Liquid radiation curable compositions are disclosed which are suitable for hybrid (i.e. cationic and free-radical) polymerization when processed via additive fabrication equipment utilizing sources of actinic radiation with peak spectral intensities in the UV/vis region. According to one aspect, the compositions possess a first photoinitiator that is an iodonium salt of a non-fluorinated borate anion. According to another aspect, the composition is substantially devoid of a Norrish Type I and/or Type II photoinitiator. Also disclosed are methods of creating three-dimensional parts via additive fabrication processes utilizing sources of actinic radiation with peak spectral intensities in the UV/vis region employing liquid radiation curable compositions suitable for hybrid polymerization, and the parts cured therefrom.
C08F 2/50 - Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
B29C 64/129 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask
A method includes: accessing a part model comprising a three-dimensional representation of a part; accessing a material profile relating exposure energy and three-dimensional polymerization geometry of a material selected for the part; segmenting the part model into a set of model layers; detecting a first upward-facing surface in the part model; defining a first model volume in a first model layer, adjacent the first upward-facing surface, and fully contained within the part model; based on the material profile, calculating a first exposure energy predicted to yield a first three-dimensional polymerization geometry approximating a first contour of the first upward-facing surface when projected onto the material during a build; populating a first print image with the first exposure energy in a first image area corresponding to the first model volume in the first model layer; and storing the first print image in a print file for the part.
G06F 30/17 - Mechanical parametric or variational design
B22F 12/00 - Apparatus or devices specially adapted for additive manufacturing; Auxiliary means for additive manufacturing; Combinations of additive manufacturing apparatus or devices with other processing apparatus or devices
B29C 64/393 - Data acquisition or data processing for additive manufacturing for controlling or regulating additive manufacturing processes
A method of printing a multi-material part in a layer-wise manner with an extrusion-based 3D printer includes providing a sliced digital model of a multi-material part and determining a number of materials in each of the slices of the digital mode. The method includes utilizing a digital model of a purge tower having N subdivisions having a closed geometry, wherein N is the number of print heads needed to print the part that is greater than or equal to three, each adjacent subdivision contact one another along an interface and assigning each print head to one subdivision and to tool paths forming the one subdivision in each layer. The method includes reassigning the assigned subdivision within the purge tower of an inactive print head in a layer to a print head that is active in the layer of the multi-material part.
B29C 64/386 - Data acquisition or data processing for additive manufacturing
B29C 64/118 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using filamentary material being melted, e.g. fused deposition modelling [FDM]
Matrix-filled liquid radiation curable resin compositions for additive fabrication are described and claimed. Such resins include a cationically polymerizable component that is an aliphatic epoxide, a multifunctional (meth)acrylate component, a cationic photoinitiator, a free-radical photo initiator, and a matrix of inorganic fillers, wherein the matrix further constitutes prescribed ratios of at least one microparticle constituent and at least one nanoparticle constituent. Also described and claimed is a process for using the matrix-filled liquid radiation curable resins for additive fabrication to create three dimensional parts, and the three-dimensional parts made from the liquid radiation curable resins for additive fabrication.
B29C 64/135 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask the energy source being concentrated, e.g. scanning lasers or focused light sources
B33Y 70/10 - Composites of different types of material, e.g. mixtures of ceramics and polymers or mixtures of metals and biomaterials
C08F 2/50 - Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
C08L 33/10 - Homopolymers or copolymers of methacrylic acid esters
G03F 7/00 - Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printed surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
A 3D printer includes a gantry configured to move in a plane substantially parallel to a x-y build plane and a print head configured to extrude molten material to print a 3D part in a layer-by-layer process. The 3D printer includes a platen configured to support the part being printed in the layer by layer process and positionable with a primary Z positioner along a z-axis substantially normal to the x-y build plane. The 3D printer includes a local Z positioner moved by the gantry, the local Z positioner comprising a linear motor configured to move the print head in the z-direction and having an operable range of motion extending from a nominal build position at which a nozzle of the print head is positioned in the x-y build plane to a raised position above the x-y build plane.
A photo-curable composition can include a photo-curable resin and a photoinitiator. The photo-curable composition can typically include a (meth)acrylate-terminated prepolymer, a second prepolymer, and a reactive diluent.
C08F 2/50 - Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
B29C 64/129 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask
C08F 220/20 - Esters of polyhydric alcohols or phenols
C08F 283/00 - Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass
C08G 18/12 - Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
A photo-curable composition can include a photo-curable resin and a photoinitiator. The photo-curable composition can typically include a (meth)acrylate-terminated prepolymer, a second prepolymer, and a reactive diluent.
A method includes providing values for a set of tunable build parameters (208) corresponding to a print job specification to a user interface, and in response to user modification or selection of the tunable build parameters (208), computing values for a set of additional build parameters (214). A data package (216,222) is created based on the values for the tunable build parameters (208) and the set of additional build parameters (214) and data files are then sent to one or more 3D printers (224,226) and one or more slicing programs (218, 220).
The present disclosure is directed to pulverulent thermoplastic polymer blends comminuted to a particle size of less than 300 μm. The pulverulent thermoplastic polymer blends can include a first thermoplastic polyurethane and a second thermoplastic polyurethane at a weight ratio of from about 90:10 to about 30:70 first thermoplastic polyurethane to second thermoplastic polyurethane. The first thermoplastic polyurethane can include a reaction product of a first reaction mixture consisting of or consisting essentially of an aliphatic diisocyanate having a number average molecular weight of from 140 g/mol to 170 g/mol and an aliphatic diol having a number average molecular weight of from 62 g/mol to 120 g/mol. The second thermoplastic polyurethane can include a reaction product of a second reaction mixture comprising a polyisocyanate, an isocyanate-reactive component having a number average molecular weight of from 500 g/mol to 10,000 g/mol, and a chain extender having a number average molecular weight of from 60 g/mol to 450 g/mol.
A method for 3D printing a part in a layer-wise manner includes providing a pool of polymerizable liquid in a vessel over a build window and positioning a downward-facing build platform in the pool, thereby defining a build region above the build window. The method includes selectively curing a volume of polymerizable liquid in the build region by imparting electromagnetic radiation through the build window to form a printed layer of the part adhered to the build platform and scanning at least a portion of the build window with monochromatic, polarized light along a plane of incidence. The method includes measuring a change in intensity and polarity of the light to obtain information about the printed layer. The method includes raising the build platform to a height of a next layer to be printed and modifying the electromagnetic energy imparted into the next layer based upon the obtained information to print a next layer. The imparting, scanning, measuring, raising and modifying steps are repeated until the part is printed.
B33Y 50/00 - Data acquisition or data processing for additive manufacturing
B29C 64/129 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask
13.
TETHERED SPOOL ASSEMBLY AND METHODS OF USE THEREOF
A consumable assembly for a 3D printer includes a spool carrying wound filament. The spool is configured to be installed into a spool cabinet to maintain the filament in a controlled environment. A filament key fob that carries a spool chip programmed with identification data for the consumable assembly is tethered to the spool. The filament key fob is configured to be received in a dock of the 3D printer outside of a controlled environment of a chamber of the spool cabinet while remaining tethered to the spool installed in the chamber of the spool cabinet.
B29C 64/255 - Enclosures for the building material, e.g. powder containers
B33Y 30/00 - ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING - Details thereof or accessories therefor
A consumable assembly for a 3D printer includes a spool carrying wound filament. A 3D printer includes a print head configured to receive filament material and a spool cabinet configured to have a filament spool positioned therein to provide a controlled environment for filament on the filament spool. A dock of the 3D printer is located outside of a chamber of the spool cabinet and is configured to receive a filament key fob, including a spool chip, of the filament spool to maintain the spool chip outside of the controlled environment of the chamber.
B29C 64/118 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using filamentary material being melted, e.g. fused deposition modelling [FDM]
B33Y 30/00 - ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING - Details thereof or accessories therefor
15.
TETHERED SPOOL ASSEMBLY AND METHODS OF USE THEREOF
A consumable assembly for a 3D printer (10) includes a spool (208,210) carrying wound filament (202). The spool is configured to be installed into a spool cabinet (52) to maintain the filament in a controlled environment. A filament key fob (204) that carries a spool chip programmed with identification data for the consumable assembly is tethered to the spool. The filament key fob is configured to be received in a dock (68) of the 3D printer outside of a controlled environment of a chamber (54) of the spool cabinet while remaining tethered to the spool installed in the chamber of the spool cabinet.
B29C 64/118 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using filamentary material being melted, e.g. fused deposition modelling [FDM]
B29C 64/259 - Enclosures for the building material, e.g. powder containers interchangeable
B29C 64/307 - Handling of material to be used in additive manufacturing
B33Y 30/00 - ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING - Details thereof or accessories therefor
B33Y 40/00 - Auxiliary operations or equipment, e.g. for material handling
16.
METHOD FOR CONTROLLING DIMENSIONAL TOLERANCES, SURFACE QUALITY, AND PRINT TIME IN 3D-PRINTED PARTS
A method for generating print images for additive manufacturing includes: accessing a part model; accessing a set of dimensional tolerances for the part model; and segmenting the part model into a set of model layers. The method also includes, and, for each model layer: detecting an edge in the model layer; assigning a dimensional tolerance to the edge; defining an outer exposure shell inset from the edge by an erosion distance inversely proportional to a width of the dimensional tolerance; defining an inner exposure shell inset from the outer exposure shell and scheduled for exposure separately from the outer exposure shell; defining an a outer exposure energy proportional to the width of the dimensional tolerance and assigned to the outer exposure shell; and defining an inner exposure energy greater than the outer exposure energy and assigned to the inner exposure shell.
G05B 19/4093 - Numerical control (NC), i.e. automatically operating machines, in particular machine tools, e.g. in a manufacturing environment, so as to execute positioning, movement or co-ordinated operations by means of programme data in numerical form characterised by part programming, e.g. entry of geometrical information as taken from a technical drawing, combining this with machining and material information to obtain control information, named part programme, for the NC machine
G06T 19/20 - Editing of 3D images, e.g. changing shapes or colours, aligning objects or positioning parts
36 - Financial, insurance and real estate services
Goods & Services
Providing extended warranties and extended warranty services on 3D printers; and providing pre-paid service and self-service plans and extended service and self-service plans on 3D printers
18.
