %, based on weight of the dispersant polymer, of structural units of formula I
An automatic dishwashing composition is provided including a builder; a nonionic surfactant; and a dispersant polymer comprising: (a) >60 to <90 wt %, based on weight of the dispersant polymer, of structural units of formula I
wherein each R1 is independently selected from a hydrogen and a —CH3 group; and (b) >10 to <40 wt %, based on weight of the dispersant polymer, of structural units of formula II
An automatic dishwashing composition is provided including a builder; a nonionic surfactant; and a dispersant polymer comprising: (a) >60 to <90 wt %, based on weight of the dispersant polymer, of structural units of formula I
wherein each R1 is independently selected from a hydrogen and a —CH3 group; and (b) >10 to <40 wt %, based on weight of the dispersant polymer, of structural units of formula II
An automatic dishwashing composition is provided including a builder; a nonionic surfactant; and a dispersant polymer comprising: (a) >60 to <90 wt %, based on weight of the dispersant polymer, of structural units of formula I
wherein each R1 is independently selected from a hydrogen and a —CH3 group; and (b) >10 to <40 wt %, based on weight of the dispersant polymer, of structural units of formula II
wherein each R2 is independently selected from the group consisting of a C1-6 hydroxyalkyl group and a C1-6 alkoxy group; and wherein each R3 is independently selected from a hydrogen and a methyl group.
A composite polymer composition comprising: the emulsion polymerization product of: (i) an aqueous polyolefin dispersion comprising the melt kneading product of one or more polyolefins, from 0.5 to 25 wt % of one or more dispersion stabilizing agents and water, and (ii) one or more (meth)acrylic monomers; wherein the one or more polyolefins have a Tg equal to or less than 50° C.; wherein the melt kneading product (i) comprises polymer particles having a volume average particle size between 50 nm and 2000 nm dispersed in the water; wherein the one or more dispersion stabilizing agents comprises a fatty acid or fatty acid salt stabilizing agent; and wherein the one or more (meth)acrylic monomers graft onto the polymer particles form composite polymer particles is provide. Also provided is a method of making the composition and impact modifiers comprising the composition.
C08L 51/06 - Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
C08F 255/02 - Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group on to polymers of olefins having two or three carbon atoms
C08L 69/00 - Compositions of polycarbonates; Compositions of derivatives of polycarbonates
A barrier coating comprising a polyvinyl alcohol, a polyacrylic acid, and a carbodiimide wherein the barrier film is formed at less than 120℃ is disclosed. A laminate comprising the barrier coating comprising a polyvinyl alcohol, a polyacrylic acid, and a carbodiimide is also disclosed. The polyacrylic acid can comprise a poly (meth) acrylic acid with a molecular weight from 2000 to 400, 000g/mol, and a degree of neutralization of from 2 to 50%. The polyvinyl alcohol can have a saponification degree of at least 80% and a molecular weight of from 10, 000 to 300, 000 g/mol. The disclosed barrier coating provides good OTR at high humidity without the need for high curing temperatures or non-commercially viable cure times.
An aqueous composition comprises a filler and a dispersion of multi-stage polymer particles. The particles have a first stage formed from non-ionic ethylenically unsaturated monomers and ethylenically unsaturated acid functional monomers polymer and a second stage, formed from 85-98.5 weight% non-ionic ethylenically unsaturated monomers, 1-15 weight% of ethylenically unsaturated acid functional monomers, and either (i) 0.01-0.5 weight % a non-silane functional chain transfer agent and 0.4-2 weight% of an ethylenically unsaturated silane functional monomer or (ii) 0.01-0.5 weight% of a silane functional chain transfer agent and 0-2 weight% of an ethylenically unsaturated silane functional monomer based on total weight of monomers and chain transfer agent in the second stage. The weight ratio of the first stage to the second stage is 1:1 to 9:1. The weight ratio of filler to polymer particles is 0.01:1 to 2:1. The composition can form sealants that meet ASTM C920 class 50.
C08F 265/06 - Polymerisation of acrylate or methacrylate esters on to polymers thereof
C08F 285/00 - Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
C09D 151/00 - Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
E21B 33/00 - Sealing or packing boreholes or wells
C09J 151/00 - Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
35.
MULTISTAGE IMPACT MODIFIERS WITH ORGANO-PHOSPHORUS IN A LATTER STAGE
Provided are multistage polymer compositions comprising (a) an initial stage polymer, and (b) a latter stage polymer, wherein latter stage polymer comprises polymerized units derived from at least one alkyl (meth)acrylate monomer, a styrene monomer, and at least one organo-phosphorus monomer. The at least one organo-phosphorus monomer is in the acid form as a salt of the phosphorus acid group. The weight ratio of the at least one alkyl (meth) acrylate monomer to styrene monomer in the latter stage polymer ranges from 50:50 to 90:10. Also provided are matrix resin compositions comprising such polymer compositions and a matrix resin, and a method for making the multistage polymer compositions.
C08F 279/02 - Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group on to polymers of conjugated dienes
C08L 51/04 - Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
Provided is an aqueous composition comprising dispersed particles that comprise a polymer, wherein the polymer comprises, by weight based on the weight of the polymer, a) 60% to 99.95% polymerized units of one or more (meth)acrylate ester, b) 0.05% to 6% polymerized units of one or more N-vinyl lactam, c) 0% to 39.95% polymerized units of one or more other monomers. Also provided is a method of making that composition, a process for producing an article using that composition, and a method of bonding two substrates using that article.
The present invention relates to composition comprising an aqueous dispersion of single phase crosslinked low Tg microspheres and film-forming polyurethane particles. The composition of the present invention is useful as a basecoat layer for a multilayered leather article.
A laundry detergent formulation is provided including a detergent surfactant; a builder; a filler and an antiredeposition agent, comprising: 10 to 65 wt % of structural units of formula I
A laundry detergent formulation is provided including a detergent surfactant; a builder; a filler and an antiredeposition agent, comprising: 10 to 65 wt % of structural units of formula I
A laundry detergent formulation is provided including a detergent surfactant; a builder; a filler and an antiredeposition agent, comprising: 10 to 65 wt % of structural units of formula I
wherein each R1 and R2 is independently selected from a hydrogen and a C1-3 alkyl group; 10 to 80 wt % of structural units of formula II
A laundry detergent formulation is provided including a detergent surfactant; a builder; a filler and an antiredeposition agent, comprising: 10 to 65 wt % of structural units of formula I
wherein each R1 and R2 is independently selected from a hydrogen and a C1-3 alkyl group; 10 to 80 wt % of structural units of formula II
A laundry detergent formulation is provided including a detergent surfactant; a builder; a filler and an antiredeposition agent, comprising: 10 to 65 wt % of structural units of formula I
wherein each R1 and R2 is independently selected from a hydrogen and a C1-3 alkyl group; 10 to 80 wt % of structural units of formula II
wherein each R3 is independently selected from a hydrogen and a —C(O)CH3 group; and 10 to 65 wt % of structural units of formula III
A laundry detergent formulation is provided including a detergent surfactant; a builder; a filler and an antiredeposition agent, comprising: 10 to 65 wt % of structural units of formula I
wherein each R1 and R2 is independently selected from a hydrogen and a C1-3 alkyl group; 10 to 80 wt % of structural units of formula II
wherein each R3 is independently selected from a hydrogen and a —C(O)CH3 group; and 10 to 65 wt % of structural units of formula III
A laundry detergent formulation is provided including a detergent surfactant; a builder; a filler and an antiredeposition agent, comprising: 10 to 65 wt % of structural units of formula I
wherein each R1 and R2 is independently selected from a hydrogen and a C1-3 alkyl group; 10 to 80 wt % of structural units of formula II
wherein each R3 is independently selected from a hydrogen and a —C(O)CH3 group; and 10 to 65 wt % of structural units of formula III
wherein each R4 is independently selected from a hydrogen and a —CH3 group; and wherein at least one of R1 and R2 is a C1-3 alkyl group in at least 1 mol % of the structural units of formula I in the antiredeposition agent; wherein the antiredeposition agent has a lactone end group and wherein the antiredeposition agent has a weight average molecular weight of 1,500 to 6,000 Daltons.
Provided is a composition comprising one or more epoxy phosphate esters wherein the structure comprises two or more polyester linkages. Also provided is a method of making the epoxy phosphate esters that comprises reacting one or more epoxy-terminated polyesters with one or more phosphoric acids. Further provided is an adhesive composition that comprises one or more epoxy phosphate esters, one or more multifunctional isocyanate prepolymers, and one or more multifunctional isocyanate-reactive compounds.
C09J 167/00 - Adhesives based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Adhesives based on derivatives of such polymers
The present disclosure relates to a formaldehyde-free aqueous curable composition comprising: A) a polymer polymerized from a monomer mixture comprising (a) 30-90 wt % of C1-C10 alkyl acrylate; (b) 10-60 wt % of vinylaromatics; (c) 0.5-10 wt % of an ethylenically unsaturated compound having at least two carboxylic acid groups; (d) 0-10 wt % of an ethylenically unsaturated acid having one carboxylic acid group; (e) 0-5 wt % of other ethylenically unsaturated monomers; wherein the percentages are based on the total weight of the monomer mixture; and B) a titanium catalyst.
D06M 15/263 - Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
C08F 4/76 - Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group selected from refractory metals selected from titanium, zirconium, hafnium, vanadium, niobium, or tantalum
The present invention provides modified urea formaldehyde (UF) resin binder compositions and mineral fiber mats having an emulsion polymer modifier comprising, in copolymerized form, from 5 to 25 wt. % of co polymerized carboxylic acid functional monomers. The emulsion polymers have a measured glass transition temperature (DSC) ranging from −40° C. to 70° C. and a large average particle size. Further, the emulsion polymers comprise less than 30% of the copolymerized acid in neutralized form and do not excessively thicken aqueous compositions containing them. The modified UF resin binder compositions enable good dilution stability in use and high tensile strength in products containing them.
C08L 61/24 - Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds with urea or thiourea
D04H 1/587 - Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives characterised by the bonding agents used
D04H 1/645 - Impregnation followed by a solidification process
The present invention relates to a method for preparing a multiplicity of containers of paints or pre-paints from separate vessels containing an aqueous solution of a rheology modifier, optionally an aqueous dispersion of an opacifying pigment, an aqueous dispersion of polymer particles, and an aqueous dispersion of organic polymeric microspheres. The process of the present invention provides a simple and cost-effective way of preparing a wide variety of a large quantity of contained and finished paints at point-of-sale.
A two-component, solvent-based polyurethane adhesive composition based on a crystalline polycarbonate for producing an adhesive laminate structure including: (a) at least one isocyanate component; and (b) at least one isocyanate-reactive component comprising a reaction product of: (i) at least one crystalline polycarbonate diol compound, (ii) at least one acrylic polymer compound; and (iii) at least one solvent; and a process for preparing the adhesive composition.