(METH)ACRYLATE-FUNCTIONAL RADIATION CURABLE COMPOSITIONS FOR ADDITIVE FABRICATION
Described herein are thermoset compositions and kits of compositions suitable for use in additive fabrication processes including specified concentrations of reactive compounds including urethane-(meth)acrylate compounds, monofunctional diluent monomers, and methacrylate-functional compounds having 1.5 polymerizable groups or more. Also described and claimed are methods of creating three-dimensional parts via additive fabrication processes utilizing the compositions elsewhere herein described and claimed, as well as the articles cured therefrom.
C08G 18/12 - Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
C08G 18/04 - Polymeric products of isocyanates or isothiocyanates with vinyl compounds
19.
USE OF AN ELASTIC POLYMER FOR PRODUCTION OF A POROUS BODY IN AN ADDITIVE MANUFACTURING METHOD
It is a feature of a use of an elastic polymer for production of a porous body (in an additive manufacturing method that the porous body comprises a three-dimensional network of node points joined to one another by struts, and a void volume present between the struts, where the struts have an average length of ≥200 μm to ≤50 mm and the struts (100) have an average thickness of ≥100 μm to ≤5 mm. The polymer here is an elastomer selected from the following group: thermoset polyurethane elastomers (PUR), thermoplastic copolyamides (TPA), thermoplastic copolyesters (TPC), thermoplastic olefin-based elastomers (TPO), styrene block copolymers (TPS), thermoplastic urethane-based elastomers (TPU), crosslinked thermoplastic olefin-based elastomers (TPV), thermoplastic polyvinyl chloride-based elastomers (PVC), thermoplastic silicone-based elastomers and a combination of at least two of these elastomers.
A method of printing a hollow part with a robotic additive manufacturing system includes extruding thermoplastic material onto a build platform movable in at least two degrees of freedom in a helical pattern along a continuous 3D tool path with an extruder mounted on a robotic arm, to thereby print a hollow member having a length and a diameter. The method includes orienting the hollow member during printing by moving the build platform based on a geometry of the hollow member wherein the movement of the build platform and the movement of the robotic arm are synchronized to print the part without support structures.
B33Y 30/00 - ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING - Details thereof or accessories therefor
B25J 9/04 - Programme-controlled manipulators characterised by movement of the arms, e.g. cartesian co-ordinate type by rotating at least one arm, excluding the head movement itself, e.g. cylindrical co-ordinate type or polar co-ordinate type
B29C 64/118 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using filamentary material being melted, e.g. fused deposition modelling [FDM]
An extrusion-based 3D printer configured to print 3D parts in a layer-by-layer manner includes a heated build chamber, a build platen within the chamber and at least one print head configured to extrude material onto the build platen or previously extruded material wherein the at least one print head is configured to move in a print plane. The 3D printer includes at least one air intake and exhaust system that includes ductwork having an inlet configured to intake air from the build chamber and an outlet configured to exhaust air into the build chamber proximate the build plane, a fan proximate the inlet and configured to draw air into the ductwork through the inlet and propel the air towards the outlet, a heater proximate the outlet, the heater configured to heat the air as the air passes the heater and a perforated diffuser plate between the fan and the heater.
B33Y 30/00 - ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING - Details thereof or accessories therefor
A method of forming a three-dimensional object comprises the steps of forming a layer of a particulate composition, selectively depositing a liquid composition onto the layer of the particulate composition in accordance with computer data corresponding to the shape of at least a portion of a three-dimensional object, and repeating the steps a plurality of times to form a three-dimensional object. The particulate composition comprises a plurality of first particles that comprise a resin component comprising a first resin, the first resin comprising a first resin polymerizable group. Either or both of the particulate composition and the liquid composition comprise an initiator capable of initiating polymerization of at least the first resin. At least the first resin undergoes melting and polymerization in a plurality of the locations where the liquid composition has been selectively deposited.
B29C 64/165 - Processes of additive manufacturing using a combination of solid and fluid materials, e.g. a powder selectively bound by a liquid binder, catalyst, inhibitor or energy absorber
C08G 18/42 - Polycondensates having carboxylic or carbonic ester groups in the main chain
C08G 18/67 - Unsaturated compounds having active hydrogen
C08F 220/18 - Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
B29C 64/393 - Data acquisition or data processing for additive manufacturing for controlling or regulating additive manufacturing processes
C08F 216/12 - Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical by an ether radical
A layer-by layer method for additive manufacturing that includes: photocuring a first volume of resin to form a layer of a build at an upper surface of a separation membrane laminated over a build window; injecting a fluid into an interstitial region between the separation membrane and the build window; retracting the build from the build window; evacuating the fluid from the interstitial region; and photocuring a second volume of liquid resin to form a subsequent layer of the build between an upper surface of a separation membrane and the previous layer of the build.
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
A water dispersible sulfo-polyamide is configured as a filament for use as an extrudable support material in the additive manufacture of a part comprising a non water dispersible polymer. The water dispersible sulfo-polyamide is a reaction product of a sulfo monomer, the water dispersible sulfo-polymer being dispersible in water resulting in separation of the water dispersible polymer from the part comprising the non water dispersible polymer.
B29C 64/40 - Structures for supporting 3D objects during manufacture and intended to be sacrificed after completion thereof
B33Y 30/00 - ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING - Details thereof or accessories therefor
G03G 15/22 - Apparatus for electrographic processes using a charge pattern involving the combination of more than one step according to groups
G03G 15/16 - Apparatus for electrographic processes using a charge pattern for transferring a pattern to a second base of a toner pattern, e.g. a powder pattern
B29C 64/106 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
C08G 18/38 - Low-molecular-weight compounds having hetero atoms other than oxygen
An extruder or other similar tool head of a three-dimensional printer is slidably mounted along a feedpath of build material so that the extruder can move into and out of contact with a build surface according to whether build material is being extruded. The extruder may be spring-biased against the forward feedpath so that the extruder remains above the build surface in the absence of applied forces, and then moves downward into a position for extrusion when build material is fed into the extruder. In another aspect, modular tool heads are disclosed that can be automatically coupled to and removed from the three-dimensional printer by a suitable robotics system. A tool crib may be provided to store multiple tool heads while not in use.
B29C 64/112 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using individual droplets, e.g. from jetting heads
B29C 48/02 - Small extruding apparatus, e.g. handheld, toy or laboratory extruders
B29C 48/25 - Component parts, details or accessories; Auxiliary operations
B29C 48/80 - Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling at the plasticising zone, e.g. by heating cylinders
B29C 48/285 - Feeding the extrusion material to the extruder
B33Y 40/00 - Auxiliary operations or equipment, e.g. for material handling
B29C 64/118 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using filamentary material being melted, e.g. fused deposition modelling [FDM]
B33Y 30/00 - ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING - Details thereof or accessories therefor
26.
INDUCTION SENSING METHOD FOR LOCATING CENTER OF METALLIC NOZZLE TIP
An induction sensing method for identifying the center of a tip surface of a nozzle of print head of a 3D printer includes providing an eddy current sensor in a fixed position and providing a metal nozzle with a tip orifice in a main body and a tip surface about the tip orifice. The method includes moving the metal nozzle over the eddy current sensor in a predetermined motion path above the eddy current sensor while the eddy current sensor remains stationary and samples the magnitude of inductance in a generated inductive field, thereby generating a curve representing the inductive field. The method includes identifying a maximum amplitude of the curve to identify the center of the tip surface.
G01D 5/20 - Mechanical means for transferring the output of a sensing member; Means for converting the output of a sensing member to another variable where the form or nature of the sensing member does not constrain the means for converting; Transducers not specially adapted for a specific variable using electric or magnetic means influencing the magnitude of a current or voltage by varying inductance, e.g. by a movable armature
B33Y 30/00 - ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING - Details thereof or accessories therefor
B33Y 50/00 - Data acquisition or data processing for additive manufacturing
B22F 12/90 - Means for process control, e.g. cameras or sensors
27.
METHOD FOR POLYMERIZING SUPERFICIAL FEATURES IN 3D-PRINTED PARTS
A method includes: accessing a part model comprising a three-dimensional representation of a part; accessing a material profile relating exposure energy and three-dimensional polymerization geometry of a material selected for the part; segmenting the part model into a set of model layers; detecting a first upward-facing surface in the part model; defining a first model volume in a first model layer, adjacent the first upward-facing surface, and fully contained within the part model; based on the material profile, calculating a first exposure energy predicted to yield a first three-dimensional polymerization geometry approximating a first contour of the first upward-facing surface when projected onto the material during a build; populating a first print image with the first exposure energy in a first image area corresponding to the first model volume in the first model layer; and storing the first print image in a print file for the part.
B29C 64/393 - Data acquisition or data processing for additive manufacturing for controlling or regulating additive manufacturing processes
B33Y 50/02 - Data acquisition or data processing for additive manufacturing for controlling or regulating additive manufacturing processes
B22F 12/00 - Apparatus or devices specially adapted for additive manufacturing; Auxiliary means for additive manufacturing; Combinations of additive manufacturing apparatus or devices with other processing apparatus or devices
A method includes: accessing a part model comprising a three-dimensional representation of a part; accessing a material profile relating exposure energy and three-dimensional polymerization geometry of a material selected for the part; segmenting the part model into a set of model layers; detecting a first upward-facing surface in the part model; defining a first model volume in a first model layer, adjacent the first upward-facing surface, and fully contained within the part model; based on the material profile, calculating a first exposure energy predicted to yield a first three-dimensional polymerization geometry approximating a first contour of the first upward-facing surface when projected onto the material during a build; populating a first print image with the first exposure energy in a first image area corresponding to the first model volume in the first model layer; and storing the first print image in a print file for the part.
G06F 30/17 - Mechanical parametric or variational design
G06F 113/10 - Additive manufacturing, e.g. 3D printing
B29C 64/393 - Data acquisition or data processing for additive manufacturing for controlling or regulating additive manufacturing processes
B33Y 50/02 - Data acquisition or data processing for additive manufacturing for controlling or regulating additive manufacturing processes
B22F 12/00 - Apparatus or devices specially adapted for additive manufacturing; Auxiliary means for additive manufacturing; Combinations of additive manufacturing apparatus or devices with other processing apparatus or devices
The hardware and software properties of a three-dimensional printer can be queried and applied to select suitable directly printable models for the printer, or to identify situations where a new machine-ready model must be generated. The properties may be any properties relevant to fabrication including, e.g., physical properties of the printer, printer firmware, user settings, hardware configurations, and so forth. A printer may respond to configuration queries with a dictionary of capabilities or properties, and this dictionary may be used to select suitable models, or determine when a new model must be created. Similarly, when a printable model is sent to the printer, metadata for the printable model may be compared to printer properties in the dictionary to ensure that the model can be fabricated by the printer.