An aqueous polymer composition contains (a) polymeric particles comprising an acrylic copolymer and a hydroxyl-terminated polysiloxane, where the polymeric particles have an average particle size of from 50 nm to 300 nm; and where the hydroxyl-terminated polysiloxane present in the aqueous polymer composition is at a concentration of greater than 3.5% to 9%, by weight based on the weight of the acrylic copolymer; and (b) from 3% to 12%, by weight based on the weight of the acrylic copolymer, of an alkyl silane containing at least one alkyl having 5 to 20 carbon atoms.
A two-component, solvent-based polyurethane adhesive composition based on a crystalline polyester-polycarbonate for producing an adhesive laminate structure including: (a) at least one isocyanate component; and (b) at least one isocyanate-reactive component comprising at least one crystalline polyester-polycarbonate compound; and a process for preparing the adhesive composition.
A novel polyol compound represented by Formula (I) is provided. A polyurethane-based adhesive composition comprising the polyol compound can produce an adhesive layer exhibiting superior bond strength and heat seal strength which will not be substantially deteriorated by the change in the weight ratio between isocyanate component and polyol component. Methods for preparing the polyol compound and for preparing the adhesive composition, as well as a laminate article prepared with said adhesive composition are also provided.
A novel polyol compound represented by Formula (I) is provided. A polyurethane-based adhesive composition comprising the polyol compound can produce an adhesive layer exhibiting superior bond strength and heat seal strength which will not be substantially deteriorated by the change in the weight ratio between isocyanate component and polyol component. Methods for preparing the polyol compound and for preparing the adhesive composition, as well as a laminate article prepared with said adhesive composition are also provided.
The present invention relates to a waterborne composition comprising an aqueous dispersion of first and second multistage polymer particles, wherein each of the first and second polymer particles comprises a water-occluded core and a high Tg polymeric shell wherein the second multistage polymer particles further comprise a polymeric binder layer superposing the shell. The composition of the present invention is useful for reducing the load of TiO2 in paint formulations, while producing coatings with excellent hiding and scrub resistance.
The present invention is a composition comprising an aqueous admixture of a neutralized or partially neutralized aminosilane and an associative thickener, wherein the admixture has a pH of less than 10.2. The admixture is beneficial as an easy-to-use paint additive that provides stain removal, stain blocking, and corrosion resistance for coatings from low VOC paints.
A method of making an aqueous cotton renewing composition for renewing a soiled cotton containing fabric is provided comprising: providing a liquid carrier; providing a cellulase; selecting a protectant polymer, comprising: 25 to 65 wt %, based on weight of the protectant polymer, of structural units of formula I
A method of making an aqueous cotton renewing composition for renewing a soiled cotton containing fabric is provided comprising: providing a liquid carrier; providing a cellulase; selecting a protectant polymer, comprising: 25 to 65 wt %, based on weight of the protectant polymer, of structural units of formula I
A method of making an aqueous cotton renewing composition for renewing a soiled cotton containing fabric is provided comprising: providing a liquid carrier; providing a cellulase; selecting a protectant polymer, comprising: 25 to 65 wt %, based on weight of the protectant polymer, of structural units of formula I
wherein each R1 is independently selected from a hydrogen and a —CH3 group; and 35 to 75 wt %, based on weight of the protectant polymer, of structural units of formula II
A method of making an aqueous cotton renewing composition for renewing a soiled cotton containing fabric is provided comprising: providing a liquid carrier; providing a cellulase; selecting a protectant polymer, comprising: 25 to 65 wt %, based on weight of the protectant polymer, of structural units of formula I
wherein each R1 is independently selected from a hydrogen and a —CH3 group; and 35 to 75 wt %, based on weight of the protectant polymer, of structural units of formula II
A method of making an aqueous cotton renewing composition for renewing a soiled cotton containing fabric is provided comprising: providing a liquid carrier; providing a cellulase; selecting a protectant polymer, comprising: 25 to 65 wt %, based on weight of the protectant polymer, of structural units of formula I
wherein each R1 is independently selected from a hydrogen and a —CH3 group; and 35 to 75 wt %, based on weight of the protectant polymer, of structural units of formula II
wherein each R2 is independently selected from a —C2-3 alkyl group and wherein each R3 is independently selected from a hydrogen and a methyl group; providing the selected protectant polymer; and combining the liquid carrier, the cellulase and the selected protectant polymer to form the aqueous cotton renewing composition. Also provided is a method of renewing a soiled cotton containing fabric.
The present invention relates to an aqueous dispersion of polymeric microspheres with a high surface Young's modulus and a relatively low core Young's modulus. The dispersion of the present invention is useful in paint formulations for providing improving hydrophobic stain resistance, for example, resistance to lipstick.
C08L 51/00 - Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
C08F 220/18 - Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
A vinyl article comprises a vinyl substrate and an infrared reflective film disposed on the vinyl substrate. The infrared reflective film has a reflectivity greater than 30% for wavelengths between 800 to 1000 nm and a transmittance greater than 60% for wavelengths between 400 to 700 nm. A process for producing the vinyl article is also disclosed.
C08F 265/02 - Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group on to polymers of acids, salts or anhydrides
C08F 285/00 - Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
The present invention relates to a composition comprising an aqueous dispersion of cerium (III) carbonate particles having a z-average particle size in the range of from 5 nm to 500 nm, which composition further comprises a capping ligand. The composition is useful as an additive in formulations that contain polymer, pigments, dyes, or tints, or a combination thereof, to promote color retention and attenuate unwanted color formation in coatings formed from these formulations.