A method of moving a print head between a plurality of partitioned chambers in a 3D printer includes providing the 3D printer having a thermal barrier having an area defined by a length and width, wherein a print head nozzle can be positioned through the thermal barrier along the width or the length and at least two partitioned chambers below the area of the thermal barrier, wherein a first chamber comprises a printing chamber and a second chamber comprises a chamber providing another functionality. The method includes raising the print head in a z direction from the second chamber to above the thermal barrier and moving the print head in a x-y direction from above the second chamber over the partition to a location above the first chamber. The method also includes lowering the print head in the z direction and into the first chamber such that an extrusion port of a nozzle of the print head is proximate a x-y print plane.
An induction sensing method for identifying the center of a tip surface of a nozzle (604) of print head of a 3D printer includes providing an eddy current sensor (610) in a fixed position and providing a metal nozzle (604) with a tip orifice in a main body and a tip surface about the tip orifice. The method includes moving the metal nozzle (604) over the eddy current sensor (610) in a predetermined motion path above the eddy current sensor (610) while the eddy current sensor remains stationary and samples the magnitude of inductance in a generated inductive field, thereby generating a curve representing the inductive field. The method includes identifying a maximum amplitude of the curve to identify the center of the tip surface.
G01B 7/00 - Measuring arrangements characterised by the use of electric or magnetic techniques
B29C 64/236 - Driving means for motion in a direction within the plane of a layer
B29C 64/393 - Data acquisition or data processing for additive manufacturing for controlling or regulating additive manufacturing processes
B33Y 50/02 - Data acquisition or data processing for additive manufacturing for controlling or regulating additive manufacturing processes
B29C 64/118 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using filamentary material being melted, e.g. fused deposition modelling [FDM]
32.
3D PRINTER WITH A PLURALITY OF PARTITIONED CHAMBERS
A 3D printer includes a gantry configured to move in a plane and in a direction substantially normal to the plane and at least one print head carried by the gantry, the at least on print head comprising an extrusion nozzle at a bottom end. The 3D printer includes a plurality of partitioned chambers accessible by the at least one print head, each of the partitioned chambers having an upper edge defining an opening into each of the plurality of chambers, and a platen within a first chamber of the plurality of chambers, the platen configured to receive material from the print head to print the 3D part. The at least one print head is configured to be moved between each of the plurality of partitioned chambers by raising the print head in the direction substantially normal to the plane such that the extrusion nozzle is above the upper edge of the plurality of chambers, moving the print head in the plane from a first location above the first chamber of the plurality of partitioned chambers to a second location above a second chamber of the plurality of partitioned chambers and lowering the at least one print head into the second chamber.
B29C 64/236 - Driving means for motion in a direction within the plane of a layer
B33Y 30/00 - ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING - Details thereof or accessories therefor
33.
BRAIDED COMINGLED TOW FILAMENT FOR USE IN 3D PRINTING
A feedstock configured for use in an extruder in an additive manufacturing system is configured as a braided comingled tow filament. A method of producing the braided comingled tow filament includes providing a bundle of comingled tow material having a fiber count ranging from about 1,000 fibers to about 25,000 fibers having thermoplastic fibers comingled therewith, wherein the tow material in the filament ranges from about 50 to 75 volume percent and the volume percent of the thermoplastic material ranges from about 25 volume percent to about 50 volume percent. The method includes dividing the length of comingled tow material into sections, twisting each section into a strand to form a plurality of strands of twisted tow material, and braiding together the strands.
B29C 64/118 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using filamentary material being melted, e.g. fused deposition modelling [FDM]
B29C 64/307 - Handling of material to be used in additive manufacturing
A method for calibrating a 3D printer includes the steps of providing information obtained in a factory calibration indicating a center of an inner diameter of a tip orifice in a metal extrusion nozzle and a center of a tip surface for the nozzle and inductively sensing the nozzle with an eddy current sensor when secured to a print head on a gantry or robotic arm of the 3D printer to identify a sensed location of the center of the tip surface of the nozzle. The method includes determining a location of the center of the inner diameter of the tip orifice on the nozzle on the print head and utilizing the provided information to locate the center of the inner diameter of the tip orifice.
A photo-curable composition can include a photo-curable resin and a photoinitiator. The photo-curable composition can typically have a shear viscosity of less than 1 Pa·s at 100 °C at a shear rate of 50 s-1 and can typically include a first prepolymer, a second prepolymer, and a reactive diluent.
A method of additive manufacturing comprises operating an additive manufacturing system for fabricating a multiplicity of objects, while acquiring a set of images during fabrication of each of the objects. For each object, a respective set of images is analyzed to identify fabrication irregularities, and a fabrication score is generated based on the irregularities. The multiplicity of objects is clustered according to the fabrication scores into at least two clusters.
B07C 5/342 - Sorting according to other particular properties according to optical properties, e.g. colour
B29C 64/386 - Data acquisition or data processing for additive manufacturing
B29C 64/118 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using filamentary material being melted, e.g. fused deposition modelling [FDM]
37.
METHOD OF ANALYZING AND UTILIZING SURFACE TOPOGRAPHY FOR TARGETED LOCAL THERMAL MANAGEMENT IN ADDITIVE MANUFACTURING SYSTEMS
A method for 3D printing a part with an additive manufacturing system includes printing a first portion (302)(308) of a part (342) in a layerwise manner and analyzing a topology (344) of the first portion (302)(308) of the part. The method includes determining a tool path for printing a second portion (306) of the part on a surface of the first portion (302) of the part (346), and pre-heating the first portion (302)(308) of the part along the tool path as a function of the topological analysis of the first portion of the part (348). The method includes printing the second portion (306) of the part along the tool path (350).
B29C 64/118 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using filamentary material being melted, e.g. fused deposition modelling [FDM]
B29C 64/188 - Processes of additive manufacturing involving additional operations performed on the added layers, e.g. smoothing, grinding or thickness control
B29C 64/268 - Arrangements for irradiation using electron beams [EB]
B33Y 30/00 - ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING - Details thereof or accessories therefor
B33Y 40/00 - Auxiliary operations or equipment, e.g. for material handling
B33Y 50/02 - Data acquisition or data processing for additive manufacturing for controlling or regulating additive manufacturing processes
B29C 64/194 - Processes of additive manufacturing involving additional operations performed on the added layers, e.g. smoothing, grinding or thickness control during lay-up
A low pull force system for feeding a filament along a feed path from a source to a liquefier in a 3D printer includes a low compressive force loading drive for advancing filament from the source, a feed drive for advancing filament into the liquefier, and an in-line accumulator comprising a telescoping joint positioned in the feed path between the loading drive and the feed drive. When the telescoping joint is in a contracted position, the loading drive activates to feed filament into the feed path at a rate faster than a rate at which the feed drive advances filament into the liquefier, causing the telescoping joint to expand and accrue a slack of filament in the feed path. When the telescoping joint reaches an extended position, the loading drive deactivates while the feed drive continues to advance filament into the liquefier, and the slack of filament is consumed.
B29C 64/118 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using filamentary material being melted, e.g. fused deposition modelling [FDM]
B33Y 30/00 - ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING - Details thereof or accessories therefor
B29C 64/393 - Data acquisition or data processing for additive manufacturing for controlling or regulating additive manufacturing processes
Thermoset compositions and methods for forming three-dimensional articles via an additive fabrication process, and articles made therefrom are disclosed herein. In an embodiment, a composition comprises a first network-forming component comprising a first oligomer comprising a backbone and having at least 2 polymerizable groups, one or more first network monomers, and a first network initiator. The backbone of the first oligomer comprises a polyepoxide based on Bisphenol A, F, or S, a polyepoxide based on hydrogenated Bisphenol A, F, or S, a polycarbonate, or a polyimide. The composition may further comprise a second network-forming component.
C08F 2/46 - Polymerisation initiated by wave energy or particle radiation
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
C08G 61/04 - Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
C09D 11/101 - Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
C09D 11/102 - Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
C09D 11/107 - Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
B29C 64/153 - Processes of additive manufacturing using only solid materials using layers of powder being selectively joined, e.g. by selective laser sintering or melting
B33Y 70/10 - Composites of different types of material, e.g. mixtures of ceramics and polymers or mixtures of metals and biomaterials
G03F 7/038 - Macromolecular compounds which are rendered insoluble or differentially wettable
41.
THERMOSETTING COMPOSITIONS AND FORMING THREE-DIMENSIONALOBJECTS THEREFROM
Thermoset compositions and methods for forming three-dimensional articles via an additive fabrication process, and articles made therefrom are disclosed herein. In an embodiment, a composition comprises a first network-forming component comprising a TPA-based polyester comprising a backbone and having at least 2 polymerizable groups, one or more first network monomers, and a first network initiator. The backbone of the TPA-based polyester comprises the reaction product of a terephthalic acid and a polyol. The composition may further comprise a second network-forming component.
C09D 11/101 - Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
B33Y 70/00 - Materials specially adapted for additive manufacturing
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
C09D 11/102 - Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
C09D 11/107 - Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
A method for additive manufacturing includes: at a build tray arranged over a build window and containing a resin reservoir of a resin, heating the resin reservoir toward a target bulk resin temperature less than a heat deflection temperature of the resin in a photocured state; at a resin interface between a surface of the build window and the resin reservoir, heating an interface layer of the resin reservoir toward a target reaction temperature; and, in response to the resin reservoir exhibiting a first temperature proximal the target bulk resin temperature and to the interface layer exhibiting a second temperature proximal the target reaction temperature: at the resin interface, selectively photocuring a first volume of the resin to form a first layer of a build adhered to a build platform; and retracting the build platform away from the build window.
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
B29C 64/393 - Data acquisition or data processing for additive manufacturing for controlling or regulating additive manufacturing processes
B29C 64/135 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask the energy source being concentrated, e.g. scanning lasers or focused light sources
B33Y 50/02 - Data acquisition or data processing for additive manufacturing for controlling or regulating additive manufacturing processes
B29C 64/255 - Enclosures for the building material, e.g. powder containers
B29C 64/232 - Driving means for motion along the axis orthogonal to the plane of a layer
B29C 64/129 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask
B33Y 40/00 - Auxiliary operations or equipment, e.g. for material handling
B33Y 30/00 - ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING - Details thereof or accessories therefor
43.
SYSTEM FOR WINDOW SEPARATION IN AN ADDITIVE MANUFACTURING PROCESS
An additive manufacturing system including a base assembly and a tray assembly. The base assembly includes a build window, substantially transparent to electromagnetic radiation; a projection system configured to project electromagnetic radiation toward an upper surface of the build window; and a tray seat arranged around a perimeter of the build window. The tray assembly is configured to engage with the base assembly in an engaged configuration and includes: a tray structure defining a registration feature configured to engage the tray seat to locate an aperture proximal to the upper surface of the build window in the engaged configuration; and a separation membrane that is configured to laminate across the upper surface of the build window in response to an evacuation of gas from an interstitial region and configured to separate from the build window in response to injection of gas into the interstitial region.
B33Y 30/00 - ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING - Details thereof or accessories therefor
B29C 64/255 - Enclosures for the building material, e.g. powder containers
B29C 64/135 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask the energy source being concentrated, e.g. scanning lasers or focused light sources
B29C 64/379 - Handling of additively manufactured objects, e.g. using robots
44.
Multiple axis robotic additive manufacturing system and methods
A multiple axis robotic additive manufacturing system includes a robotic arm movable in six degrees of freedom. The system includes a build platform movable in at least two degrees of freedom and independent of the movement of the robotic arm to position the part being built to counteract effects of gravity based upon part geometry. The system includes an extruder mounted at an end of the robotic arm. The extruder is configured to extrude at least part material with a plurality of flow rates, wherein movement of the robotic arm and the build platform are synchronized with the flow rate of the extruded material to build the 3D part.
B29C 64/118 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using filamentary material being melted, e.g. fused deposition modelling [FDM]
B33Y 30/00 - ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING - Details thereof or accessories therefor
B25J 9/04 - Programme-controlled manipulators characterised by movement of the arms, e.g. cartesian co-ordinate type by rotating at least one arm, excluding the head movement itself, e.g. cylindrical co-ordinate type or polar co-ordinate type
B29C 64/106 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
A 3D printer includes a gantry configured to move in a plane substantially parallel to a x-y build plane and a print head configured to extrude molten material to print a 3D part in a layer-by-layer process. The 3D printer includes a platen configured to support the part being printed in the layer by layer process and positionable with a primary Z positioner along a z-axis substantially normal to the x-y build plane. The 3D printer includes a local Z positioner moved by the gantry, the local Z positioner comprising a linear motor configured to move the print head in the z-direction and having an operable range of motion extending from a nominal build position at which a nozzle of the print head is positioned in the x-y build plane to a raised position above the x-y build plane.
B29C 64/236 - Driving means for motion in a direction within the plane of a layer
B33Y 30/00 - ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING - Details thereof or accessories therefor
B29C 64/118 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using filamentary material being melted, e.g. fused deposition modelling [FDM]
A 3D printer (10) includes a heated build chamber (16), a build platen (30) positioned within the heated build chamber (16), and a primary z-axis positioner (32) configured to move the build platen (30) in a z-direction within the heated build chamber (16). The 3D printer (10) also includes a tool chamber (18) positioned above the build chamber (16) and having an unheated, cooled, or room temperature environment. A thermal insulator (20) separates the build chamber (16) and the tool chamber (18). A print head carriage (26) of the 3D printer (10) is configured to engage one of the plurality of print heads and/or print head tools (24) stored in a tool rack (22) positioned within the tool chamber (18). The 3D printer (10) also includes a local Z positioner (72) configured to move the carriage (26) from a tool engagement z-height within the tool chamber (18), to a position where the engaged print head or print head tool (24) extends from the tool chamber (18) through the insulator (20) into the build chamber (16).
B29C 64/118 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using filamentary material being melted, e.g. fused deposition modelling [FDM]
B33Y 30/00 - ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING - Details thereof or accessories therefor
B29C 64/259 - Enclosures for the building material, e.g. powder containers interchangeable
B33Y 40/00 - Auxiliary operations or equipment, e.g. for material handling
A method for generating print images for additive manufacturing includes: accessing a part model; accessing a set of dimensional tolerances for the part model; and segmenting the part model into a set of model layers. The method also includes, and, for each model layer: detecting an edge in the model layer; assigning a dimensional tolerance to the edge; defining an outer exposure shell inset from the edge by an erosion distance inversely proportional to a width of the dimensional tolerance; defining an inner exposure shell inset from the outer exposure shell and scheduled for exposure separately from the outer exposure shell; defining an a outer exposure energy proportional to the width of the dimensional tolerance and assigned to the outer exposure shell; and defining an inner exposure energy greater than the outer exposure energy and assigned to the inner exposure shell.
A method for generating print images for additive manufacturing includes: accessing a part model; accessing a set of dimensional tolerances for the part model; and segmenting the part model into a set of model layers. The method also includes, and, for each model layer: detecting an edge in the model layer; assigning a dimensional tolerance to the edge; defining an outer exposure shell inset from the edge by an erosion distance inversely proportional to a width of the dimensional tolerance; defining an inner exposure shell inset from the outer exposure shell and scheduled for exposure separately from the outer exposure shell; defining an a outer exposure energy proportional to the width of the dimensional tolerance and assigned to the outer exposure shell; and defining an inner exposure energy greater than the outer exposure energy and assigned to the inner exposure shell.
G05B 19/4093 - Numerical control (NC), i.e. automatically operating machines, in particular machine tools, e.g. in a manufacturing environment, so as to execute positioning, movement or co-ordinated operations by means of programme data in numerical form characterised by part programming, e.g. entry of geometrical information as taken from a technical drawing, combining this with machining and material information to obtain control information, named part programme, for the NC machine
G06T 19/20 - Editing of 3D images, e.g. changing shapes or colours, aligning objects or positioning parts
G06T 7/73 - Determining position or orientation of objects or cameras using feature-based methods
B33Y 50/02 - Data acquisition or data processing for additive manufacturing for controlling or regulating additive manufacturing processes
B29C 64/393 - Data acquisition or data processing for additive manufacturing for controlling or regulating additive manufacturing processes
G06T 7/62 - Analysis of geometric attributes of area, perimeter, diameter or volume
B29C 64/135 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask the energy source being concentrated, e.g. scanning lasers or focused light sources
49.
ADDITIVE MANUFACTURING PROCESS USING A BUILDING MATERIAL HAVING A HIGH HARD SEGMENT CONTENT
A method for producing an object comprises the step of producing the object by means of an additive manufacturing process from a construction material. The construction material comprises a first polyurethane polymer which has: a weight percentage ratio of O to N of ≥2 to ≤2.5, determined by elementary analysis; a weight percentage ratio of N to C of ≥0.1 to ≤0.25, determined by elementary analysis; a full-width at half maximum of the melting peak of ≤20 K, determined by dynamic differential scanning calorimetry DSC (2nd heating at heating rate 20 k/min); and a difference between the melting temperature and the recrystallisation temperature of ≥5 K and ≤100 K, determined by dynamic differential scanning calorimetry DSC (2nd heating) at a heating and cooling rate of 20 K/min.
B33Y 70/00 - Materials specially adapted for additive manufacturing
B29C 64/118 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using filamentary material being melted, e.g. fused deposition modelling [FDM]
B29C 64/165 - Processes of additive manufacturing using a combination of solid and fluid materials, e.g. a powder selectively bound by a liquid binder, catalyst, inhibitor or energy absorber
Provided is a photopolymerizable composition comprising a blend of: a) from 40 wt. % to 70 wt. % of at least one urethane component; b) from 25 wt. % to 70 wt % of at least one monofunctional reactive diluent; c) from 0.1 wt. % to 5 wt. % of at least one initiator; and d) from 2 wt. % to 10 wt % of an amine-functional (meth)acrylate monomer. Also provided is a process of producing a photopolymerizable composition by blending these ingredients. Further provided is a process of producing a three-dimensional object, by depositing the photopolymerizable composition atop a carrier; depositing additional photopolymerizable composition atop a previously applied layer wherein the depositing of the photopolymerizable composition comprises introducing energy.
C08F 2/46 - Polymerisation initiated by wave energy or particle radiation
C08F 2/50 - Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
C08G 61/04 - Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
C08F 283/00 - Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass
B33Y 70/00 - Materials specially adapted for additive manufacturing
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
B29K 75/00 - Use of polyureas or polyurethanes as moulding material
The invention relates to a method for modifying an object comprising the step of: I) providing an object which is made at least partially of a construction material comprising a thermoplastic polyurethane. The method also comprises the following steps: II) contacting, at least in part, the construction material, for a first predetermined period of time, with a first liquid comprising ≥80% by weight, based on the total weight of the first liquid, of a polar aprotic solvent; III) contacting, for a second predetermined period of time, the areas of the construction material that were in contact with the liquid in step II) with a second liquid comprising ≥80% by weight, based on the total weight of the second liquid, of a polar protic solvent. Preferably, the first liquid is DMSO or acetone and the second liquid is water.
B29C 64/165 - Processes of additive manufacturing using a combination of solid and fluid materials, e.g. a powder selectively bound by a liquid binder, catalyst, inhibitor or energy absorber
B29C 64/268 - Arrangements for irradiation using electron beams [EB]
The present invention relates to a fire, smoke and toxicity retardant (FST) polyamide thermoplastic mass usable for 3D printing which comprises at least one non-halogenated organic flame retardant in combination with at least one particulate inorganic flame retardant. Moreover, the present invention refers to uses of such FST polyamide thermoplastic mass for 3D printing. The invention further relates to methods of preparing a three-dimensionally shaped product by means of 3D printing based on such FST polyamide thermoplastic mass.
B33Y 70/00 - Materials specially adapted for additive manufacturing
B29C 64/153 - Processes of additive manufacturing using only solid materials using layers of powder being selectively joined, e.g. by selective laser sintering or melting
B29C 64/118 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using filamentary material being melted, e.g. fused deposition modelling [FDM]
53.
METHOD FOR UNDERWATER PROCESSING OF WATER-DISPERSIBLE MATERIALS
A method of processing a water-dispersible, polymer-based material in a bath of a water-based solution includes providing a molten water-dispersible polymer material having monovalent cations. The water-dispersible polymer is introduced into a water bath comprising multivalent salt dissociated in the water bath into multivalent cations and anions. The water-dispersible polymer is retained within the water bath with the dissociated multivalent cations to quench the water-dispersible, polymer-based material while the monovalent cations proximate a surface of the water-dispersible polymer are exchanged with multivalent cations to form a barrier that temporarily resists dispersion of the water-dispersible, polymer-based material within the water bath. The method includes removing the water-dispersible polymer from water bath after the exchange step.