Disclosed is a composition comprising a polycarbonate or engineering resin and a branched polymer which is a reaction product of reactants comprising one or more monoethylenically unsaturated ester monomers, a chain transfer agent in an amount of 0.1 to 10 weight percent, and a crosslinker in an amount of 0.1 to 10 weight percent of a crosslinker, wherein weight percent is based on total amount of reactants, provided the amount of crosslinker in moles is less than the effective amount of chain transfer agent in moles, and articles thereof.
C08F 285/00 - Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
C08F 265/02 - Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group on to polymers of acids, salts or anhydrides
C09D 151/00 - Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
C08F 265/04 - Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group on to polymers of esters
A scale inhibitor composition includes a reaction product of a polymerization mixture that includes acrylic acid, 2-acrylamido-2-methylpropane sulfonic acid, and a phosphoethyl methacrylate composition including at least 10 wt% of phosphoethyl methacrylate monoester, at least 10 wt% of phosphoethyl methacrylate diester, and at least 5 wt% of phosphoric acid, based on a total weight of the phosphoethyl methacrylate composition.
The present invention provides coated films and articles formed from such films. In one aspect, a coated film comprises (a) a film and (b) a coating on an outer surface of the film comprising polyurethane and a plurality of [(trimethylsilyl)oxy]-modified silica particles. In some embodiments, the coated film is thermally resistant under the sealing conditions of ASTM 1921-98 over a temperature range of 80 C to 200 C, and/or has a gloss of 11 or less when measured at 45 in accordance with ASTM D2457.
The present invention relates to a method of preparing an aqueous dispersion of nanosized cerium (III) carbonate particles comprising the step of admixing in water a) a water-soluble ammonium cerium (III) salt, b) a water-soluble carbonate, and c) a capping ligand to form an aqueous dispersion of cerium (III) carbonate particles having a resultant z-average particle size is in the range of from 5 nm to 500 nm. The method is useful for the preparation of an additive that is useful in formulations that contain polymer, pigments, dyes, or tints, or a combination thereof, to promote color retention and attenuate unwanted color formation in coatings formed from these formulations.
The present invention relates to a process for preparing a blend of comprising an aqueous dispersion of polymer particles, a PMHS, an opacifying pigment, and an extender. The blend of the present invention is useful in exterior paint applications, especially where retention of color in the painted substrate is important.
A laminate, an article comprising the laminate and a method for preparing the laminate are provided. The present disclosure relates to a laminate, comprising a first substrate comprising a metalized polyethylene-based (PE based) film; a second substrate comprising a polyethylene terephthalate-based film or a polypropylene-based film; and, an adhesive layer adhering the first substrate to the second substrate, wherein the adhesive layer is derived from a two-component solvent-based polyurethane adhesive composition; wherein the concentration of fatty acids or fatty acid derivatives in the metalized PE-based film is less than 300ppm, based on the total weight of the metalized PE-based film, wherein the two-component solvent-based polyurethane adhesive composition comprises a polyester polyol component and a polyisocyanate component, wherein the polyester polyol component has about 40wt%-60 wt %of aromatic rings in the backbone, based on the total weight of the polyester polyol and a molecular weight (Mw) between 5,000 and 50,000; and wherein the weight ratio of the polyester polyol component to the polyisocyanate component is from 100: 5 to 100: 30.
An aqueous coating composition contains: (a) from 50% to 90%, by weight based on the weight of the aqueous coating composition, of a film-forming polymer; (b) from 4% to 90%, by weight based on the weight of the film-forming polymer, of an oligomer having a weight average molecular weight of less than 15,000 g/mol; where the oligomer comprises, by weight based on the weight of the oligomer, from 1% to 20% of structural units of an acid monomer, a salt thereof, or mixtures thereof; from zero to 20% of structural units of a monoethylenically unsaturated functional monomer carrying at least one of functional groups selected from an amide, carbonyl, ureido, silane, hydroxy, or amino group, or combinations thereof; from 30% to 99%of structural units of a hydrophilic monoethylenically unsaturated nonionic monomer; and from zero to 30% of structural units of a hydrophobic monoethylenically unsaturated nonionic monomer; and (c) from 4% to 15%, by weight based on the weight of the aqueous coating composition, of a specific silicone polyether copolymer.
The present invention relates to a composition comprising an aqueous solution of a copolymer of (meth)acrylic acid and a cyclic ketene acetal monomer. The copolymer is useful as a biodegradable dispersant.
The present invention relates to a composition comprising a polymer and cerium (III) carbonate. The composition is useful in coatings formulations that include pigments, dyes, or tints, or a combination thereof, to promote color retention and attenuate unwanted color formation in coatings formed from these formulations.
A process for reducing hair damage upon exposure to heat is provided, including: providing aqueous carrier; selecting heat protectant, wherein heat protectant is selected for its ability to impart thermal protection to hair and to be modified carbohydrate polymer, comprising cellulose ether base material functionalized with trialkyl ammonium moieties, having Kjeldahl nitrogen content of 0.75 to 2.5 wt %; and hydrophobic substituents having 16 carbon atoms; providing the selected heat protectant; combining the cosmetically acceptable aqueous carrier and the heat protectant to form aqueous thermal protectant formulation; wherein the aqueous thermal protectant formulation contains 0.1 to 5 wt %, based on weight of the aqueous thermal protectant formulation, of the heat protectant; providing hair; applying the aqueous thermal protectant formulation to hair; providing heat generating hair care appliance; exposing hair to heat at 50 to 300° C. using the heat generating hair care appliance for 1 to 30 minutes.
The present invention relates to a method for preparing a copolymer comprising structural units of acrylic acid and a cyclic ketene acetal monomer. The copolymer is useful as a biodegradable dispersant.
An automatic dishwashing composition is provided including a builder; a nonionic surfactant; a poly(glutamic acid); and a dispersant polymer selected from the group consisting of: (a) a non-sulfonated hydrophobic modified polymer, comprising (i) 60 to 98 wt%, based on weight of the non-sulfonated hydrophobic modified polymer, of structural units of formula I, wherein each R1 is independently selected from a hydrogen and a -CH3 group; and (ii) 2 to 40 wt%, based on weight of the non-sulfonated hydrophobic modified polymer, of structural units of formula II, wherein each R2 is independently selected from a -C1-4 alkyl group and wherein each R3 is independently selected from a hydrogen and a methyl group; (b) a sulfonated polymer; (c) an acrylic acid homopolymer; and (d) a mixtures thereof.
The present invention relates to a method for preparing a multiplicity of containers of paint from a plurality of vessels separately containing an aqueous solution of a rheology modifier, an aqueous dispersion of a colorant, an aqueous dispersion of polymer particles, and an aqueous dispersion of organic polymeric microspheres. In another embodiment, the present invention relates to a method of dispensing a colorant or an opacifying agent or an inorganic extender into separate containers partially filled with a waterborne pre-paint mixture of rheology modifier, polymer particles, and organic polymeric microspheres. The process of the present invention provides a simple and cost-effective way of preparing a wide variety of a large quantity of contained and finished paints at point-of-sale.
The present invention relates to a composition comprising an aqueous solution of a branched HEUR, and a nonionic surfactant having an HLB in the range of 11 to 19. The composition of the present invention provides a rheology modifier that provides a formulator with independent control of viscosity across low-, mid-, and high-shear rate regimes.
22 composite particles and an organic matting agent, as well as a method for making the composition. The composition of the present invention is useful for coating compositions to improve mar resistance of coatings.
A hair care formulation is provided, comprising: a dermatologically acceptable vehicle; a dermatologically acceptable oil; and a deposition aid polymer, wherein the deposition aid polymer is a dextran polymer functionalized with an amine group; wherein the dextran polymer has a weight average molecular weight of 100,000 to 650,000 Daltons; and wherein the deposition aid polymer enhances deposition of the dermatologically acceptable oil from the hair care formulation onto mammalian hair.
A process for producing a coated, printed substrate comprising (a) providing a printed substrate, wherein the substrate comprises a surface on which resides one or more areas of a layer of an ink, (b) bringing together a component A and a component B to form a urethane coating composition, wherein component A comprises a polyisocyanate prepolymer A1, wherein the polyisocyanate prepolymer A1 is a reaction product of a polyisocyanate monomer A1a and an isocyanate-polyreactive compound A1b, wherein component B comprises one or more polyol B1, wherein the urethane coating composition has isocyanate index greater than 0.9, (c) applying a layer of the urethane coating composition to the surface. Also provided is a coated printed substrate made by such a method.
A process for the production of methyl methacrylate via the oxidative esterification in a reactor system comprises introducing a reaction mixture comprising methacrolein, methanol, and an oxygen-containing gas to the reactor system comprising a noble metal-containing catalyst. A methanol concentration of the reaction mixture entering the reactor is greater than 32 wt% based on the total weight of methanol and methacrolein entering the reactor system. The methanol concentration in the product stream exiting the reactor system is at least 65 wt% based on the total weight of the methanol and methacrolein exiting the reactor system. The product stream exiting the reactor system comprises greater than 0.1 ppm and less than 5000 ppm methyl isobutyrate.
A process for producing methyl methacrylate by oxidative esterification in a reactor system comprising one or more reactors is disclosed. The process comprises feeding methanol, methacrolein, and an oxygen containing gas to a first reactor. The first reactor comprises a heterogeneous noble metal-containing catalyst. A base material is introduced at a position external to the first reactor and the base material is mixed with one or more reactants to form a base-containing stream. The base-containing stream is fed to the first reactor, wherein the pH in the first reactor is between 4 and 10.
A process for the production of an alkyl methacrylate is disclosed, the method comprising: a) producing methacrolein from propionaldehyde and formaldehyde; and b) reacting the methacrolein in an oxidative esterification reaction to obtain the alkyl methacrylate. Reacting the methacrolein in an oxidative esterification reaction comprises introducing a reaction mixture comprising the methacrolein, an alkyl alcohol, and an oxygen-containing gas to a reactor system comprising a heterogeneous noble metal-containing catalyst. An average concentration of methacrolein in step b) is less than 40 wt% based on the total weight of alkyl alcohol and methacrolein. The reactor system of step d) has an average ratio of alkyl alcohol to methacrolein less than 20:1 based on an average amount of alkyl alcohol and methacrolein entering and exiting the system. A liquid phase stream exiting the reactor system contains at least 30 wt% alcohol based on the total weight of the liquid phase stream. The liquid phase stream exiting the reactor system contains less than 30 wt% methacrolein based on the total weight of the liquid phase stream. The liquid phase stream exiting the reactor system comprises greater than 0.1 ppm and less than 5000 ppm of an alkyl isobutyrate. A gas phase stream exiting the reactor system comprises between 1 mol% and 7.5 mol% oxygen based on the total amount of the gas phase stream. The alkyl alcohol is a straight or branched alcohol comprising from 1 to 12 carbon atoms.