C08J 3/07 - Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media from polymer solutions
C08J 3/14 - Powdering or granulating by precipitation from solutions
B29C 48/80 - Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling at the plasticising zone, e.g. by heating cylinders
The present disclosure is directed to pulverulent thermoplastic polymer blends comminuted to a particle size of less than 300 μm. The pulverulent thermoplastic polymer blends can include a first thermoplastic polyurethane and a second thermoplastic polyurethane at a weight ratio of from about 90:10 to about 30:70 first thermoplastic polyurethane to second thermoplastic polyurethane. The first thermoplastic polyurethane can include a reaction product of a first reaction mixture consisting of or consisting essentially of an aliphatic diisocyanate having a number average molecular weight of from 140 g/mol to 170 g/mol and an aliphatic diol having a number average molecular weight of from 62 g/mol to 120 g/mol. The second thermoplastic polyurethane can include a reaction product of a second reaction mixture comprising a polyisocyanate, an isocyanate-reactive component having a number average molecular weight of from 500 g/mol to 10,000 g/mol, and a chain extender having a number average molecular weight of from 60 g/mol to 450 g/mol.
A build chamber for a 3D printer includes a heated build space in an interior of the build chamber and a thermal isolator configured to insulate 3D printer components from the heated build space. The thermal isolator includes a first baffle section and a second baffle section. Each of the first baffle section and the second baffle section includes an accordion-pleated panel having a length, a width, a first end and a second end, wherein the panel comprises a parallel alternating top folds and bottom folds along the width forming a series of pleats, and each pleat within the series being configured to expand and contract, and wherein the panel is constructed of a heat-resistant material. Each baffle section also includes support rods affixed to the accordion-pleated panel in parallel to the pleats and at intervals along the length of the panel, the support rods substantially spanning the width of the panel. Ends of the support rods rest on surfaces proximate a ceiling of the build chamber to support the first and second baffle sections wherein the support rods are configured to provide sufficient strength and rigidity to the panel to substantially prevent the panel from sagging or buckling as the panel is expanded and contracted along its length.
B33Y 40/00 - Auxiliary operations or equipment, e.g. for material handling
B33Y 30/00 - ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING - Details thereof or accessories therefor
A 3D printer includes a holding area holding material to be used to produce a part and at least one component for producing the part through layer-wise additive manufacturing. A data storage device in the 3D printer stores instructions for generating build parameter values, the instructions including empirically derived data, relationships, and/or equations. A processor in the 3D printer receives values for a public build parameter set and a category for the material wherein the category represents multiple different materials. The processor executes instructions to determine values for a private build parameter set that vary based on the properties of the material. The values for the private build parameter set are determined from the received values for the public build parameter set and the received category. The processor then uses the received values for the public build parameter set and the values for the private build parameter set to build the part.
G05B 19/4093 - Numerical control (NC), i.e. automatically operating machines, in particular machine tools, e.g. in a manufacturing environment, so as to execute positioning, movement or co-ordinated operations by means of programme data in numerical form characterised by part programming, e.g. entry of geometrical information as taken from a technical drawing, combining this with machining and material information to obtain control information, named part programme, for the NC machine
B33Y 50/00 - Data acquisition or data processing for additive manufacturing
57.
Liquid, hybrid UV/vis radiation curable resin compositions for additive fabrication
Liquid radiation curable compositions are disclosed which are suitable for hybrid (i.e. cationic and free-radical) polymerization when processed via additive fabrication equipment utilizing sources of actinic radiation with peak spectral intensities in the UV/vis region. According to one aspect, the compositions possess a first photoinitiator that is an iodonium salt of a non-fluorinated borate anion. According to another aspect, the composition is substantially devoid of a Norrish Type I and/or Type II photoinitiator. Also disclosed are methods of creating three-dimensional parts via additive fabrication processes utilizing sources of actinic radiation with peak spectral intensities in the UV/vis region employing liquid radiation curable compositions suitable for hybrid polymerization, and the parts cured therefrom.
C08F 2/46 - Polymerisation initiated by wave energy or particle radiation
C08F 2/50 - Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
C08G 61/04 - Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
B29C 64/129 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask
Radiation curable compositions for additive fabrication are described and claimed. Such compositions are particularly suited for investment casting applications, and include a cationically polymerizable component, a radically polymerizable component, a certain type of prescribed antimony-free, sulfonium salt-based cationic photoinitiator, and a free-radical photoinitiator. In other embodiments, the composition may also include a photosensitizer and/or a UV/absorber. Also described and claimed is a method for using a liquid radiation curable resin for additive fabrication with a certain type of prescribed antimony-free, sulfonium salt-based cationic photoinitiator and a certain type of prescribed photosensitizer in an investment casting process.
C08F 2/50 - Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
C08G 59/68 - Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups characterised by the catalysts used
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
Disclosed herein are expanding spinal fusion cage embodiments including an expandable cage assembly configured to expand from a collapsed state to an expanded state in an intervertebral space when inflated with a material. The assembly can include an inflatable section defining an interior volume configured to receive the material and expand the interior volume in response to a pressure from the received material to cause the expandable cage assembly to transition from the collapsed state to the expanded state, and a stabilization section configured to restrain the inflatable section during inflation.
Disclosed herein are expanding spinal fusion cage embodiments including an expandable cage assembly configured to expand from a collapsed state to an expanded state in an intervertebral space when inflated with a material. The assembly can include an inflatable section defining an interior volume configured to receive the material and expand the interior volume in response to a pressure from the received material to cause the expandable cage assembly to transition from the collapsed state to the expanded state, and a stabilization section configured to restrain the inflatable section during inflation.
A61F 2/44 - Joints for the spine, e.g. vertebrae, spinal discs
B29C 64/106 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
B29C 64/112 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using individual droplets, e.g. from jetting heads
B29C 64/118 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using filamentary material being melted, e.g. fused deposition modelling [FDM]
A z-lift and leveling assembly for leveling a platen in a heated chamber of a 3D printer includes first, second, third, and fourth z-actuators in a rectangular configuration. Each z-actuator includes a linear drive configured to supply motion in the z-direction and a mounting bracket secured to the linear drive and configured to move with the linear drive in the z-direction. The assembly includes a set of four pin couplings each associated with one of the first, second, third and fourth z-actuators. Each pin coupling includes a pivot block secured to the mounting bracket with a first pivot pin forming a first pin joint between the mounting bracket and the pivot block, where the pivot block is configured to move relative to the mounting bracket about a first pivot axis of the first pivot pin. The pivot block is secured to the platen or an arm of the platen with a second pivot pin forming a second pin joint such that the pivot block and the platen move relative to each other about a second pivot axis. As the mounting bracket is moved, the pivot block moves relative to the mounting bracket about the first pivot axis and the pivot block moves relative to the platen about the second pivot axis such that a z-position of the platen can be manipulated to and maintained in a substantially level configuration in the z-direction though the independent manipulation of the first, second, third and fourth z-actuators and wherein the substantially level configuration can be maintained when the platen is incremented in the z-direction during printing of a part.
B29C 64/393 - Data acquisition or data processing for additive manufacturing for controlling or regulating additive manufacturing processes
B29C 64/236 - Driving means for motion in a direction within the plane of a layer
B33Y 50/02 - Data acquisition or data processing for additive manufacturing for controlling or regulating additive manufacturing processes
B33Y 30/00 - ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING - Details thereof or accessories therefor
An extruder or other similar tool head of a three-dimensional printer is slidably mounted along a feedpath of build material so that the extruder can move into and out of contact with a build surface according to whether build material is being extruded. The extruder may be spring-biased against the forward feedpath so that the extruder remains above the build surface in the absence of applied forces, and then moves downward into a position for extrusion when build material is fed into the extruder. In another aspect, modular tool heads are disclosed that can be automatically coupled to and removed from the three-dimensional printer by a suitable robotics system. A tool crib may be provided to store multiple tool heads while not in use.
B29C 67/00 - Shaping techniques not covered by groups , or
B29C 64/112 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using individual droplets, e.g. from jetting heads
B29C 48/02 - Small extruding apparatus, e.g. handheld, toy or laboratory extruders
B29C 48/25 - Component parts, details or accessories; Auxiliary operations
B29C 48/80 - Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling at the plasticising zone, e.g. by heating cylinders
B29C 48/285 - Feeding the extrusion material to the extruder
B33Y 40/00 - Auxiliary operations or equipment, e.g. for material handling
B29C 64/118 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using filamentary material being melted, e.g. fused deposition modelling [FDM]
B33Y 30/00 - ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING - Details thereof or accessories therefor
Matrix-filled liquid radiation curable resin compositions for additive fabrication are described and claimed. Such resins include a cationically polymerizable component that is an aliphatic epoxide, a multifunctional (meth)acrylate component, a cationic photoinitiator, a free-radical photoinitiator, and a matrix of inorganic fillers, wherein the matrix further constitutes prescribed ratios of at least one microparticle constituent and at least one nanoparticle constituent. Also described and claimed is a process for using the matrix-filled liquid radiation curable resins for additive fabrication to create three dimensional parts, and the three-dimensional parts made from the liquid radiation curable resins for additive fabrication.
C08F 2/46 - Polymerisation initiated by wave energy or particle radiation
C08F 2/50 - Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
C08G 61/04 - Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
G03F 7/00 - Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printed surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
G03F 7/038 - Macromolecular compounds which are rendered insoluble or differentially wettable
G03F 7/027 - Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
B29C 64/135 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask the energy source being concentrated, e.g. scanning lasers or focused light sources
B33Y 70/10 - Composites of different types of material, e.g. mixtures of ceramics and polymers or mixtures of metals and biomaterials
C08L 33/10 - Homopolymers or copolymers of methacrylic acid esters
A method for printing a 3D part in a layer-wise manner includes providing a pool of polymerizable liquid in a vessel over a build window and positioning a downward-facing build platform in the pool, thereby defining a build region above the build window. The method includes selectively curing a volume of polymerizable liquid in the build region by imparting electromagnetic radiation through the build window to form a printed layer of the part adhered to the build platform and actively cooling the build window to remove energy imparted by the electromagnetic radiation and the polymerization reaction of the polymerizable liquid such that the printed layer is between about 1° C. and about 30° C. below an average part temperature prior to raising the print layer and printing the next layer.