A process for producing methacrylic acid comprising: a) producing methacrolein from propionaldehyde and formaldehyde; b) producing methacrylic acid in an oxidative reaction from the methacrolein produced in step a) and water. Step b) is performed at a pressure above 1 bar. Step c) is performed in a reactor system in a liquid phase reaction in the presence of a heterogeneous noble metal-containing catalyst, where the reactor system comprises an oxygen-containing gas. An average concentration of methacrolein in step b) is less than 40 wt% based on the total weight of water and methacrolein. The reactor system of step b) has an average ratio of water to methacrolein less than 40:1 based on an average amount of water and methacrolein entering and exiting the system.
C07C 45/50 - Preparation of compounds having C=O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
C07C 51/25 - Preparation of carboxylic acids or their salts, halides, or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
A process for producing methyl methacrylate by oxidative esterification is disclosed. The process comprises reacting methanol and methacrolein in a reactor system comprising an oxygen-containing gas and a heterogeneous noble metal-containing catalyst to produce methyl methacrylate. No Arrhenius base is added to the reactor system.
A catalyst comprising noble metal particles and titanium-containing particles. The noble metal particles and titanium-containing particles are disposed on an outer surface of a support. At least 20% by weight of the total weight of noble metal particles are adjacent to at least one titanium-containing particle. The noble metal particles have an average diameter of less than 15 nm, and the catalyst has an average diameter of at least 200 microns. A method for preparing methyl methacrylate from methacrolein and methanol using the catalyst is also disclosed.
Process for producing methyl methacrylate is disclosed, the method comprising: a) producing propionaldehyde from ethylene; b) reacting the propionaldehyde with formaldehyde to produce methacrolein; and c) reacting the methacrolein in an oxidative esterification reaction to produce methyl methacrylate. Step b) is performed at a pressure above 1 bar. Step c) is a liquid phase reaction and is carried in a reactor system comprising one or more reactors and is performed in the presence of a heterogeneous noble metal-containing catalyst. An average ratio of methanol to methacrolein in the reactor system is less than 20:1 based on average amount of methanol and methacrolein entering and exiting the system. An average concentration of methacrolein in the reactor system is less than 40 wt% based on the total weight of the methanol and methacrolein in the reactor system, where the average concentration of methacrolein in the reactor system is the average of the concentration of methacrolein entering and exiting the reactor system. Oxygen is maintained in a vapor space in the reactor system in a concentration ranging from 2.5 mol% to 7.5 mol% relative to the total amount of the vapor phase.
C07C 45/50 - Preparation of compounds having C=O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
A catalyst comprises gold particles and titanium-containing particles. The catalyst comprises gold particles that are within at least 15 nm of at least one titanium-containing particle. The gold particles have an average diameter of less than 15 nm and a standard deviation of +/-5 nm. A method for preparing methyl methacrylate from methacrolein and methanol using the catalyst is also disclosed.
A process for the production of methyl methacrylate is disclosed, the method comprising: a) producing methacrolein from propionaldehyde and formaldehyde; and b) reacting the methacrolein in an oxidative esterification reaction to obtain methyl methacrylate. Reacting the methacrolein in an oxidative esterification reaction comprises introducing a reaction mixture comprising the methacrolein, methanol, and an oxygen-containing gas to a reactor system comprising a heterogeneous noble metal-containing catalyst. A liquid phase stream exiting the reactor system contains at least 30 wt% methanol based on the total weight of the liquid phase stream. The liquid phase stream exiting the reactor system contains less than 30 wt% methacrolein based on the total weight of the liquid phase stream. The liquid phase stream exiting the reactor system comprises greater than 0.1 ppm and less than 5000 ppm methyl isobutyrate. A gas phase stream exiting the reactor system comprises between 1 mol% and 7.5 mol% oxygen based on the total amount of the gas phase stream.
A process for producing methyl methacrylate is disclosed, the method comprising: a) producing ethylene from ethanol; b) producing propionaldehyde from the ethylene produced in step a); c) producing methacrolein from propionaldehyde produced in step b) and formaldehyde; and d) producing methyl methacrylate in an oxidative esterification reaction from the methacrolein produced in step c) with methanol. Step c) is performed at a pressure above 1 bar. Step d) is performed in a reactor system in a liquid phase reaction in the presence of a heterogeneous noble metal-containing catalyst, wherein the reactor system comprises an oxygen-containing gas. An average concentration of methacrolein in step d) is less than 40 wt% based on the total weight of methanol and methacrolein. The reactor system of step d) has an average ratio of methanol to methacrolein less than 20:1 based on an average amount of methanol and methacrolein entering and exiting the system.
C07C 45/50 - Preparation of compounds having C=O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
C07C 1/24 - Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as hetero atoms by elimination of water
A hair cleansing formulation is provided, comprising: a dermatologically acceptable vehicle; a dermatologically acceptable hair care cleansing surfactant; a dermatologically acceptable silicone; and a deposition aid polymer, wherein the deposition aid polymer is a tertiary amine functionalized dextran polymer, comprising a branched chain dextran polymer functionalized with tertiary amine groups; wherein the deposition aid polymer enhances deposition of the dermatologically acceptable silicone from the hair cleansing formulation onto mammalian hair.
A61K 8/44 - Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts, esters or N-acylated derivatives thereof
A61K 8/58 - Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
122 alkyl ester of (meth) acrylic acid, a hydroxyalkyl (meth) acrylate, or mixtures thereof; all weight percentage relative to the weight of the first polymer; where the second polymer comprises from zero to less than 0.5%of structural units of an acid monomer, a salt thereof, or mixtures thereof; from zero to 10%of structural units of diacetone (meth) acrylamide; and structural units of a monoethylenically unsaturated nonionic monomer; all weight percentage relative to the weight of the second polymer; and where the second polymer has a glass transition temperature of from -25 to 10 ℃, and the first polymer has a glass transition temperature of at least 50 ℃ higher than that of the second polymer; provided that at least one of the first polymer and the second polymer comprises structural units of the diacetone (meth) acrylamide and the total concentration of structural units of the diacetone (meth) acrylamide is 1.1%or more, by weight based on the weight of the multistage polymeric particles.
C08F 265/00 - Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group
C08L 51/00 - Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
C09D 151/00 - Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
84.
PREPARATION OF AQUEOUS DISPERSION OF ACRYLATE-SILOXANE COPOLYMER PARTICLES
The present invention is a method for preparing a aqueous dispersion of copolymer particles comprising structural units of a) an acrylate monomer; b) an acid monomer; and c) a siloxane acrylate monomer of formula I:
The present invention is a method for preparing a aqueous dispersion of copolymer particles comprising structural units of a) an acrylate monomer; b) an acid monomer; and c) a siloxane acrylate monomer of formula I:
The present invention is a method for preparing a aqueous dispersion of copolymer particles comprising structural units of a) an acrylate monomer; b) an acid monomer; and c) a siloxane acrylate monomer of formula I:
where R, R1, R2, Y and x are defined herein. The method also requires the use of special classes on anionic and nonionic surfactants as described herein. The aqueous dispersion prepared by the method of the present invention is useful in a variety of applications ranging from architectural coatings to personal care products.
A method of making a liquid laundry detergent formulation is provided, comprising: providing a liquid carrier; providing a cleaning surfactant; and selecting a cleaning booster of Formula (I)
A method of making a liquid laundry detergent formulation is provided, comprising: providing a liquid carrier; providing a cleaning surfactant; and selecting a cleaning booster of Formula (I)
A method of making a liquid laundry detergent formulation is provided, comprising: providing a liquid carrier; providing a cleaning surfactant; and selecting a cleaning booster of Formula (I)
wherein x is 3 to 10; wherein y is 5 to 20; wherein z is 5 to 30; wherein x + y + z ≥ 18; wherein x ≠ z; wherein each R is a C7-9 alkyl group, wherein ≥ 75 wt% of the R groups are branched; wherein the selected cleaning booster of Formula (I) is selected based its cleaning boosting properties; providing the selected cleaning booster of Formula (I); and combining the liquid carrier, the cleaning surfactant and the selected cleaning booster of Formula (I) to provide the liquid laundry detergent formulation.
The present invention provides two-component instant-set aqueous coating compositions that provide coating films having good film quality despite a rapid film build and set. The compositions comprise, as Component I, a film-forming aqueous anionically stabilized polymer composition, such as an elastomeric acrylic or vinyl polymer, and one or more surfactants; and, as Component II, a polycation tolerant mixture of polycation, an aqueous polymer composition, such as a film-forming acrylic emulsion polymer, and a nonionic or ethoxylated anionic surfactant having an average of 7 or more or, preferably, 9 or more ethylene oxide groups per molecule. Component I can be an elastomeric roof coating composition. The compositions can be co-sprayed to form coatings, e.g. roof coatings.
C09D 133/06 - Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
C09D 133/26 - Homopolymers or copolymers of acrylamide or methacrylamide
B05D 1/34 - Applying different liquids or other fluent materials simultaneously
A skin cleansing formulation is provided, comprising: a dermatologically acceptable vehicle; a dermatologically acceptable oil; and a deposition aid polymer, wherein the deposition aid polymer is a cationic dextran polymer, comprising a dextran polymer functionalized with quaternary ammonium groups; wherein the deposition aid polymer enhances the deposition of the dermatologically acceptable oil from the skin cleansing formulation onto mammalian skin.
A fabric care composition is provided including water; a cleaning surfactant; a fabric softening silicone; and a deposition aid polymer, wherein the deposition aid polymer is a dextran polymer functionalized with quaternary ammonium moieties; wherein the deposition aid polymer enhances deposition of the fabric softening silicone from the fabric care composition onto a fabric.
The present invention is a composition comprising an aqueous dispersion of copolymer particles comprising structural units of a) an acrylate monomer; b) an acid monomer; and c) a siloxane-acrylate monomer of formula I:
The present invention is a composition comprising an aqueous dispersion of copolymer particles comprising structural units of a) an acrylate monomer; b) an acid monomer; and c) a siloxane-acrylate monomer of formula I:
The present invention is a composition comprising an aqueous dispersion of copolymer particles comprising structural units of a) an acrylate monomer; b) an acid monomer; and c) a siloxane-acrylate monomer of formula I:
where R, R1, R2, Y and x are defined herein. The composition, which also comprises a nonionic and anionic surfactant as described herein, is useful in a variety of applications ranging from architectural coatings to personal care products.
C08F 230/08 - Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium, or a metal containing a metal containing silicon
C08F 2/30 - Emulsion polymerisation with the aid of emulsifying agents non-ionic
C08F 2/26 - Emulsion polymerisation with the aid of emulsifying agents anionic
A hair care formulation is provided, comprising: a dermatologically acceptable vehicle; a dermatologically acceptable silicone; and a deposition aid polymer, wherein the deposition aid polymer is a branched chain cationic dextran polymer, comprising a dextran polymer functionalized with quaternary ammonium groups; wherein the dextran polymer has a weight average molecular weight of 100,000 to 650,000 Daltons; and wherein the deposition aid polymer enhances deposition of silicone from the hair care formulation onto mammalian hair.