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
B29C 64/188 - Processes of additive manufacturing involving additional operations performed on the added layers, e.g. smoothing, grinding or thickness control
B29C 64/20 - Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering - Details thereof or accessories therefor
B33Y 30/00 - ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING - Details thereof or accessories therefor
66.
Part quality monitoring in a stereolithographic additive manufacturing system
A method for 3D printing a part in a layer-wise manner includes providing a pool of polymerizable liquid in a vessel over a build window and positioning a downward-facing build platform in the pool, thereby defining a build region above the build window. The method includes selectively curing a volume of polymerizable liquid in the build region by imparting electromagnetic radiation through the build window to form a printed layer of the part adhered to the build platform and scanning at least a portion of the build window with monochromatic, polarized light along a plane of incidence. The method includes measuring a change in intensity and polarity of the light to obtain information about the printed layer. The method includes raising the build platform to a height of a next layer to be printed and modifying the electromagnetic energy imparted into the next layer based upon the obtained information to print a next layer. The imparting, scanning, measuring, raising and modifying steps are repeated until the part is printed.
B33Y 50/00 - Data acquisition or data processing for additive manufacturing
B29C 64/129 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask
B33Y 50/02 - Data acquisition or data processing for additive manufacturing for controlling or regulating additive manufacturing processes
Radiation curable compositions for additive fabrication with improved toughness are described and claimed. Such resins include a rubber toughenable base resin package and a liquid, phase-separating toughening agent. The rubber toughenable base resin, which may possess a suitably high average molecular weight between crosslinks and may be a pre-reacted hydrophobic macromolecule, may further include a cationically polymerizable component, a radically polymerizable component, a cationic photoinitiator, a free radical photoinitiator, and customary additives. Also described and claimed are methods for forming a three-dimensional objects using such radiation curable compositions for additive fabrication with improved toughness, along with the three-dimensional parts created therefrom.
B29C 64/129 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask
G03F 7/027 - Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
G03F 7/105 - Photosensitive materials - characterised by structural details, e.g. supports, auxiliary layers having substances, e.g. indicators, for forming visible images
G03F 7/038 - Macromolecular compounds which are rendered insoluble or differentially wettable
G03F 7/00 - Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printed surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
B29C 64/393 - Data acquisition or data processing for additive manufacturing for controlling or regulating additive manufacturing processes
B29C 64/277 - Arrangements for irradiation using multiple radiation means, e.g. micromirrors or multiple light-emitting diodes [LED]
B29C 64/268 - Arrangements for irradiation using electron beams [EB]
C08L 63/00 - Compositions of epoxy resins; Compositions of derivatives of epoxy resins
A method for additive manufacturing includes: at a build tray arranged over a build window and containing a resin reservoir of a resin, heating the resin reservoir toward a target bulk resin temperature less than a heat deflection temperature of the resin in a photocured state; at a resin interface between a surface of the build window and the resin reservoir, heating an interface layer of the resin reservoir toward a target reaction temperature; and, in response to the resin reservoir exhibiting a first temperature proximal the target bulk resin temperature and to the interface layer exhibiting a second temperature proximal the target reaction temperature: at the resin interface, selectively photocuring a first volume of the resin to form a first layer of a build adhered to a build platform; and retracting the build platform away from the build window.
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
B29C 64/393 - Data acquisition or data processing for additive manufacturing for controlling or regulating additive manufacturing processes
B29C 64/135 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask the energy source being concentrated, e.g. scanning lasers or focused light sources
B33Y 50/02 - Data acquisition or data processing for additive manufacturing for controlling or regulating additive manufacturing processes
B29C 64/255 - Enclosures for the building material, e.g. powder containers
B29C 64/232 - Driving means for motion along the axis orthogonal to the plane of a layer
B29C 64/129 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask
B33Y 40/00 - Auxiliary operations or equipment, e.g. for material handling
B33Y 30/00 - ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING - Details thereof or accessories therefor
69.
WATER DISPERSIBLE POLYMER FOR USE IN ADDITIVE MANUFACTURING
A water dispersible sulfopolymer for use as a material in the layer-wise additive manufacture of a 3D part made of a non water dispersible polymer wherein the water dispersible polymer is a reaction product of a metal sulfo monomer, the water dispersible sulfo-polymer being dispersible in water resulting in separation of the water dispersible polymer from the 3D part made of the non water dispersible polymer.
C08G 63/688 - Polyesters containing atoms other than carbon, hydrogen, and oxygen containing sulfur
B29C 64/40 - Structures for supporting 3D objects during manufacture and intended to be sacrificed after completion thereof
B33Y 30/00 - ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING - Details thereof or accessories therefor
B33Y 70/00 - Materials specially adapted for additive manufacturing
G03G 15/16 - Apparatus for electrographic processes using a charge pattern for transferring a pattern to a second base of a toner pattern, e.g. a powder pattern
G03G 15/22 - Apparatus for electrographic processes using a charge pattern involving the combination of more than one step according to groups
B29C 64/118 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using filamentary material being melted, e.g. fused deposition modelling [FDM]
70.
METHOD OF ANALYZING AND UTILIZING SURFACE TOPOLOGY FOR TARGETED LOCAL THERMAL MANAGEMENT IN ADDITIVE MANUFACTURING SYSTEMS
A method for 3D printing a part with an additive manufacturing system includes printing a first portion of a part in a layerwise manner and analyzing a topology of the first portion of the part. The method includes determining a tool path for printing a second portion of the part on a surface of the first portion of the part, and pre-heating the first portion of the part along the tool path as a function of the topological analysis of the first portion of the part. The method includes printing the second portion of the part along the tool path.
A supply of build material such as a spool or cartridge is instrumented with a data tag that includes information about the build material. A three-dimensional printer, or a tag reader in communication therewith (directly or indirectly), can read the information from the tag for a determination as to how to use the build material during fabrication of a three-dimensional object.
B29C 64/40 - Structures for supporting 3D objects during manufacture and intended to be sacrificed after completion thereof
B29C 64/118 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using filamentary material being melted, e.g. fused deposition modelling [FDM]
B29C 64/386 - Data acquisition or data processing for additive manufacturing
B29C 64/106 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
B33Y 30/00 - ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING - Details thereof or accessories therefor
B33Y 50/02 - Data acquisition or data processing for additive manufacturing for controlling or regulating additive manufacturing processes
B33Y 40/00 - Auxiliary operations or equipment, e.g. for material handling
B33Y 70/00 - Materials specially adapted for additive manufacturing
B33Y 80/00 - Products made by additive manufacturing
B29C 48/02 - Small extruding apparatus, e.g. handheld, toy or laboratory extruders
B29C 48/265 - Support structures or bases for apparatus, e.g. frames
B29C 48/25 - Component parts, details or accessories; Auxiliary operations
B33Y 50/00 - Data acquisition or data processing for additive manufacturing
An additive manufacturing system configured to: during a first build cycle of an additive manufacturing process for manufacturing a first layer of a build, sampling a first set of sensor data streams via the sensor suite; calculate a first likelihood of failure of the build based on the first set of sensor data streams; in response to calculating the first likelihood of failure within a first likelihood range, flag the build to indicate the first likelihood of failure; and in response to calculating the first likelihood of failure within a second likelihood range greater than the first likelihood range, pause the additive manufacturing process, and notify an operator of the additive manufacturing system of the first likelihood of failure.
B29C 64/393 - Data acquisition or data processing for additive manufacturing for controlling or regulating additive manufacturing processes
B33Y 30/00 - ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING - Details thereof or accessories therefor
B33Y 50/02 - Data acquisition or data processing for additive manufacturing for controlling or regulating additive manufacturing processes
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
The present invention is directed to polyester powders suitable for use in 3D printing processes, methods of using such polyester powders in 3D printing processes, and processes for the manufacturing thereof. The polyester powders prepared in accordance with the present invention are easily recycled after such polyester powders have been subjected to 3D printing conditions. In addition, the present invention is directed to recycling processes that recondition waste polyester powders into polyester powders suitable for 3D printing.
B29C 64/153 - Processes of additive manufacturing using only solid materials using layers of powder being selectively joined, e.g. by selective laser sintering or melting
B29C 64/165 - Processes of additive manufacturing using a combination of solid and fluid materials, e.g. a powder selectively bound by a liquid binder, catalyst, inhibitor or energy absorber
B33Y 70/10 - Composites of different types of material, e.g. mixtures of ceramics and polymers or mixtures of metals and biomaterials
C08L 67/03 - Polyesters derived from dicarboxylic acids and dihydroxy compounds the dicarboxylic acids and dihydroxy compounds having the hydroxy and the carboxyl groups directly linked to aromatic rings
A multiple axis robotic additive manufacturing system includes a robotic arm movable in six degrees of freedom. The system includes a build platform movable in at least two degrees of freedom and independent of the movement of the robotic arm to position the part being built to counteract effects of gravity based upon part geometry. The system includes an extruder mounted at an end of the robotic arm. The extruder is configured to extrude at least part material with a plurality of flow rates, wherein movement of the robotic arm and the build platform are synchronized with the flow rate of the extruded material to build the 3D part.
B29C 64/118 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using filamentary material being melted, e.g. fused deposition modelling [FDM]
B33Y 30/00 - ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING - Details thereof or accessories therefor
B25J 9/04 - Programme-controlled manipulators characterised by movement of the arms, e.g. cartesian co-ordinate type by rotating at least one arm, excluding the head movement itself, e.g. cylindrical co-ordinate type or polar co-ordinate type
B29C 64/106 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
Radiation curable compositions for additive fabrication processes, the components cured therefrom, and their use in particle image velocimetry testing methods are described and claimed herein. Such compositions include compounds which induce free-radical polymerization, optionally compounds which induce cationic polymerization, a filler constituent, and a light absorbing component, wherein the compositions are configured to possess certain absorbance values at wavelengths commonly utilized in particle image velocimetry testing. In another embodiment, the compositions include a fluoroantimony-modified compound. Such compositions may be used in particle imaging velocimetry testing methods, wherein the test object utilized is created via additive fabrication and is of a substantially homogeneous construction.
C08F 2/46 - Polymerisation initiated by wave energy or particle radiation
C08F 2/50 - Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
C08G 61/04 - Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
B29C 64/106 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
G01P 5/20 - Measuring speed of fluids, e.g. of air stream; Measuring speed of bodies relative to fluids, e.g. of ship, of aircraft by measuring the time taken by the fluid to traverse a fixed distance using particles entrained by a fluid stream
C08F 220/18 - Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
B33Y 70/10 - Composites of different types of material, e.g. mixtures of ceramics and polymers or mixtures of metals and biomaterials
B29C 64/135 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask the energy source being concentrated, e.g. scanning lasers or focused light sources
76.