A polymeric composition includes 10 wt % to 80 wt % of a silane-grafted ethylene polymer based on a total weight of the polymeric composition. The silane-grafted ethylene polymer has a silane content of 0.40 mol % to 1.50 mol % based on a total moles of the silane-grafted ethylene polymer and the ethylene polymer used to make the silane-grafted ethylene polymer has a polar comonomer content of less than 15 wt % based on a total weight of the ethylene polymer. The polymeric composition also includes 10 wt % to 80 wt % of a flame-retardant filler based on a total weight of the polymeric composition.
H01B 3/44 - Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances waxes acrylic resins
H01B 7/295 - Protection against damage caused by external factors, e.g. sheaths or armouring by extremes of temperature or by flame using material resistant to flame
A hair cleanser is provided, comprising: a dermatologically acceptable vehicle; a dermatologically acceptable hair care cleansing surfactant; a dermatologically acceptable silicone; and a deposition aid polymer, wherein the deposition aid polymer is a dextran polymer crosslinked with a dextran crosslinking agent of formula (I)
A hair cleanser is provided, comprising: a dermatologically acceptable vehicle; a dermatologically acceptable hair care cleansing surfactant; a dermatologically acceptable silicone; and a deposition aid polymer, wherein the deposition aid polymer is a dextran polymer crosslinked with a dextran crosslinking agent of formula (I)
A hair cleanser is provided, comprising: a dermatologically acceptable vehicle; a dermatologically acceptable hair care cleansing surfactant; a dermatologically acceptable silicone; and a deposition aid polymer, wherein the deposition aid polymer is a dextran polymer crosslinked with a dextran crosslinking agent of formula (I)
wherein X is a halogen; wherein each R1 is independently selected from a substituted or unsubstituted C1-6 alkyl group; wherein each R2 is independently selected from the group consisting of a C1-6 alkanediyl group; wherein Y is a divalent bridging group; and wherein the deposition aid polymer enhances deposition of the dermatologically acceptable silicone from the hair cleanser onto mammalian hair.
A61K 8/892 - Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a hydroxy group, e.g. dimethiconol
A liquid laundry detergent formulation is provided, comprising: a liquid carrier; a cleaning surfactant; and a cleaning booster, wherein the cleaning booster is of Formula (I)
A liquid laundry detergent formulation is provided, comprising: a liquid carrier; a cleaning surfactant; and a cleaning booster, wherein the cleaning booster is of Formula (I)
A liquid laundry detergent formulation is provided, comprising: a liquid carrier; a cleaning surfactant; and a cleaning booster, wherein the cleaning booster is of Formula (I)
wherein x is 3 to 10; wherein y is 5 to 20; wherein z is 5 to 30; wherein x+y+z≥18;
wherein x≠z; wherein each R is a C7-9 alkyl group and wherein ≥75 wt % of the R groups are branched.
A game ball including a leather cover secured about a solid core, wherein the leather cover includes an inner surface contacting the solid core and an opposing outer surface and wherein the game ball is characterized by including polyacrylate particles dispersed on but not encased about the outer surface of the leather cover.
The present invention relates to a composition comprising an aqueous dispersion of a thermosettable compound and polymer particles functionalized with aminoalkyl ester groups. The composition is useful as a two-component waterborne curing system and is effective in providing corrosion and blister resistance in industrial coatings applications.
The present invention provides an aqueous polymer dispersion and an aqueous coating composition comprising such aqueous polymer dispersion and providing coatings with improved early water blister resistance as well as satisfactory water streaking resistance and good durability properties.
The present invention relates to a composition comprising an aqueous dispersion of multiphase polymer particles comprising first polymer particles having a Tg of less than 30° C. and second polymer particles having a Tg in the range of from 100° C. to 110° C., wherein the second polymer particles are phase separated from and occluded within the first polymer particles; wherein the number average molecular weight (Mn) of the multiphase polymer particles is in the range of from 9,000 to 25,000 g/mole; and wherein the second polymer particles comprise at least 95 weight percent methyl methacrylate. The composition of the present invention is useful in a formulation that can be used to prepare a water-resistant blister free LASD coating with little or no surface defects.
C08G 18/12 - Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
B32B 15/04 - Layered products essentially comprising metal comprising metal as the main or only constituent of a layer, next to another layer of a specific substance
C09J 153/02 - Vinyl aromatic monomers and conjugated dienes
The present invention relates to a method for preparing ureido methacrylate comprising the step of contacting, in the presence zinc acetylacetonate (Zn(acac)2) and a radical inhibitor, methyl methacrylate with 1-(2-hydroxyethyl)imidazoline-2-one to form ureido methacrylate. The method provides an efficient and environmentally friendly way of making a key monomer used in the synthesis of acrylic latexes.
The present invention relates to a process for preparing an aqueous dispersion of multiphase occluded polymer particles comprising the steps of a) contacting, under emulsion polymerization conditions, first monomers and a chain transfer agent to form an aqueous dispersion of first polymer particles having a Tg in the range of from −30° C. to 30° C.; then b) contacting the aqueous dispersion of first polymer particles with a second monomer under emulsion polymerization conditions to form an aqueous dispersion of second polymer particles occluded within the first polymer particles, wherein the first monomers a phosphorus acid monomer or a salt thereof; and the second monomer comprises at least 90 weight percent methyl methacrylate. The aqueous dispersion of occluded polymer particles arising from the process of the present invention is useful in a formulation that can be used to prepare a water-resistant blister free LASD coating.
C08F 220/18 - Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
C08F 230/02 - Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium, or a metal containing phosphorus