Powder coating method for manufacturing 3D-printed components having improved mechanical properties
The invention relates to a method for producing an object from different powdered components by means of additive manufacturing, wherein a plurality of powdered components having different melting points are simultaneously placed in precise positions, and the powder coating (1) is subsequently thermally treated. The construction material is, for example, polyether ether ketone (PEEK), polyaryl ether ketone (PAEK), polyether ketone ketone (PEKK), polyether sulfone, polyimide, polyether imide, polyester, polyamides, polycarbonates, polyurethanes, polyvinyl chloride, polyoxymethylene, polyvinyl acetate, polyacrylates, polymethacrylates, polyethylene, polypropylene, polylactide, ABS (acrylonitrile butadiene styrene copolymers), PETG (glycol modified polyethylene terephthalate), polystyrene, or mixtures thereof. The supporting material is an inorganic salt of the alkali metals, an inorganic salt of the alkaline earth metals, or a mixture thereof.
B29C 64/153 - Processes of additive manufacturing using only solid materials using layers of powder being selectively joined, e.g. by selective laser sintering or melting
B29C 64/40 - Structures for supporting 3D objects during manufacture and intended to be sacrificed after completion thereof
A filament drive mechanism for use with an additive manufacturing system includes at least first and second drives. Each drive includes a first rotatable shaft and a second rotatable shaft engaged with the first rotatable shaft in a counter rotational configuration. Each drive includes a pair of filament engagement elements, one on each rotatable shaft, and positioned on opposing sides of the filament path with a gap therebetween so as to engage a filament provided in the filament path. The drive mechanism includes a bridge follower configured to rotatably couple the first drive to the second drive wherein one of the shafts is a drive shaft configured to be driven by a motor at a rotational rate selected to advance the filament at a desired feed rate and to cause the other shafts to rotate at the same rotational rate, such that each pair of filament engagement teeth will engage a filament in the filament path and will coordinate to advance the filament while counter-rotating at the same rotational rate to drive the filament into a liquefier.
B33Y 40/00 - Auxiliary operations or equipment, e.g. for material handling
B29C 64/118 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using filamentary material being melted, e.g. fused deposition modelling [FDM]
B65H 51/10 - Rollers, pulleys, capstans, or intermeshing rotary elements arranged to operate in groups or in co-operation with other elements with opposed coacting surfaces, e.g. providing nips
78.
METHOD FOR PRINTING THREE-DIMENSIONAL PARTS WITH CYRSTALLIZATION KINETICS CONTROL
A method for printing a three-dimensional part with an additive manufacturing system, which includes providing a part material that compositionally has one or more semi-crystalline polymers and one or more secondary materials that are configured to retard crystallization of the one or more semi-crystalline polymers, where the one or more secondary materials are substantially miscible with the one or more semi-crystalline polymers. The method also includes melting the part material in the additive manufacturing system, forming at least a portion of a layer of the three-dimensional part from the melted part material in a build environment, and maintaining the build environment at an annealing temperature that is between a glass transition temperature of the part material and a cold crystallization temperature of the part material.
B29C 64/118 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using filamentary material being melted, e.g. fused deposition modelling [FDM]
B29C 71/00 - After-treatment of articles without altering their shape; Apparatus therefor
B29B 13/02 - Conditioning or physical treatment of the material to be shaped by heating
B33Y 50/02 - Data acquisition or data processing for additive manufacturing for controlling or regulating additive manufacturing processes
B29C 64/112 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using individual droplets, e.g. from jetting heads
G03G 15/22 - Apparatus for electrographic processes using a charge pattern involving the combination of more than one step according to groups
The present invention relates to a method for functionalizing a workpiece surface, comprising the following steps: a) providing a workpiece; b) providing a film; c) functionalizing at least one film side by the location-selective application of a functionalization composition comprising a polymer material onto part of the film side in one or more layers by means of a 3D printing process; d) creating an integrally bonded or interlocking connection between the workpiece surface and the film functionalized in step c) by bringing the film into contact with at least part of the workpiece surface, wherein the integrally bonded or interlocking connection to the workpiece surface is achieved with a functionalized film side. The invention further relates to workpieces having a surface functionalized according to the invention.
B33Y 40/20 - Post-treatment, e.g. curing, coating or polishing
B29C 64/118 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using filamentary material being melted, e.g. fused deposition modelling [FDM]
B29C 51/02 - Combined thermoforming and manufacture of the preform
B29C 51/14 - Shaping by thermoforming, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor using multilayered preforms or sheets
A platen assembly for use with an extrusion-based 3D printer includes a grid assembly comprising at least a 4×2 framework of interlocked perpendicular x direction beams and y direction beams, providing a substantially planar upper surface and a bottom surface. The platen assembly includes a platen comprising a thin metal sheet supported on the upper surface of the grid assembly and secured to the grid assembly such that the top surface provides a substantially flat build surface. The x direction beams, the y direction beams and the platen are constructed of substantially a same thermal expansion properties, and wherein the build surface of the platen has a build surface area of at least 400 square inches and maintains its flatness to within a flatness tolerance of 0.020 inches over a temperature range of at least 20 C-300 C.
B29C 64/232 - Driving means for motion along the axis orthogonal to the plane of a layer
B33Y 30/00 - ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING - Details thereof or accessories therefor
B29C 64/118 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using filamentary material being melted, e.g. fused deposition modelling [FDM]
81.
Core-shell filament for use in extrusion-based additive manufacturing systems and method of printing parts
A filament for use in an extrusion-based additive manufacturing system includes an elastomeric core and a harder, non-elastomeric shell. The core compositionally comprising an elastomeric core material having a flexural modulus of less than 31,000 psi and a durometer of less than 80 Shore. The shell overlays the core portion and compositionally comprises a non-elastomeric thermoplastic shell material that is substantially miscible with the elastomeric core material, wherein the core material and the shell material have the same monomer chemistry. The non-elastomeric thermoplastic shell material has a flexural modulus that is greater than the flexural modulus of the elastomeric core material by at least a factor of five, wherein the shell provides sufficient strength or stiffness to the filament such that filament can be utilized as a feedstock in the extrusion-based additive manufacturing system.
B29C 64/118 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using filamentary material being melted, e.g. fused deposition modelling [FDM]
D01F 8/12 - Conjugated, i.e. bi- or multicomponent, man-made filaments or the like; Manufacture thereof from synthetic polymers with at least one polyamide as constituent
D01F 8/14 - Conjugated, i.e. bi- or multicomponent, man-made filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
The present invention relates to a method of producing an article, comprising the step of producing the article by means of an additive manufacturing method from a build material comprising an aromatic polycarbonate and interference pigments and/or pearlescent pigments from the group of the metal oxide-coated micas. The invention likewise relates to an article obtainable by the method. The build material further comprises ≥0.05% by weight to ≤3% by weight of anhydride-modified α-olefin polymer.
B29C 64/118 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using filamentary material being melted, e.g. fused deposition modelling [FDM]
C08K 5/5313 - Phosphinic compounds, e.g. R2=P(:O)OR'
C08L 69/00 - Compositions of polycarbonates; Compositions of derivatives of polycarbonates
C08L 23/26 - Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
85.
Method for build separation from a curing interface in an additive manufacturing process
A layer-by layer method for additive manufacturing that includes: photocuring a first volume of resin to form a layer of a build at an upper surface of a separation membrane laminated over a build window; injecting a fluid into an interstitial region between the separation membrane and the build window; retracting the build from the build window; evacuating the fluid from the interstitial region; and photocuring a second volume of liquid resin to form a subsequent layer of the build between an upper surface of a separation membrane and the previous layer of the build.
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
B33Y 30/00 - ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING - Details thereof or accessories therefor
B29C 37/00 - Component parts, details, accessories or auxiliary operations, not covered by group or
86.
SYSTEM AND METHOD FOR 3D PRINTING WITH METAL FILAMENT MATERIALS
An additive manufacturing system configured to a 3D print using a metal wire material includes a drive mechanism configured to feed the metal feedstock into an inlet tube and a liquefier. The liquefier has a chamber configured to accept the metal feedstock from the inlet tube. The metal feed stock is heated in the chamber such that a melt pool is formed in the chamber. The liquefier has an extrusion tube in fluid communication with the chamber, the extrusion tube having a length (L) and a diameter (D) wherein the ratio of length to diameter (L/D) ranges from about 4:1 to about 20:1. The system has a platen with a surface configured to accept melted material from the liquefier, wherein the platen and the liquefier move in at least three dimensions relative to each other. The system includes a regulated source of pressurized inert gas flowably coupled to the liquefier and configured to place a controlled positive pressure onto the melt pool sufficient to overcome the resistance of the extrusion tube such that a part may be formed by the extrusion of the liquidus metal along toolpaths defined by the relative motion of the liquefier and the platen.
B29C 64/118 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using filamentary material being melted, e.g. fused deposition modelling [FDM]
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
B29C 64/40 - Structures for supporting 3D objects during manufacture and intended to be sacrificed after completion thereof
B33Y 30/00 - ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING - Details thereof or accessories therefor
B29C 64/20 - Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering - Details thereof or accessories therefor
87.
METHOD FOR PRODUCING AN ADDITIVELY MANUFACTURED AND TREATED OBJECT
The invention relates to a method for producing a treated object, comprising the steps: a) producing an object by means of additive manufacturing, the object being produced by the repeated arrangement, layer by layer, of at least one first material on a substrate spatially selectively in accordance with a cross-section of the object, the method comprising the additional method step: b) at least partially bringing the object, which is still on the substrate or has already been detached from the substrate and which has been produced by additive manufacturing, into contact with a liquid heated to ≥T or a powder bed of a second material heated to ≥T for a time ≥1 minute in order to obtain the treated object, T standing for a temperature of ≥25° C. The invention further relates to an object produced by a method of this type.
B29C 64/165 - Processes of additive manufacturing using a combination of solid and fluid materials, e.g. a powder selectively bound by a liquid binder, catalyst, inhibitor or energy absorber
B29C 64/188 - Processes of additive manufacturing involving additional operations performed on the added layers, e.g. smoothing, grinding or thickness control
An additive manufacturing system including a base assembly and a tray assembly. The base assembly includes a build window, substantially transparent to electromagnetic radiation; a projection system configured to project electromagnetic radiation toward an upper surface of the build window; and a tray seat arranged around a perimeter of the build window. The tray assembly is configured to engage with the base assembly in an engaged configuration and includes: a tray structure defining a registration feature configured to engage the tray seat to locate an aperture proximal to the upper surface of the build window in the engaged configuration; and a separation membrane that is configured to laminate across the upper surface of the build window in response to an evacuation of gas from an interstitial region and configured to separate from the build window in response to injection of gas into the interstitial region.
B33Y 30/00 - ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING - Details thereof or accessories therefor
B29C 64/255 - Enclosures for the building material, e.g. powder containers
B29C 64/135 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask the energy source being concentrated, e.g. scanning lasers or focused light sources
B29C 64/379 - Handling of additively manufactured objects, e.g. using robots
89.
Water dispersible sulfonated thermoplastic copolymer for use in additive manufacturing
A sulfonated water-dispersible thermoplastic copolymer material for use as a support material in an additive manufacturing process is made by a method comprising providing a selected thermoplastic copolymer having an acid or an anhydride group; esterifying the acid group of the selected thermoplastic copolymer with a hydroxyl-functionalized sulfonate salt, or amidizing the acid group of the selected thermoplastic copolymer with an amine sulfonate salt, or imidizing the anhydride group of the selected thermoplastic copolymer with an amine sulfonate salt. The esterification, the amidization or the imidization results in a sulfonated water thermoplastic dispersible copolymer having a glass transition temperature suitable to provide an effective support during the additive manufacturing process and wherein the sulfonated water-dispersible thermoplastic copolymer will disperse in tap water in less than 1 hour.
C09D 11/107 - Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
B29C 64/118 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using filamentary material being melted, e.g. fused deposition modelling [FDM]
B29C 64/40 - Structures for supporting 3D objects during manufacture and intended to be sacrificed after completion thereof
B29K 33/00 - Use of polymers of unsaturated acids or derivatives thereof, as moulding material
B29K 105/00 - Condition, form or state of moulded material
B33Y 70/00 - Materials specially adapted for additive manufacturing
C09D 11/54 - Inks based on two liquids, one liquid being the ink, the other liquid being a reaction solution, a fixer or a treatment solution for the ink
90.
Method of printing an unsupported part with a robotic additive manufacturing system
A method of printing a hollow part with a robotic additive manufacturing system includes extruding thermoplastic material onto a build platform movable in at least two degrees of freedom in a helical pattern along a continuous 3D tool path with an extruder mounted on a robotic arm, to thereby print a hollow member having a length and a diameter. The method includes orienting the hollow member during printing by moving the build platform based on a geometry of the hollow member wherein the movement of the build platform and the movement of the robotic arm are synchronized to print the part without support structures.
B29C 64/118 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using filamentary material being melted, e.g. fused deposition modelling [FDM]
B33Y 30/00 - ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING - Details thereof or accessories therefor
B25J 9/04 - Programme-controlled manipulators characterised by movement of the arms, e.g. cartesian co-ordinate type by rotating at least one arm, excluding the head movement itself, e.g. cylindrical co-ordinate type or polar co-ordinate type
B29C 64/106 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
The present invention relates to a fibre-reinforced 3D-printed elastic product (1, 3, 4, 7, 10, 12), wherein the product comprises a weight proportion of ≥50% of a polymer having a mean molecular weight of ≥5000 g/mol, measured by means of GPC, and a weight proportion of ≥0.5% and ≤20% of one or more fibres having an aspect ratio of ≥100 and a length of ≥3 cm and ≤1000 cm, the product being produced at least in part by means of an FFF (Fused Filament Fabrication) method, and the product having a tensile modulus of ≥1.5 GPa in the region of the fibre reinforcement and in the direction of the fibre symmetry axis. The product also has a tensile modulus, measured according to DIN EN ISO 527-1, of ≤1.2 GPa in the region of the fibre reinforcement and perpendicular to the fibre symmetry axis, and has a yield strength of ≥5%, measured according to DIN EN ISO 527-1, perpendicular to the fibre symmetry axis.
Methods for post-processing photofabricated articles created via additive fabrication processes are described and claimed herein. Such methods include providing a photofabricated article, preferably an article that has been at least partially cured via cationic polymerization mechanisms, optionally, post-processing the photofabricated article, and base-washing the photofabricated article in an alkaline solution or dispersion to create a neutralized photofabricated article. In another embodiment, the methods include treating a photofabricated article having a residual acid or base species with a treatment composition in order to create a neutralized photofabricated article. Also described and claimed are the neutralized photofabricated articles created via the methods herein elsewhere described. Such articles are preferably biocompatible, especially as determined by their lack of cytotoxicity potential.
B33Y 70/00 - Materials specially adapted for additive manufacturing
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
B33Y 40/20 - Post-treatment, e.g. curing, coating or polishing
93.
3D-PRINTED ORTHODONTIC SPLINT MADE OF CROSSLINKED POLYMERS
The present invention relates to an orthodontic splint made of a crosslinked polymer, wherein the crosslinked polymer has a glass transition temperature Tg, determined by means of dynamic-mechanical analysis at a frequency of 1/s DMA as peak tan δ, of ≥25° C. and ≤60° C., a modulus of elasticity, determined by means of dynamic-mechanical analysis as the storage modulus E′ at a frequency of 1/s at 35° C., of ≥500 MPa and ≤4000 MPa, and a loss factor tan δ, determined by means of dynamic-mechanical analysis at a frequency of 1/s at 35° C., of ≥0.08. The invention further relates to a process for producing such splints.
The hardware and software properties of a three-dimensional printer can be queried and applied to select suitable directly printable models for the printer, or to identify situations where a new machine-ready model must be generated. The properties may be any properties relevant to fabrication including, e.g., physical properties of the printer, printer firmware, user settings, hardware configurations, and so forth. A printer may respond to configuration queries with a dictionary of capabilities or properties, and this dictionary may be used to select suitable models, or determine when a new model must be created. Similarly, when a printable model is sent to the printer, metadata for the printable model may be compared to printer properties in the dictionary to ensure that the model can be fabricated by the printer.
42 - Scientific, technological and industrial services, research and design
Goods & Services
3D printers Scientific and technological services, namely, new product design and development services, scientific and technological consultation services, and research and product design analysis services relating thereto in the field of custom manufacturing of goods; Providing a website featuring technology that enables the user to upload, download, modify, design, and order customer-manufactured parts on the Internet; Testing new computer aided design concepts for others
96.
METHOD FOR MULTIVARIATE TESTING, DEVELOPMENT, AND VALIDATION OF A MATERIAL FOR AN ADDITIVE MANUFACTURING DEVICE
A method includes: accessing a first selection of a first test variable; based on the selection, photocuring a first test build by varying a value of the first test variable over a first set of test regions; accessing a first set of measurements of the first test build; calculating a target range of the first test variable based on the first set of measurements; accessing a second selection of a second test variable; based on the second selection, photocuring a second test build by varying a value of the second test variable over a second set of test regions while maintaining a target value of the first test variable within the target range of the first test variable; accessing a second set of measurements of the second test build; and calculating a second target range of the second test variable based on the second set of measurements.
A method of recycling a water dispersible sulfonated polymer material used as a support structure in an additive manufacturing process includes providing a tap water bath and placing a printed part having an adhered support structure into the tap water bath, the support structure comprising a water-soluble sulfonated polymer material. The method includes dissolving the sulfonated polymer material in the water bath to thereby create a dispersion, and modifying the ionic strength of the dispersion by adding a multivalent metal salt to the dispersion at a concentration of between 1 gram/L and 30 grams/L, to precipitate the dissolved sulfonated polymer material from the water. The method includes recovering the precipitated sulfonated polymer material from the water, drying the recovered sulfonated polymer material and reforming the dried sulfonated polymer material into a form suitable for subsequent use as a consumable feedstock in an additive manufacturing process.
Described herein are thermoset compositions and kits of compositions suitable for use in additive fabrication processes including high concentrations of urethane methacrylate oligomers having at least one polymerizable group, and a number average molecular weight from 750 to 4000 g/mol, an effective quantity of a monofunctional reactive diluent monomer, a defined concentration of a network building agent having a molecular weight that is lower than the urethane methacrylate oligomer, optionally a photoinitiator, and optionally, additives. Also disclosed are methods of creating three-dimensional parts via additive fabrication processes utilizing urethane methacrylate oligomer-centric compositions, wherein various exposure irradiances, cure temperatures, and oxygen content levels are prescribed, as well as the articles cured therefrom.
C08F 2/46 - Polymerisation initiated by wave energy or particle radiation
C08F 2/50 - Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
C08G 61/04 - Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
C08G 18/42 - Polycondensates having carboxylic or carbonic ester groups in the main chain
B33Y 70/00 - Materials specially adapted for additive manufacturing
B33Y 80/00 - Products made by additive manufacturing
B29C 64/129 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask
A low pull force system for feeding a filament along a feed path from a source to a liquefier in a 3D printer includes a low compressive force loading drive for advancing filament from the source, a feed drive for advancing filament into the liquefier, and an in-line accumulator comprising a telescoping joint positioned in the feed path between the loading drive and the feed drive. When the telescoping joint is in a contracted position, the loading drive activates to feed filament into the feed path at a rate faster than a rate at which the feed drive advances filament into the liquefier, causing the telescoping joint to expand and accrue a slack of filament in the feed path. When the telescoping joint reaches an extended position, the loading drive deactivates while the feed drive continues to advance filament into the liquefier, and the slack of filament is consumed.
B29C 64/118 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using filamentary material being melted, e.g. fused deposition modelling [FDM]
B33Y 30/00 - ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING - Details thereof or accessories therefor
B29C 64/393 - Data acquisition or data processing for additive manufacturing for controlling or regulating additive manufacturing processes
01 - Chemical and biological materials for industrial, scientific and agricultural use
09 - Scientific and electric apparatus and instruments
42 - Scientific, technological and industrial services, research and design
Goods & Services
Chemical materials, namely, photocurable liquid synthetic resins and industrial chemicals used in 3D printers to create 3D embodiments of computer-generated designs Downloadable software for operating and controlling 3D printers; Downloadable software for processing digital image files for 3D printing Providing temporary use of non-downloadable cloud-based software for operating and controlling 3D printers; Providing temporary use of non-downloadable cloud-based software for processing digital image files for 3D printing
